Radiometric characteristics of heavy mineral deposits along the west coast of South Africa

During the last decade, exploration and mining of modern-Tertiary heavy mineral beach and raised beach sands along the west coast of South Africa has developed into a major industry. High resolution radiometric techniques have demonstrated their use as a quantitative indicator of total heavy mineral concentration (THM) and also have the ability to discriminate between sediments derived from different provenance terrains. Results indicate that it is possible to calculate the total heavy mineral concentration from high resolution radiometric measurements, but the ability to quantify the concentration of individual mineral fractions, such as ilmenite, requires further refinement of the method. Radiometric characteristics of the light mineral fraction made it possible to distinguish between sediments from mixed marine-aeolian palaeoplacers and active present beach placers. The effects of in situ alteration of the ilmenite fraction in the palaeoplacers were also reflected by subtle contrasts in the radiometric character of the deposits. Furthermore, the uniform radiometric character of the sample population indicates a common provenance for the heavy mineral suite and supports previous results which indicate the metamorphites of the mid-Proterozoic Namaqua Province as the primary source terrain. The high resolution radiometric techniques discussed offer a broad spectrum of applications in sedimentology and have the potential to aid heavy mineral exploration. With further refinement it can possibly be used quantitatively in grade control during mining and beneficiation of heavy mineral deposits. Received: 19 July 1996 / Accepted: 7 January 1997     

Automated AF-demagnetization on the 2G-Enterprises through-bore,cryogenic magnetometer

Since the early sixties, alternating field demagnetization (AFD) has been a standard laboratory technique for demagnetizing rocks to expose the multicomponent structure of their natural remanent magnetization (NRM). In the majority of AFD implementations, however, the procedure remains as labour-intensive as ever. The implementation that we have developed at the Australian Geological Survey Organisation, automates the procedure for AFD based on the static method, and results in significant productivity and efficiency gains without compromising data quality. A properly formulated procedure for static AFD may be the only method of retrieving higher-coercivity components of natural remanence in samples prone to developing gyroremanence at higher alternating fields (AFs). Our AFD environment comprises: a 2G-Enterprises through-bore, cryogenic magnetometer; 2G AF-coils and control equipment; and personal computer software, developed by us, to control all procedural aspects for a complete AFD of a sample including, importantly, a counteracting procedure to neutralize the effects of gyroremanence build-up at higher AFs. With our system, AFD of 8 samples/day, each of 20+ steps, requires only 20 min of user attention compared with a full day for conventional systems.     

Geotechnical Hazards Associated with Desert Environment

The aridity of the Arabian Peninsula's deserts ranges between arid to hyperarid with hot dry climate, scarce precipitation and sparse vegetation. These harsh environmental conditions enhance some geomorphologic processes more than others, cause specific geotechnical problems, and increase desertification.From west to east, the general physiography of Saudi Arabia shows the Red Sea coastal plains and the escarpment foothills called Tihama followed by the Arabian Shield mountains, the Arabian Shelf plateau and finally the Arabian Gulf coastal plains. Sand moves by wind either as drifting sand or migrating dunes in four major sand seas, over the Arabian Shelf, and in the inter-mountain valleys, in the Arabian Shield causing problems of erosion and deposition. Human activities in the deserts may cause more instability to the sand bodies, enlarging the magnitude of the problem. Fine silty soil particles also move by wind, depositing loess mainly in selected areas downwind in the Tihama. These loess deposits subside and may form earth fissures by the process of hydrocompaction upon wetting. The addition of water can be either natural through storms or man-made through human agricultural or civil activities. Extensive sabkhas exist along the coastal plains of both the Red Sea and Arabian Gulf. The sabkha soil may also heave by salt re-crystallization or collapse by wetting. The shallow groundwater brines present in sabkhas also attack and corrode civil structures. Urbanization and excessive groundwater pumping may also deplete the fresh groundwater resources and may cause subsidence, ground fissuring and surface faulting as observed in some locations in the Arabian Shield. Although the average annual precipitation is very low, rain usually falls in the form of torrential storms, collected by dry valley basins and causing floods to unprotected downstream areas on the coastal plains of the Red Sea.The desert environment, being a fragile echo system, needs to be treated with care. Intercommunications between different national and international agencies and education of the layman should help to keep the system balanced and reduce the resulting environmental hazards. In addition, any suggested remedial measures should be planned with nature and engineered with natural materials.     

