Middle and late Pleistocene glaciations in the Campo Felice Basin (central Apennines, Italy)

The present paper refers to research conducted in the tectonic-karst depression of Campo Felice in the central Apennines (Italy), in which glacial, alluvial and lacustrine sediments have been preserved. Stratigraphic interpretations of sediments underlying the Campo Felice Plain are based on evidence obtained from nine continuous-core boreholes. The boreholes reach a depth of 120 m and provide evidence of five sedimentation cycles separated by erosion surfaces. Each cycle is interpreted as an initial response to a mainly warm stage, characterized by low-energy alluvial and colluvial deposition, pedogenesis, and limited episodes of marsh formation. In turn, a mainly cold stage follows during which a lake formed, and glaciers developed and expanded, leading to deposition of glacial and fluvioglacial deposits. The chronological framework is established by eleven accelerator mass spectrometer ¹⁴C ages and three ³⁹Ar-⁴⁰Ar ages on leucites from interbedded tephra layers. These age determinations indicate five glacial advances that respectively occurred during marine oxygen isotope stages 2, 3-4, 6, 10 and 14.     

Molecular weight distribution,analytical and spectroscopic characterization of humic fractions sequentially isolated by organic solvents from a brown coal humic acid

A sequential fractionation procedure employing a series of selected mild organic solvents of different polarity has been applied for the isolation of chemically different organic fractions from a brown coal humic acid. Elemental composition, molecular weight distribution, i.r. and electron spin resonance analysis were carried out on the isolated humic fractions. They were characterized by: (a) a low polydispersity, (b) a decreasing aliphatic and increasing aromatic character along the series, (c) very different molecular weight which significantly correlated with E₄/E₆ ratios (particle aggregation and molecular association) and free radical concentrations (chemical and biochemical activity). Significant correlations were found between physico-chemical parameters of the isolated humic fractions, i.e. M_n, M_w, E₄/E₆ ratios, spins/g contents and the dielectric constants of the solvents used. This suggested the efficiency of the applied procedure in isolating chemically different organic fractions from the bulk, original humic acid.     

The Quaternary Lancaster Sound trough‐mouth fan,NW Baffin Bay

The development of the Lancaster Sound Trough Mouth Fan (TMF) and glacial history in Arctic Canada were studied using a high‐resolution seismic profile across the entire fan and two piston cores. Stacked tills separated by erosion surfaces on the shelf pass seaward through till deltas into thick transparent glacigenic debris flow (GDF) deposits on the slope, separated by thin, well‐stratified glaciomarine layers. An age model was built by ties to the Ocean Drilling Program Site 645. The deepest GDF on the seismic profile was indicative of the onset of shelf‐crossing glaciation in the Early Pleistocene. The transition of the growth of Lancaster Sound TMF from an aggradational sequence (unit M) to an aggradational–progradational sequence (unit F) occurred at the Middle Pleistocene transition in glacial cyclicity. In the most recent glacial cycle, GDF sheets were deposited during Heinrich events 4 and 2 according to the correlation of the main detrital carbonate beds in two piston cores. The outmost till wedge reflects the maximum advance of the grounding glacier, far seaward of previously proposed Last Glacial Maximum ice extent. Copyright © 2011 John Wiley & Sons, Ltd.     

On characterizing the temporal dominance patterns of model parameters and processes

Diagnostic analyses of hydrological models intend to improve the understanding of how processes and their dynamics are represented in models. Temporal patterns of parameter dominance could be precisely characterized with a temporally resolved parameter sensitivity analysis. In this way, the discharge conditions are characterized, that lead to a parameter dominance in the model. To achieve this, the analysis of temporal dynamics in parameter sensitivity is enhanced by including additional information in a three‐tiered framework on different aggregation levels. Firstly, temporal dynamics of parameter sensitivity provide daily time series of their sensitivities to detect variations in the dominance of model parameters. Secondly, the daily sensitivities are related to the flow duration curve (FDC) to emphasize high sensitivities of model parameters in relation to specific discharge magnitudes. Thirdly, parameter sensitivities are monthly averaged separately for five segments of the FDC to detect typical patterns of parameter dominances for different discharge magnitudes. The three methodical steps are applied on two contrasting catchments (upland and lowland catchment) to demonstrate how the temporal patterns of parameter dynamics represent different hydrological regimes. The discharge dynamic in the lowland catchment is controlled by groundwater parameters for all discharge magnitudes. In contrast, different processes are relevant in the upland catchment, because the dominances of parameters from fast and slow runoff components in the upland catchment are changing over the year for the different discharge magnitudes. The joined interpretation of these three diagnostic steps provides deeper insights of how model parameters represent hydrological dynamics in models for different discharge magnitudes. Thus, this diagnostic framework leads to a better characterization of model parameters and their temporal dynamics and helps to understand the process behaviour in hydrological models. Copyright © 2015 John Wiley & Sons, Ltd.     

