Regional metamorphism of some Dalradian pelites in the Buchan area,N.E. Scotland

Regional metamorphic zones, based on mineral assemblages in pelites, are presented for the Dalradian rocks of Aberdeenshire and Banffshire, in the type area of Buchan metamorphism; electron microprobe analyses of cordierite (C), staurolite (S), chlorite (Chl), biotite (B) and white mica (Ms) are reported for rocks from the classic sections of the Banffshire coast and the valley of the Ythan.A low grade biotite zone, separates two NE-SW trending sets of higher grade zones, in which the sequence s defined by the entry of cordierite, andalusite (A) and (in the west only) staurolite. The zones are characterised by the assemblages (with quartz and muscovite) B-Chl, C-B-Chl, A-C-B and S-A-B.The western sequence contains a transition towards higher pressure, Barrovian type, metamorphism. The isograds arise from continuous reactions affecting rocks of restricted bulk composition (M/FM). With increasing grade, there is a regular trend towards more magnesian ranges of composition for the assemblages C-B-Chl, A-C-B and finally (as P increases in the west), S-A-B. The isograds form when these assemblages intersect the most Fe⁺⁺-rich rock compositions present which occurs in each case when the biotite M/FM=40. A complex of divariant equilibria, derived for the system KFMASH, is used to model the natural reactions.     

The measurement of dissolved organic carbon released by phytoplankton

The effects of applied filtration vacuum and incubation time on the release of dissolved organic carbon (DOC) by natural phytoplankton populations dominated by diatoms were examined. The rate of primary production and release of DOC remained reasonably constant during a 5 hour incubation period. The measured release of DOC was found to be quite sensitive to the applied filtration vacuum, ranging from near 2 percent of fixed carbon (neglecting respiration) for gravity-filtered samples to 36 percent for samples filtered at 40 cm Hg vacuum.     

Carbonaceous chondrites—I. Characterization and significance of carbonaceous chondrite (CM) xenoliths in the Jodzie howardite

Mineralogical, chemical, textural, and isotopic studies of the abundant carbonaceous inclusions in the Jodzie howardite are consistent with CM characteristics. These CM xenoliths show regolith alteration on a level comparable to the Murray and Murchison meteorites but less than Nogoya, flow-oriented development of phyllosilicates and ‘poorly characterized phases’, and partial oxidation of sulfides. Temperature-programmed pyrolysis mass spectrometry (25°–1400°C) indicates that gas release patterns of volatiles and hydrocarbon components and percent contents of N(0.15), C(2.3) and S(2.4) are typical of CM meteorites. Release of significant amounts of SO₂ is attributed to the thermal breakdown of ‘poorly characterized phases’ (Fe-Ni-C-S-O) that formed during low temperature aqueous alteration in the CM parent body.Noble gas abundances are well within the reported range of CM meteorites. The fact that the Ne composition is typical for ‘solar’ values and the isotopic structure of Xe is ‘planetary’ argues that these gases were entrapped by different mechanisms. Cosmic ray exposure ages for the xenoliths (³He, 5 × 10⁶; ²¹Ne, 6.7 × 10⁶; ³⁸Ar, 6.9 × 10⁶ yr) agree with the reported exposure age for the eucritic host. Volatile abundances, presence of intact organic molecules, and phyllosilicates in the CM xenoliths preclude regolith temperatures in excess of 200°C after CM incorporation. Mixing of the host and xenoliths probably occurred during a low-velocity collision of main belt asteroids.     

Inter‐laboratory Characterisation of Apatite Reference Materials for Chlorine Isotope Analysis

Here we report on a set of six apatite reference materials (chlorapatites MGMH#133648, TUBAF#38 and fluorapatites MGMH#128441A, TUBAF#37, 40, 50) which we have characterised for their chlorine isotope ratios; these RMs span a range of Cl mass fractions within the apatite Ca₁₀(PO₄)₆(F,Cl,OH)₂ solid solution series. Numerous apatite specimens, obtained from mineralogical collections, were initially screened for ³⁷Cl/³⁵Cl homogeneity using SIMS followed by δ³⁷Cl characterisation by gas source mass spectrometry using both dual‐inlet and continuous‐flow modes. We also report major and key trace element compositions as determined by EPMA. The repeatability of our SIMS results was better than ± 0.10‰ (1s) for the five samples with > 0.5 % m/m Cl and ± 0.19‰ (1s) for the low Cl abundance material (0.27% m/m). We also observed a small, but significant crystal orientation effect of 0.38‰ between the mean ³⁷Cl/³⁵Cl ratios measured on three oriented apatite fragments. Furthermore, the results of GS‐IRMS analyses show small but systematic offset of δ³⁷Cl_SMOC values between the three laboratories. Nonetheless, all studied samples have comparable chlorine isotope compositions, with mean 10³δ³⁷Cl_SMOC values between +0.09 and +0.42 and in all cases with 1s ≤ ± 0.25.     

