Cumberland Falls chondritic inclusions: Mineralogy/petrology of a forsterite chondrite suite

As previously found for a chondritic inclusion of unknown affinity, mineralogic and petrologic properties of 9 inclusions in the Cumberland Falls enstatitc achondrite are primitive members of the forsterite (F) chondrite group, hitherto defined by 4 meteorites of similar redox state. The inclusions define a primitive suite with properties indicating 8 as F3 and one of even lower petrologic type. The abundant minerals include: low-Ca pyroxene, olivine, plagioclase, kamacite, taenite, schreibersite, troilite, ferroan alabandite and daubreelite. Diopside, oldhamite and a Ti-rich sulfide are present in one or two inclusions. Petrologic textures and jadeitic pyroxene, hitherto unidentified in meteorites, indicate substantial degree of shock. The inclusions acquired their chemical characteristics during nebular condensation and accretion over a broad redox range (metal-silicate trends in them verify Prior's Rules): their parent body later impacted the enstatite meteorite parent body. During impact, the inclusions were shocked and incorporated with enstatite achondrite host as a breccia that would become Cumberland Falls.     

Kinetic and equilibrium study of Ni(II) sorption from aqueous solutions onto Peganum harmala-L

In this study, the adsorption behavior of Ni(II) in an aqueous solution system using natural adsorbent Peganum harmala-L was measured via batch mode. The prepared sorbent was characterized by scanning electron microscope, Fourier transform infrared spectroscopy, N₂ adsorption–desorption and pH_zpc. Adsorption experiments were carried out by varying several conditions such as contact time, metal ion concentration and pH to assess kinetic and equilibrium parameters. The equilibrium data were analyzed based on the Langmuir, Freundlich, Temkin and Dubinin–Radushkevich isotherms. Kinetic data were analyzed using the pseudo-first-order, pseudo-second-order and intra-particular diffusion models. Experimental data showed that at contact time 60 min, metal ion concentration 50 mg/L and pH 6, a maximum amount of Ni(II) ions can be removed. The experimental data were best described by the Langmuir isotherm model as is evident from the high R ² value of 0.988. The adsorption capacity (q _m) obtained was 68.02 mg/g at an initial pH of 6 and a temperature of 25 °C. Kinetic studies of the adsorption showed that equilibrium was reached within 60 min of contact and the adsorption process followed the pseudo-first-order model. The obtained results show that P. harmala-L can be used as an effective and a natural low-cost adsorbent for the removal of Ni(II) from aqueous solutions.     

Symplectites in upper mantle peridotites: Development and implications for the growth of subsolidus garnet,pyroxene and spinel

Silicate-oxide symplectites in complex mineral intergrowths are relatively common in upper mantle xenoliths and in xenoliths in the Jagersfontein Kimberlite, South Africa.Harzburgites of olivine and high-Al (1.9–3.6 wt%), Ca (0.6–0.9 wt%) and Cr (0.3–0.9 wt%) enstatite contain symplectites of spinel and diopside, or spinel, diopside and lower-Al (0.8–2.2 wt%), Ca (0.1–0.4 wt%) and Cr (0.02–0.8 wt%) enstatite. From textures and mineral chemistries these symplectites are interpreted to have formed by mineral unmixing and migration from Al–Ca–Cr discrete enstatite to adjoining mineral interfaces.Garnet harzburgites are composed of large (0.5–1 cm) olivine, equally large discrete low-Al (0.6–1.1 wt%), Ca (0.1–0.5 wt%), and Cr (0.1–0.3 wt%) enstatite and smaller interstitial garnet, diopside, and high-Cr and low-Al spinel. Symplectites are composed of either spinel+diopside+garnet, or garnet+spinel. Spinel diopside garnet symplectites have cores of spinel+diopside, resembling symplectites inharzburgites, but surrounded by rims of garnet or garnet+undigested globular spinel. From textures and chemistries we suggest that the spinel+diopside cores formed from Ca-Al-Cr-rich orthopyroxene initially as a nonstoichiometric homogeneous single phase clinopyroxene enriched in Fe, Cr and Al. This was followed by decomposition of the clinopyroxene to diopside+spinel, and subsequent garnet formation in a prograde reaction with olivine or enstatite. In bothharzburgites andgarnet harzburgites the metastable cellular structures may also have formed by the simultaneous precipitation of pyroxene and spinel. In all cases there is a strongly preferred embayment of symplectite bodies into olivine. Olivine appears to have activated adjacent     