Beryllium-10 in Australasian tektites: Constraints on the location of the source crater

By using accelerator mass spectrometry we have measured the ¹⁰Be concentrations of 86 Australasian tektites. Corrected to the time of tektite production ∼0.8 My ago, the ¹⁰Be concentrations (10⁶ atom/g) range from 59 for a layered tektite from Huai Sai, Thailand, to 280 for an australite from New South Wales, Australia. The average value is 143 ± 50. When tektites are sorted by country, their average measured ¹⁰Be concentrations increase slowly with increasing distance from Southeast Asia, the probable location of the tektite producing event, from 59 ± 9 for 6 layered tektites from Laos to 136 ± 20 for 20 splash-form tektites from Australia. The lowest ¹⁰Be concentrations for tektites fall on or within a contour centered off the shore of Vietnam, south of the Gulf of Tonkin (107°E; 17°N), but also encompassing two other locations in the area of northeastern Thailand previously proposed for the site of a single tektite-producing impact. The ¹⁰Be concentrations of layered tektites show only a weak anticorrelation (R ∼ −0.3) with the numbers of relict crystalline inclusions.Loosely consolidated, fine-grained terrestrial sediments or recently consolidated sedimentary rocks are the most likely precursor materials. Dilution of sediments with other kinds of rock raises problems in mixing and is not supported by petrographic data. Sedimentary columns that have the right range of ¹⁰Be concentrations occur off the coasts of places where sedimentation rates are high relative to those in the deep sea. A single impact into such a region, 15 to 300 m thick, could have propelled near-surface, high-¹⁰Be material farthest—to Australia—while keeping the deeper-lying, low-¹⁰Be layers closer to home. We do not rule out, however, other proposed mechanisms for tektite formation.     

Neotectonic deformation in the transition zone between the Dead Sea Transform and the East Anatolian Fault Zone, Southern Turkey: a palaeomagnetic study of the Karasu Rift Volcanism

In southern Turkey ongoing differential impingement of Arabia into the weak Anatolian collisional collage resulting from subduction of the Neotethyan Ocean has produced one of the most complex crustal interactions along the Alpine–Himalayan Orogen. Several major transforms with disputed motions, including the northward extension of the Dead Sea Fault Zone (DSFZ), meet in this region. To evaluate neotectonic motion on the Amanos and East Hatay fault zones considered to be northward extensions of the DSFZ, the palaeomagnetism of volcanic fields in the Karasu Rift between these faults has been studied. Remanence carriers are low-Ti magnetites and all except 5 of 51 basalt lavas have normal polarity. Morphological, polarity and K–Ar evidence show that rift formation occurred largely during the Brunhes chron with volcanism concentrated at 0.66–0.35 Ma and a subsidiary episode at 0.25–0.05. Forty-four units of normal polarity yield a mean of D/I=8.8°/54.7° with inclination identical to the present-day field and declination rotated clockwise by 8.8±4.0°. Within the 15-km-wide Hassa sector of the Karasu Rift, the volcanic activity is concentrated between the Amanos and East Hatay faults, both with left lateral motions, which have rotated blocks bounded by NW–SE cross faults in a clockwise sense as the Arabian Block has moved northwestwards. An average lava age of 0.5 Ma yields a minimum cumulative slip rate on the system bounding faults of 0.46 cm/year according with the rate deduced from the Africa–Arabia Euler vector and reduced rates of slip on the southern extension of the DSFZ during Plio-Quaternary times. Estimates deduced from offsets of dated lavas flows and morphological features on the Amanos Fault Zone [Tectonophysics 344 (2002) 207] are lower (0.09–0.18 cm/year) probably because they are limited to surface fault breaks and do not embrace the seismogenic crust.Results of this study suggest that most strike slip on the DSFZ is taken up by the Amanos–East Hatay–Afrin fault array in southern Turkey. Comparable estimates of Quaternary slip rate are identified on other faults meeting at an unstable FFF junction (DSFZ, East Anatolian Fault Zone, Karatas Fault Zone). A deceleration in slip rate across the DSFZ and its northward continuation during Plio-Quaternary times correlates with reorganization of the tectonic regime during the last 1–3 Ma including tectonic escape within Anatolia, establishment of the North and East Anatolian Fault Zones bounding the Anatolian collage in mid–late Pliocene times, a contemporaneous transition from transpression to transtension and concentration of all basaltic magmatism in this region within the last 1 Ma.     