Multi-phase water-rhyolite interaction and ore fluid generation at Aljustrel, Portugal

Detailed study of the Aljustrel volcanic rocks, through petrography, mineral chemistry, whole-rock geochemistry, and previously published stable isotope data, show that the rocks experienced extreme metasomatism. The metasomatic phenomena presented are explained accurately by a sea-water convective model. The evolution of the sea-water-derived fluid as it progresses downwards through the rocks is evident, from cold, oxidising, Mg-bearing, to hot, reducing, Mg-free, and enriched in Si, Fe, Cu, Zn. Several lines of evidence (feldspar mineralogy, paragenetic relations between regional and ore-zone alteration, and stable isotope data) show that the temperature of the hydrothermal circulation increased through time, and that the water-to-rock ratio evolved from very high to low values. According to our data, about 30 ppm Cu and some 100 ppm Zn were removed from the Aljustrel Volcanics. This implies, for both metals, the same amount of leached rock to produce the 2 Mt Cu and 6 Mt Zn contained in the massive sulphide deposits of the Aljustrel area. With regard to Fe, about 1% was on average removed from the rocks, producing enough metal to account for all the Fe in the MS deposits and overlying chemical sediments. This study documents semi-quantitatively the provenance of the main metals in major massive sulphide deposits via sea water leaching of the immediate host rocks.

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Resumen (translated by E. Pascual) Un estudio detallado de las rocas volcánicas de Aljustrel, mediante petrografia, química mineral, geoquímica de roca total y datos de isótopos estables previamente publicados muestra que estas rocas han sufrido metasomatismo en grado extremo. Los fenómenos metasomáticos presentados se explican con precisión mediante un modelo convectivo con agua de mar. Es evidente la evolución del fluido derivado del agua de mar conforme progresa en profundidad a través de las rocas, desde un fluido frío, oxidante y con magnesio a otro reductor, sin magnesio y enriquecido en Si, Fe, Cu y Zn. Varias líneas de evidencia (mineralogía de los feldespatos, relaciones paragenéticas entre la alteración regional y de las zonas mineralizadas, isótopos estables) muestran que la temperatura y la circulación hidrotermal se incrementaron con el tiempo y que la relación agua-roca evolucionó de valores muy altos a bajos. De acuerdo con nuestros datos, de las rocas volcánicas de Aljustrel se han extraído unas 30 ppm de Cu y unas 100 ppm de Zn. Esto implica, para ambos metales, que la misma roca lixiviada ha producido los 2 Mt de Cu y los 6 Mt de Zn contenidos en los depósitos de sulfuros masivos del área de Aljustrel. En cuanto al Fe, una media de alrededor de 1% fue extraída de las rocas, produciendo metal suficiente para explicar todo el Fe de los depósitos de sulfuros masivos y de los sedimentos químicos suprayacentes. Este estudio documenta de forma semicuantitativa la procedencia de los principales metales en depósitos mayores de sulfuros masivos, mediante lixiviado por agua de mar de sus rocas huéspedes inmediatas.

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Received: 1 February 1997 / Accepted: 30 July 1997     

Flexible spectral methods for the generation of random fields with power-law semivariograms

Random field generators serve as a tool to model heterogeneous media for applications in hydrocarbon recovery and groundwater flow. Random fields with a power-law variogram structure, also termed fractional Brownian motion (fBm) fields, are of interest to study scale dependent heterogeneity effects on one-phase and two-phase flow. We show that such fields generated by the spectral method and the Inverse Fast Fourier Transform (IFFT) have an incorrect variogram structure and variance. To illustrate this we derive the prefactor of the fBm spectral density function, which is required to generate the fBm fields. We propose a new method to generate fBm fields that introduces weighting functions into the spectral method. It leads to a flexible and efficient algorithm. The flexibility permits an optimal choice of summation points (that is points in frequency space at which the weighting function is calculated) specific for the autocovariance structure of the field. As an illustration of the method, comparisons between estimated and expected statistics of fields with an exponential variogram and of fBm fields are presented. For power-law semivariograms, the proposed spectral method with a cylindrical distribution of the summation points gives optimal results.     