Regional distribution of white K-mica polymorphs and their phengite content in the Central Alps

Some 150 white K-micas from the Central Alps were analysed for their polymorph and phengite content. Pre-Alpine white K-micas and those belonging to the Meso-Alpine Lepontine Metamorphic “High” show exclusively the 2M₁ polymorph. The 3T structural form, on the other hand, has been found in one third of the white K-micas formed during the Alpine regional metamorphism. In most cases this trigonal structure coexists with varying amounts of the 2M₁ form. The 3T distribution pattern suggests that this polymorph originated during the Eo-Alpine high-pressure/“low temperature” metamorphism. Provided this interpretation is correct, the sporadic occurrence of this polymorph within the Meso-Alpine staurolite zone may be used as a tracer for the Eo-Alpine metamorphism. The following improved correlation between the (060, 331) reflections of 2M₁ white K-micas and the RM-content (= 2Fe₂O₃+FeO+MgO in molar proportions), based on 24 micas from granitoid rocks, is presented: d(060, 331)= 1.498+0.082 RM. The phengite content of Alpine white K-micas belonging to the assemblage muscovite-biotite-K-feldspar-quartz was estimated from RM values or derived from chemical analyses and was found to be clearly related to metamorphic grade. Phengite-rich micas were formed during the Eo-Alpine high-P/“ low-T” metamorphism while aluminous muscovite was found within the Meso-Alpine thermal high of the Lepontine gneiss area. White K-micas from areas which underwent both the Eo-Alpine and the Meso-Alpine metamorphism display variable phengite contents. Although these micas show Tertiary Rb-Sr and K-Ar ages, the variable phengite content presumably reflects conditions during the Eo-Alpine high-P/“low-T” metamorphism. This interpretation implies that the cations occupying the interlayer positions are more easily equilibrated than those in octahedral and tetrahedral structural sites. A compilation of 3T white K-mica occurrences described in the literature is given in the appendix.     

Pretreatment of high strength waste emulsions by combined vibratory shear enhanced process with Fenton oxidation

Pretreatment of waste emulsions with high organic content by a combined process of vibratory shear enhanced process and Fenton’s oxidation prior to biological treatment was investigated. Vibrating membrane had shown good performance in chemical oxygen demand and oil removals and the mitigation of concentration polarization. However, the permeate after filtration processing still contained high content of organics. Thus, additional Fenton oxidation was applied to reduce the organic loading, and improve the biodegradability of the wastewater. The optimal molar ratio of ferrous iron to hydrogen peroxide was 0.05 obtained from the jar-test experiments. Removal of organics was enhanced by increasing hydrogen peroxide dosage, while efficiency of hydrogen peroxide reached maximum of 1.11(w/w) at the hydrogen peroxide dosage of 6.8 g/L. Furthermore, the biological experiments indicated that the high concentration of organics could inhibit microbial activity, which decreased the chemical oxygen demand degradation rates. The adaptive period of the microbe was greatly shortened using Fenton’s reagent at the low dosages. The improvement of the biodegradability could be explained by partial mineralization and chemical transformation of parent organic compounds after Fenton oxidation.     