6: Classification of VMS deposits: Lessons from the South Uralides

VMS deposits of the South Urals developed within the evolving Urals palaeo-ocean between Silurian and Late Devonian times. Arc-continent collision between Baltica and the Magnitogorsk Zone (arc) in the south-western Urals effectively terminated submarine volcanism in the Magnitogorsk Zone with which the bulk of the VMS deposits are associated. The majority of the Urals VMS deposits formed within volcanic-dominated sequences in deep seawater settings. Preservation of macro and micro vent fauna in the sulphide bodies is both testament to the seafloor setting for much of the sulphides but also the exceptional degree of preservation and lack of metamorphic overprint of the deposits and host rocks. The deposits in the Urals have previously been classified in terms of tectonic setting, host rock associations and metal ratios in line with recent tectono-stratigraphic classifications. In addition to these broad classes, it is clear that in a number of the Urals settings, an evolution of the host volcanic stratigraphy is accompanied by an associated change in the metal ratios of the VMS deposits, a situation previously discussed, for example, in the Noranda district of Canada.Two key structural settings are implicated in the South Urals. The first is seen in a preserved marginal allochthon west of the Main Urals Fault where early arc tholeiites host Cu–Zn mineralization in deposits including Yaman Kasy, which is host to the oldest macro vent fauna assembly known to science. The second tectonic setting for the South Urals VMS is the Magnitogorsk arc where study has highlighted the presence of a preserved early forearc assemblage, arc tholeiite to calc-alkaline sequences and rifted arc bimodal tholeiite sequences. The boninitc rocks of the forearc host Cu–(Zn) and Cu–Co VMS deposits, the latter hosted in fragments within the Main Urals Fault Zone (MUFZ) which marks the line of arc-continent collision in Late Devonian times. The arc tholeiites host Cu–Zn deposits with an evolution to more calc-alkaline felsic volcanic sequences matched with a change to Zn–Pb–Cu polymetallic deposits, often gold-rich. Large rifts in the arc sequence are filled by thick bimodal tholeiite sequences, themselves often showing an evolution to a more calc-alkaline nature. These thick bimodal sequences are host to the largest of the Cu–Zn VMS deposits.The exceptional degree of preservation in the Urals has permitted the identification of early seafloor clastic and hydrolytic modification (here termed halmyrolysis sensu lato) to the sulphide assemblages prior to diagenesis and this results in large-scale modification to the primary VMS body, resulting in distinctive morphological and mineralogical sub-types of sulphide body superimposed upon the tectonic association classification.It is proposed that a better classification of seafloor VMS systems is thus achievable using a three stage classification based on (a) tectonic (hence bulk volcanic chemistry) association, (b) local volcanic chemical evolution within a single edifice and (c) seafloor reworking and halmyrolysis.     

Landslide HotSpot Mapping by means of Persistent Scatterer Interferometry

Landslide detection and mapping represent fundamental requirements for every hazard and risk evaluation and consequent improvement of the management strategies for such natural hazards. Optical and radar remote sensing can be used to observe landslide-induced ground deformation, ranging from regional to local scales. This work presents a methodology called Landslide HotSpot Mapping; this approach integrates cartographic, thematic and optical data with Persistent Scatterer Interferometry for the identification of extremely slow to very slow moving landslides, and for the evaluation of their state of activity and intensity. This methodology scans wide areas to detect hotspots, which are narrow unstable zones characterized by higher landslide hazard. To these hotspots, priority has to be given when planning field surveys and in situ validation campaigns, so that field work time and effort can be optimized and significantly reduced. The approach is tested in Central Calabria, over a 4,470?km² area located in southern Italy. ENVISAT ascending images acquired between 2003 and 2009 and processed with the Persistent Scatterer Pairs (PSP) technique are used to analyse deformation patterns. Combining conventional photo-interpretation with the analysis of PSP data, 64 new landslides are identified and the spatial (boundaries) and temporal (activity) information of 980 pre-mapped phenomena (23.6% of updated inventory) are updated. 1,012 active (continuous or reactivated) landslides are identified and 4 hotspot areas selected: San Fili, Rende, Lago, Catanzaro. Urgent field checks have to be organized for these hotspots to validate the satellite-based observations and to design appropriate mitigation measures to reduce impacts on the elements at risk.