Heavy metals in marine sediments of Taranto Gulf (Ionian Sea, Southern Italy)

Al, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Ti and Zn concentrations have been determined in surface sediment samples collected in the Taranto Gulf (Ionian Sea, Southern Italy) in order to evaluate their levels and spatial distribution in this important area of the Mediterranean Sea. For various metals, the geoaccumulation index has been calculated as a criterion to assess if their concentrations represent contamination levels or can be considered as background levels. The results show that metals concentrations in sediments can be considered near the background levels found in the Mediterranean Sea.Analytical results have been elaborated by using a Geographical Information System (GIS) software to show metals accumulation areas. Using multivariate statistical analysis, we evaluate the possibility to distinguish the sampling stations, in relation to their geographical position. Results have showed metals distribution in the Taranto Gulf is principally influenced by industrial and urban wastes, located mostly in the northern coastal area of the Ionian Sea. Rivers in the Basilicata region and prevailing anticlockwise marine currents are further factors influencing metal accumulation in sediments.     

Search For Correlations Between Batse Gamma-Ray Bursts and Supernovae

We report on our statistical research of space–time correlated supernovae and CGRO-BATSE gamma-ray bursts (GRBs). There exists a significantly higher abundance of core-collapse supernovae among the correlated supernovae, but the subset of all correlated objects does not seem to be physically different from the whole set.     

Long-term stability of the fish assemblages in a warm-temperate South African estuary

Little is known about long-term changes in estuarine fish populations and related environmental variations. Fishes in the temporarily open/closed East Kleinemonde Estuary were sampled bi-annually, in summer and winter, using seine and gill nets between December 1994 and July 2005. A total of 18 families, represented by 33 species, were recorded. The 10 most abundant species caught were consistently recorded in catches each year, but CPUE of individual species varied on an annual basis and this can often be related to mouth state. Multivariate analyses of the annual marine fish community identified two distinct groups, with more species recorded during years that succeeded spring (September to November) mouth-opening events than in years following no mouth-opening events in spring. Interannual community stability (IMD) and seriation (IMS) also increased from the years following no opening events in spring to the years that succeeded spring opening events. These results highlight the importance of the timing of mouth opening to the marine fish community in a temporarily open/closed estuary. This study reinforces the importance of long-term studies to understanding community changes in estuaries caused by environmental variations over different time scales.     

How Produce a Plasma Jet Using a Single and Low Energy Laser Beam

Under suitable conditions on laser intensity, focal spot radius and atomic number a radiative jet was launched from a planar target. This jet was produced using a relatively low energy laser pulse, below 500 J and it presents similarities with astrophysical protostellar jets. It lasts more than 10 ns, extends over several millimeters, has velocity more than 500 km/s, the Mach number more than 10 and the density above 10¹⁸ cm⁻³. The mechanism of jet formation was inferred from the dimensional analysis and hydrodynamic two-dimensional simulations. It is related to the radiative cooling while the magnetic fields play a minor role. PACS numbers: 98.38.Fs, 52.50.Jm, 95.30.Qd     

In situ high-temperature X-ray diffraction and spectroscopic study of fibroferrite,FeOH(SO<Subscript>4</Subscript>)·5H<Subscript>2</Subscript>O

The thermal dehydration process of fibroferrite, FeOH(SO₄)·5H₂O, a secondary iron-bearing hydrous sulfate, was investigated by in situ high-temperature synchrotron X-ray powder diffraction (HT-XRPD), in situ high-temperature Fourier transform infrared spectroscopy (HT-FTIR) and thermal analysis (TGA-DTA) combined with evolved gas mass spectrometry. The data analysis allowed the determination of the stability fields and the reaction paths for this mineral as well as characterization of its high-temperature products. Five main endothermic peaks are observed in the DTA curve collected from room T up to 800 °C. Mass spectrometry of gases evolved during thermogravimetric analysis confirms that the first four mass loss steps are due to water emission, while the fifth is due to a dehydroxylation process; the final step is due to the decomposition of the remaining sulfate ion. The temperature behavior of the different phases occurring during the heating process was analyzed, and the induced structural changes are discussed. In particular, the crystal structure of a new phase, FeOH(SO₄)·4H₂O, appearing at about 80 °C due to release of one interstitial H₂O molecule, was solved by ab initio real-space and reciprocal-space methods. This study contributes to further understanding of the dehydration mechanism and thermal stability of secondary sulfate minerals.     