Petrology and Emplacement of Reversely Zoned Gabbro-Diorite Plutons in the Smartville Complex, Northern California

Gabbroic plutons are part of the intrusive substructure of theSmartville Complex, a late Jurassic, rifted, ensimatic arc locatedin the northern Sierra Nevada of California. The plutons rangefrom unzoned, equant bodies of olivine gabbro less than 1 kmin diameter to elongate intrusions up to 25 km in length thatare reversly zoned from olivine gabbro cores to quartz dioriterims. The felsic rocks dip inward beneath the mafic core, indicatingthat this zoning reversal continues to depth. The zoned plutonshave relatively shallow keels. We interpret the reversed zoningas an emplacement feature, analogous to the compositional zoningin a zoned tephra sheet. It formed as a result of tapping analready zoned, deeper level magma chamber. Whether the originalzoning of the magma was concentric or stratiform cannot be readilydeduced. During emplacement, considerable amounts of cumulaterocks were mobilized. The mineralogy and geochemistry of the reversely zoned plutonsindicate that they contain two suites of rocks: a cumulate suiterepresented by olivine gabbro and olivine clinopyroxenite anda differentiated suite of non-cumulate olivine gabbros, gabbronorites,and diorites that lie along a compositional continuum and approximateliquid compositions. Plagioclase and olivine compositions inthe Smartville Complex cumulate suite are identical to thosein modern arc cumulates and are characteristic of the arc cumulatesuite. The differentiated rocks form a compositionally continuousseries that is geochemically very similar to a differentiatedsuite of arc tholeiitic basalts and andesites. Fractionationmodeling indicates that removal of mineral phases found in thecumulate gabbros from the mafic members of the differentiatedsuite can produce the lithologic variation seen in the zonedplutons. Plutons such as those in the Smartville Complex indicatethat there is a genetic link between cumulate rocks and a basalt-andesitefractionation trend in arcs, supporting the hypothesis thatarc andesites form by crystal fractionation. The gabbroic plutonsand related Alaska-type ultramafic complexes contain ultramaficcumulates that can rectify the discrepancy between the cumulatemode predicted by fractionation models and the observed modeof gabbroic cumulates in arcs.     

Thermal expansion of anhydrous Mg-cordierite between 25 and 950° C

Thermal expansion measurements on synthetic orthorhombic Mg-cordierite (“low cordierite”), Mg₂Al₄Si₅O₁₈, were carried out with a high-temperature X-ray Guinier camera. The measurements confirm previous studies reporting low thermal expansion and suggesting a closer relationship with ring rather than framework silicates. No indication for structural modifications correlated with symmetry changes was observed. However, two discontinuities in the thermal expansion function at 275±25° and 600±50° C were detected and are assumed to represent higher-order phase transitions. The first discontinuity is related to a minimum in specific volume, implying unusual expansion behavior (negativ thermal coefficient) at low temperatures. An estimate of the dP/dT-slope of the established discontiniuties yields a positive sign for the one at 275° C and a negative one for that at 600° C.     

Chemical fractionations in meteorites—X. Ureilites

Four ureilites (Dyalpur, Goalpara, Haverö, and Novo Urei) were analyzed by radiochemical neutron activation analysis for Ag, Au, Bi, Br, Cd, Cs, Ge, In, Ir, Ni, Rb, Re, Sb, Se, Te, Tl, and U. An attempt has been made to resolve the data into contributions from the parent ultramafic rock and the injected, carbon- and gas-rich vein material. Interelement correlations, supported by analyses of separated vein material (WANKE et al, 1972), suggest that the vein material is enriched about 10-fold in refractory Ir and Re over moderately volatile Ni and Au, and is low in volatiles except Ge, C, and noble gases. It appears to be a refractory-rich nebular condensate that precipitated carbon by surface catalytic reactions at ˜500K and trapped noble gases but few other volatiles. The closest known analogue is a Cr- and C-rich fraction from the Allende meteorite, highly enriched in heavy noble gases and noble metals. By analogy with Allende, the gas-bearing phase in ureilites may have been an Fe, Cr-sulfide.

The ultramafic rock contains siderophiles and chalcophiles (Ni, Au, Ge, S, Se) at ˜0.05 of Cl chondrite level, and highly volatile elements (Rb, Cs, Bi, Tl, Br, Te, In, Cd) at ˜0.01 Cl level. It probably represents the residue from partial melting of a C3V-like chondrite body, under conditions where phase separation was incomplete so that some liquid was retained. The vein material was injected into this rock at some later time.     