An SEM study of porosity and grain boundary microstructure in quartz mylonites, Simplon Fault Zone, Central Alps

A backscattered and secondary electron SEM study of the grain boundary microstructure in quartz mylonites sampled along the length of the retrograde Simplon Fault Zone established three characteristic components. (1) Fine isolated pores (≤?1?μm diameter) are scattered across two-grain interfaces, preferentially concentrated on surfaces in extension. Pores are uncommon on three-grain junctions and there is no evidence for fluid interconnectivity along three- and four-grain junctions. The fine porosity may develop by accumulation of original, mainly intragranular fluid inclusions to the grain boundary during deformation and recrystallization and by cavitation of grain boundaries during grain boundary sliding. Dynamic cavitation implies that the “ductile” mylonitic deformation is at least locally dilatant and therefore pressure sensitive. (2) Large “vug”-like pores (up to mm-scale) extend along multi-grain boundaries. Observed in all samples, they are most common in the higher initial temperature, coarse-grained samples with a microstructure dominated by grain boundary migration recrystallization. Grains bordering this connected porosity develop perfect crystal faces, undecorated by fine pores or pits. The irregular “lobate” optical microstructure of many migrating grain boundaries actually consists of a series of straight crystal faces. The coarse porosity is probably due to accumulation during dynamic recrystallization of (CO₂-rich ?) fluid with a high wetting angle against quartz. (3) In one sample, interconnected sinuous ridges, ≤?0.2?μm high, are observed to follow three- and four-grain junctions and disjoint into more isolated worms and spheroidal globules. On two-grain interfaces, these are transitional to more branching vein-like or convoluted brain-like forms. The brain-like and globular forms have been observed, with varying frequency, through the range of samples, with the globules attaining sizes of up to 60?μm. Vein structures have also been observed on intragranular fractures. These topologies do not match across adjoining surfaces and must have developed into free space. The ridge-vein-brain-spheroid structure is distinctly different to that previously observed on experimentally healed microcracks and its origin is not unequivocally established. They could represent unstable meniscus necking of a thin grain-boundary phase of low viscosity, developed due to quasi-adiabatic shear and/or local stress-induced dilatancy during microcracking.     

Hydrogen and oxygen isotope exchange reactions between clay minerals and water

The extent of hydrogen and oxygen isotope exchange between clay minerals and water has been measured in the temperature range 100–350° for bomb runs of up to almost 2 years. Hydrogen isotope exchange between water and the clays was demonstrable at 100°. Exchange rates were 3–5 times greater for montmorillonite than for kaolinite or illite and this is attributed to the presence of interlayer water in the montmorillonite structure.Negligible oxygen isotope exchange occurred at these low temperatures. The great disparity in D and O¹⁸ exchange rates observed in every experiment demonstrates that hydrogen isotope exchange occurred by a mechanism of proton exchange independent of the slower process of O¹⁸ exchange.At 350° kaolinite reacted to form pyrophyllite and diaspore. This was accompanied by essentially complete D exchange but minor O¹⁸ exchange and implies that intact structural units in the pyrophyllite were inherited from the kaolinite precursor.     

Effective livelihood adaptation to climate change disturbance: Scale dimensions of practice in Mozambique

Natural resource-dependent societies in developing countries are facing increased pressures linked to global climate change. While social-ecological systems evolve to accommodate variability, there is growing evidence that changes in drought, storm and flood extremes are increasing exposure of currently vulnerable populations. In many countries in Africa, these pressures are compounded by disruption to institutions and variability in livelihoods and income. The interactions of both rapid and slow onset livelihood disturbance contribute to enduring poverty and slow processes of rural livelihood renewal across a complex landscape. We explore cross-scale dynamics in coping and adaptation response, drawing on qualitative data from a case study in Mozambique. The research characterises the engagements across multiple institutional scales and the types of agents involved, providing insight into emergent conditions for adaptation to climate change in rural economies. The analysis explores local responses to climate shocks, food security and poverty reduction, through informal institutions, forms of livelihood diversification and collective land-use systems that allow reciprocity, flexibility and the ability to buffer shocks. However, the analysis shows that agricultural initiatives have helped to facilitate effective livelihood renewal, through the reorganisation of social institutions and opportunities for communication, innovation and micro-credit. Although there are challenges to mainstreaming adaptation at different scales, this research shows why it is critical to assess how policies can protect conditions for emergence of livelihood transformation.     

Kinetics of Cd sorption, desorption and fixation by calcite: A long-term radiotracer study

Time-dependent sorption and desorption of Cd on calcite was studied over 210 days utilizing ¹⁰⁹Cd as a tracer to distinguish between ‘labile’ and ‘non-labile’ forms of sorbed Cd. Stabilizing the calcite suspensions for 12 months under atmospheric P_CO2 and controlled temperature was necessary to reliably follow Cd dynamics following initial sorption. Results revealed time-dependant Cd sorption and marked desorption hysteresis by calcite under environmentally relevant conditions. Data obtained were fitted to a first-order kinetic model and a concentric shell diffusion model. Both models described the progressive transfer of Cd²⁺ to a less reactive form within calcite and subsequent desorption of Cd subject to different initial contact times. The kinetic model provided a better fit to the combined sorption and desorption data (R² = 0.992). It differentiates between two ‘pools’ of sorbed Cd²⁺ on calcite, ‘labile’ and ‘non-labile’, in which labile sorbed Cd is in immediate equilibrium with the free Cd²⁺ ion activity in solution whereas non-labile Cd is kinetically restricted. For the diffusion model (R² = 0.959), the rate constants describing Cd dynamics in calcite produced a half-life for Cd desorption of ∼175 d, for release to a ‘zero-sink’ solution. Results from this study allow comment on the likely mechanisms occurring at the calcite surface following long-term Cd sorption.