Seismic Hazard Studies in the U.K.: Source Specification Problems of Intraplate Seismicity

Although the U.K. is in an area of only low to moderate seismicity, the seismic hazard is sufficient to pose a threat to sensitive structures such as chemical plants and nuclear facilities. In quantifying the level of hazard by conventional probabilistic methodology, however, some problems arise in attempting to interpret earthquake data in terms of geological structure and faults. In the U.K., not only is it impossible to identify any demonstrably active faults, but also it is extremely difficult to discern any relationship between the pattern of seismicity and local or regional geological structure.This study discusses the use of two zonation approaches which complement each other in such a way that the general character and trend of seismicity is preserved. In one approach, the zonation is informed by the structural geology, where possible; geological zonation is avoided if it produces sources with heterogeneous seismicity. In the other approach, the record of past earthquakes is divided up into very small zones around individual epicentres or groups of epicentres, the size of each zone usually being proportional to the uncertainty in the epicentral determination of the appropriate event. This zonation preserves an observed tendency of some British earthquakes to repeat themselves. It is suggested that, in intraplate areas such as the U.K., it is often inappropriate to attempt to model individual fault sources. No faults in the U.K. are provably active. Because an earthquake of moderate size can occur on a very short fault segment, it is impractical to restrict fault modelling to major features. Even the two largest U.K. faults, suspected to be active, pose problems in attributing historical seismicity to them as distinct features.     

Accretion and exhumation at a Variscan active margin, recorded in the Saxothuringian flysch

The Saxothuringian flysch basin, on the north flank of the Central European Variscides, was fed and eventually overthrust by the northwestern, active margin of the Tepla-Barrandian terrane. Clast spectra, mineral composition and isotopic ages of detrital mica and zircon have been analyzed in order to constrain accretion and exhumation of rocks in the orogenic wedge. The earliest clastic sediments preserved are of early Famennian age (ca. 370?Ma). They are exposed immediately to the NW of the suture, and belong to the par-autochthon of the foreland. Besides ultramafic (?ophiolite) material, these rocks contain clasts derived from Early Paleozoic continental slope sediments, originally deposited at the NW margin of the Saxothuringian basin. These findings, together with the paleogeographic position of the Famennian clastics debris on the northwestern passive margin, indicate that the Saxothuringian narrow ocean had been closed by that time. Microprobe analyses of detrital hornblendes suggest derivation from the “Randamphibolit” unit, now present in the middle part of the Saxothuringian allochthon (Münchberg nappes). Detrital zircons of metamorphic rocks formed a little earlier (ca. 380?Ma) indicate rapid recycling at the tectonic front. The middle part of the flysch sequence (ca. early to middle Viséan), both in the par-autochthon and in the allochthon, contains abundant clasts of Paleozoic rocks derived from the northwestern slope and rise, together with debris of Cadomian basement, 500-Ma granitoids and 380?Ma (early Variscan) crystalline rocks. All of these source rocks were still available in the youngest part of the flysch (c. middle to late Viséan), but some clasts record, in addition, accretion of the northwestern shelf. Our findings permit deduction of minimum rates of tectonic shortening well in excess of 10–30?mm per year, and rates of exhumation of ca. 3?mm/a, and possibly more.     

Metamorphism of mafic dikes from the central White-Inyo Range, eastern California