The peterson limestone — early cretaceous lacustrine carbonate deposition in western wyoming and southeastern idaho

The lacustrine Peterson Limestone of western Wyoming and southeastern Idaho comprises six lithofacies throughout its 20,000 km² aerial extent. These are: (1) calcareous sandstone and shale, (2) red nodular limestone, (3) pink sandy micrite, (4) biomicrite, (5) graded silty micrite, and (6) limestone conglomerate. The first two represent floodplain deposition and paleosols, whereas the remaining are shallow nearshore and deeper lacustrine sediments.This sequence was developed in a large fresh, hardwater lake surrounded by fluvial systems and associated flood plains in a warm temperate climate. Well-oxidized sandy terrigenous rocks, together with calcareous paleosol nodules, indicate that flood-plain deposition both preceded and was concurrent with lacustrine carbonate deposition. Micrite and biomicrite formed in deeper parts of the basin while sandy and silty carbonate accumulated in shallower lake-margin areas. Less-calcareous shale units which are interbedded with deeper-water carbonate were deposited either during rapid basin subsidence and deepening of the lake center or during periods of slower carbonate precipitation. Turbidity currents and subaqueous debris flows generated along steeper lake margins, resulted in the deposition of rhythmic layers of graded silty micrite and diamictic limestone conglomerate in the deepest part of the basin. The carbonate-rich sediments comprising these two lithofacies were originally deposited on shallow lake-margin benches and subsequently were transported downslope toward the lake center.Comparison with other carbonate-precipitating lacustrine systems indicates that this lake was not like modern playas. Although no known modern lacustrine system is precisely like Lake Peterson, the flora, fauna, composition, and distribution of facies within modern temperate-region lakes most closely resemble those of the Peterson Limestone.     

Petrology of the Proterozoic Potato River Layered Intrusion, Northern Wisconsin, USA

The Potato River intrusion is a Keweenawan (1100 Ma) mafic plutonemplaced in Keweenawan volcanics and earlier Proterozoic metasedimentaryrocks along the southeastern flank of the Lake Superior syncline.It comprises the following lithostratigraphic zones: a thinto absent Border zone of altered olivine gabbro; a Lower zoneof olivine gabbro; a Picritic zone of picrite and troctolite;a Middle zone of olivine gabbro and leucogabbro; an Upper zoneof quartz leucogabbro and ferrogabbro; and a Roof zone of granophyricand granitic rocks. Fractional crystallization is evident fromcompositional changes in the rocks and cumulus minerals withstratigraphic height. Elements concentrated in the cumulus mineralsolivine and plagioclase (Mg, Fe²⁺, Al, Ca, Ni, Co, Cr, Sr) decreasewith height; elements concentrated in the trapped liquid (Na,K, La, Y, Zr, Nb, Rb, Ba) increase with height; and other elements(Ti, Fe³⁺, P, Ga, V, Sc, Cu, Zn) show complicated behavior relatedto the appearance of additional cumulus phases such as clinopyroxene,Fe-Ti oxides, and apatite. Lower zone rocks contain some sulfide,probably from sulfur derived from the country rock, and theUpper zone has sulfides probably precipitated from an immisciblesulfide liquid. The sulfide-bearing rocks have similaritiesto those of other intrusions, such as Bushveld, Stillwater,and Skaergaard. The picritic and troctolitic rocks of the Picritic zone indicatethat the intrusion was open to additional injections of maficmagma. Roof zone granophyric rocks are residual liquids intrudedalong the upper margin of the intrusion during regional tilting,but Roof zone granitic rocks are probably melted country rock.An attempt is made to estimate by reverse stratigraphic summationthe compositional path of the magma that solidified above thePicritic zone. The first compositions are highly aluminous,which suggests that the upper part of the intrusion has beenenriched in plagioclase by convection-aided crystal sorting.A complementary unit of mafic rocks is not exposed, but it couldbe present down dip. Some of the later compositions are similarto typical Keweenawan high-Al tholeiites. The magma did notundergo extreme iron enrichment, probably because of oxygenfugacity buffering.