Development and Pull-through of Climate Science to Services in China

正1.Introduction The impacts arising from climate change and climate variability pose major challenges to global and regional security and economic prosperity(UNFCCC,2015).Some regions are more at risk than others,through heightened exposure to climatic hazards,and high vulnerability and exposure to such hazards.China,with its rapid economic development,large     

Analysis of climatic trends in data from the agrometeorological station of Bologna-Cadriano, Italy (1952–2007)

Agriculture is highly exposed to climate change, as farming activities directly depend on climatic conditions. Knowledge of the extent of such change and of related phenomena will help to answer the questions posed by society about adaptation strategies. The global situation is well described by the Fourth IPCC assessment report (IPCC 2007), but local studies are important to understand the impact and the priorities to adopt in adaptation strategies. In this study a historical set of meteorological data, collected during the period 1952–2007 at the University of Bologna (Italy) agrometeorological station, was analysed. Several indexes, such as Frost Severity Index, number of hot days, number of rainy days, etc., were calculated, and their trends in time were analysed. The results show a scenario of increasing temperatures and evapotranspiration, a decrease in rainy days and a deepening of the watertable. The effect of these changes on agriculture will be a decrease in water availability, an increase in heat stress in plants and an increase in drought risk.     

Water‐bottom multiple attenuation by Kirchhoff extrapolation

Despite being less general than 3D surface‐related multiple elimination (3D‐SRME), multiple prediction based on wavefield extrapolation can still be of interest, because it is less CPU and I/O demanding than 3D‐SRME and moreover it does not require any prior data regularization. Here we propose a fast implementation of water‐bottom multiple prediction that uses the Kirchhoff formulation of wavefield extrapolation. With wavefield extrapolation multiple prediction is usually obtained through the cascade of two extrapolation steps. Actually by applying the Fermat’s principle (i.e., minimum reflection traveltime) we show that the cascade of two operators can be replaced by a single approximated extrapolation step. The approximation holds as long as the water bottom is not too complex. Indeed the proposed approach has proved to work well on synthetic and field data when the water bottom is such that wavefront triplications are negligible, as happens in many practical situations.     

Analysis of Heat Budget, Dissipation and Frontogenesis in a Shallow Density Current

High frequency wind and temperature measurements, obtained in March 1995 from a 10-m tower array situated in south-east Kansas, are used to analyze the structure of a shallow density current. This current is approximately 7 m deep and exhibits a current head that is estimated to be about twice the current depth. The event lasted approximately 900 s and its origin appears to be a shallow slope 2–:5 km to the west of the site, where cold air drainage occurs. The onset of the event is marked by a 5 °C temperature decrease at the 3-m level, increased variance of temperature and of wind velocity, and increased dissipation of kinetic energy, measured by a hot-wire anemometer at the 3-m level. The primary contributors to temperature changes following the frontal passage are both horizontal and vertical advections; contributions from flux divergences of temperature and of radiation, and from dew formation, do not appear to be significant. Postulated frontogenesis, prior to the arrival of the apparent equilibrated front of approximately 176-m width at the site, is examined by means of a theoretical model. The time required to equilibrate the front, by means of kinetic energy dissipation within the frontal zone, is determined to be less than 300 s, or less than the estimated travel time from the orographic slope to the observational site. The absence of upstream data is determined, however, to be a limitation of the analysis performed.