Thin mafic dikes, possibly correlative with the Independence dike swarm of SE California, transect uppermost Proterozoic–Cambrian metasedimentary strata in the White-Inyo Range. Textures and bulk-rock chemistry indicate that the protoliths were diabases and microdiorites, accompanied by Ca + Mg + Fe +Ni + Cr-rich hornblende (± minor augite) cumulates. Analytical data suggest crystal settling and fractionation at shallow depths. Most of the dikes lie in the mapped aureoles of – and were metamorphosed by – voluminous Late Jurassic granitoid plutons; however, a few metadikes cut these plutons and must have been recrystallized during the emplacement of Cretaceous granitic stocks. The mafic metadikes thus include members of two or more temporally distinct suites, pre-Late Jurassic, and latest Jurassic–Cretaceous. Neoblastic mineral assemblages and element partitioning within these nonfoliated mafic metadikes reflect lower-to-upper greenschist facies overprints; metamorphic parageneses, coincident with those developed in the metasedimentary wallrocks, are defined by the production of chlorite, biotite, white mica, epidote, and actinolite, and by albitization of the igneous plagioclase. Based on analytical and mineralogic data obtained in this study, the following conclusions regarding subsolidus recrystallization of the mafic metadikes are advanced: (1) Newly grown minerals and phase assemblages are systematic in their areal distributions. (2) Metamorphic grade increases chiefly toward the north and east, toward the Late Jurassic granitoids. (3) Element fractionation among coexisting neoblastic phases is regular, and compatible with a close approach to chemical equilibrium. (4) Assemblages 3–5 km from the granitic intrusive contacts reflect lowermost greenschist facies physical conditions. (5) Investigated mafic dikes exhibit mineral parageneses isofacial with the regional/contact metamorphic assemblages previously documented for the enclosing pre-Mesozoic clastic country rocks. Clearly, mafic dikes of several ages of injection and recrystallization are present in the central White-Inyo Range, making correlation with the Independence dike swarm problematic. In any case, the dikes record localized contact metamorphism that took place sporadically over portions of an approximately 100 million year interval. Received: 13 March 1996 / Accepted: 24 December 1996     

Argillite debris converted to bauxite during karst weathering: evidence from immobile element geochemistry at the Olmedo Deposit, Sardinia

The Olmedo bauxite deposit occurs in the Nurra district of northwest Sardinia. It forms a stratiform horizon in Cretaceous limestone and marl. Uplift in mid-Cretaceous had exposed recently deposited limestone to karst weathering, and a layer of argillaceous debris accumulated on its surface and was partly converted to bauxite. Intermediate products were desiccated marl, bauxitic argillite and argillaceous bauxite. Subsidence followed, and the bauxite was preserved by the deposition of late Cretaceous limestone and other sediments. Uplift in Oligocene-Miocene time, with ensuing erosion, exposed the bauxite horizon to its present configuration. Concentrations of normative minerals illustrate chemical processes and the build-up of Al in the bauxite horizon. Plots of chemical data and correlation coefficients show that Al, Ti, Zr, Nb, Th, Cr and V were immobile during the bauxitization process. Mass changes point to large net removal of Si, Mg and K from the system, although some of this material and slightly mobile Al were reprecipitated in the underlying argillite and altered marl. Immobile element ratios trace the source of the bauxite to the underlying argillaceous limestone. Al in the bauxite was accumulated from the degradation of 25 to 50 m of the argillaceous limestone. Received: 10 June 1996 / Accepted: 15 April 1997     

Estimation of groundwater evaporation and salt flux from Owens Lake, California, USA

Groundwater evaporation and subsequent precipitation of soluble salts at Owens Lake in eastern California have created one of the single largest sources of airborne dust in the USA, yet the evaporation and salt flux have not been fully quantified. In this study, we compare eddy correlation, microlysimeters and solute profiling methods to determine their validity and sensitivity in playa environments. These techniques are often used to estimate evaporative losses, yet have not been critically compared at one field site to judge their relative effectiveness and accuracy. Results suggest that eddy correlation methods are the most widely applicable for the variety of conditions found on large playa lakes. Chloride profiling is shown to be highly sensitive to thermal and density-driven fluxes in the near surface and, as a result, appears to underestimate yearly groundwater evaporation. Yearly mean groundwater evaporation from the playa surface estimated from the three study areas was found to range from 88 to 104 mm year⁻¹, whereas mean evaporation from the brine-covered areas was 872 mm year⁻¹. Uncertainties on these mean rates were estimated to be ±25%, based on comparisons between eddy correlation and lysimeter estimates. On a yearly basis, evaporation accounts for approximately 47 × 10⁶ m³ of water loss from the playa surface and open-water areas of the lake. Over the playa area, as much as 7.5 × 10⁸ kg (7.5 × 10⁵ t) of salt are annually concentrated by evaporation at or near the playa surface, much of which appears to be lost during dust storms in area.