The geochemistry of sulphur in a mixed allogenic–autogenic karst catchment,Castleton, Derbyshire,UK

Analyses are presented of anion chemistry and sulphur isotopic compositions of sulphate in sinking streams and groundwaters in a mixed allogenic–autogenic karst catchment. Using the sulphur isotopic data, sources of sulphate from agriculture and the effects of sulphate reduction arising from slurry application can be distinguished from natural rock weathering sources. Within the aquifer, sulphate in known autogenic waters has isotopic compositions distinct from allogenic waters, the autogenic waters being dominated by sulphate from rainfall and rock weathering in these low agricultural intensity catchments. On this basis, water rising at low flow from Whirlpool Rising, Speedwell Cavern, has been identified as dominantly autogenic. Groundwater flow between the sinks and risings in Speedwell Cavern is believed to be along conduits following mineralized faults (rakes). During transit SO42−/Cl− in the water increases. Isotopic mass balance shows that this must be due to addition of sulphate from the oxidation of ore minerals by groundwater. Mass balance considerations show that the present rate of sulphide oxidation must be the result of enhancement by lead mining operations on the rakes. Copyright © 2000 John Wiley & Sons, Ltd.     

Linking local ecological outcomes with basin-wide water planning: a case study of Yanga National Park,an important Australian inland forested wetland

Abstract

Maintaining and restoring the ecological integrity of floodplains remains a priority for many Australian federal and state government agencies. The Murray-Darling Basin Authority (MDBA) introduced the Proposed Basin Plan 2012, the Australian government’s latest basin-scale water planning instrument to promote a healthy, working river system. The proposal seeks to limit surface water (consumptive) use to 10 873 GL year^-1 on a long-term average. The controversy prompted by this proposed reduction has underscored a need for rigorous and transparent modelling of ecological benefits. In this paper, we investigate the likely ecological outcomes of the proposal for Yanga National Park, one of the most significant environmental assets in the Murray-Darling Basin, using a decision support system. Our results indicate that the proposal will increase the inundation extent with a 33% (or 7000 ha) increase in median flood. The increase in inundation would improve the hydrological conditions in most wetlands in terms of the frequency and duration of events and inter-flood dry periods and enhance the habitat quality for a range of biota, though benefits are not distributed evenly across the wetland.

Editor D. Koutsoyiannis; Guest editor M. Acreman

Citation Wen, L. and Saintilan, N., 2014. Linking local ecological outcomes with basin-wide water planning: a case study of Yanga National Park, an important Australian inland forested wetland. Hydrological Sciences Journal, 59 (3–4), 904–915.     

13C12C exchange between calcite and graphite: A possible thermometer in Grenville marbles

The fractionation of ¹³C between calcite and graphite, Δ(Cc-Gr). is consistently small (2.6–4.8 permil) in 34 assemblages from upper amphibolite- and granulite-facies marbles of the Grenville Province. In 25 samples from the Adirondack Mountains, New York, it decreases regularly with increasing metamorphic temperature. The fractionations are independent of absolute δ¹³C values of calcite (?2.9 to +5.0). For T = 600–800°C, the Adirondack data are described by Δ(Cc-Gr) = ?0.00748T (°C) + 8.68. This good correlation between Δ and T suggests that carbon isotope equilibrium was attained in these high-grade marbles and that the theoretical calculations of this fractionation by Bottinga are approximately 2 permil too large in this temperature range. Because of the relatively high temperature sensitivity suggested by these results and by Bottinga's calculations, and the pressure independence of isotope fractionation, Δ(Cc-Gr) may provide a very good thermometer for high-grade marbles.Comparison of this field calibration for Δ(Cc-Gr) vs temperature with results from other terranes supports the utility of Δ(Cc-Gr) for geothermometry and suggests that graphite is much more sluggish to exchange than calcite, that exchange between calcite and graphite occurs at temperatures as low as 300°C, and that equilibrium may normally be attained only when peak metamorphic temperatures are greater than 500–600°C.Because ¹³C exchange is an unavoidable metamorphic process at temperatures above 300°C, high values of δ¹³C(Gr) in moderate- to high-grade carbonate-bearing rocks do not provide a sufficient criterion to infer an abiogenic origin for the graphite.     

The decay of the mean solar magnetic field

We have analyzed the effects that differential rotation and a hypothetical meridional flow would have on the evolution of the Sun's mean line-of-sight magnetic field as seen from Earth. By winding the large-scale field into strips of alternating positive and negative polarity, differential rotation causes the mean-field amplitude to decay and the mean-field rotation period to acquire the value corresponding to the latitude of the surviving unwound magnetic flux. For a latitudinally broad two-sector initial field such as a horizontal dipole, the decay is rapid for about 5 rotations and slow with a t ^–1/2 dependence thereafter. If a poleward meridional flow is present, it will accelerate the decay by carrying the residual flux to high latitudes where the line-of-sight components are small. The resulting decay is exponential with an e-folding time of 0.75 yr (10 rotations) for an assumed 15 m s^–1 peak meridional flow speed.E.O. Hulburt Center for Space Research.Laboratory for Computational Physics.     

激光拉曼光谱法分析多种显微组分荧光变化及其应用

利用激发488 nm激光的氩离子激光器作为RENISHAW inVia型激光拉曼光谱仪的光源,建立了多种显微组分荧光变化(FAMM)分析方法,并对镜质体反射率明显抑制的东营凹陷有效烃源岩进行了测定。结果表明,东营凹陷有效烃源岩的有机质类型越好,镜质体反射率抑制程度越高,有效烃源岩的真实成熟度应主要处于0.64%~1.30%,而不是实测镜质体反射率所反映的0.37%~1.10%。     

The contribution of the land surface energy balance complexity to differences in means, variances and extremes using the AMIP-II methodology

This paper explores the relationship between the complexity of the land surface energy balance parameterization and the simulation of means, variances and extremes in a climate model. We used the BMRC climate model combined with the protocol of AMIP-II to perform six ensemble simulations for each of four levels of surface energy balance complexity. Our results were then compared with other AMIP-II results in terms of the mean, variance and extremes of temperatures and precipitation. In terms of the zonally-averaged mean and the maximum temperatures and precipitation, the surface energy balance complexity did not systematically affect the BMRC climate model results. The zonal minimum temperature was affected by the inclusion of tiling and/or a temporally variable canopy conductance. We found no evidence that surface energy balance complexity affected the globally- or zonally-averaged variances. Some quite large differences were identified in the probability density functions of maximum (10 K) and minimum (4 K) temperature caused by surface tiling and/or the inclusion of a time-varying canopy conductance. With these included, the model simulated a higher probability of cooler minima and warmer maxima and therefore a different diurnal temperature range. Adding interception of precipitation led to an increase in the likelihood of more extreme precipitation. Thus, provided interception, surface tiling and a time-variable stomatal conductance are included in a land surface model, the impact of other uncertainties in the parameterization of the surface energy balance are unlikely to limit the use of climate models for simulating changes in the extremes. Most published results indicating changes to precipitation and temperature extremes due to increasing carbon dioxide are therefore unlikely to be significantly limited by uncertainty in how to parameterize the surface energy balance. Given that the variations in surface energy balance complexity included in our experiments approximates the range included in the AMIP-II models, we conclude that it this is unlikely to explain the differences found between the AMIP-II simulations. This does not mean that AMIP-II differences are not caused to a significant degree by differences in their respective LSMs, rather it limits the potential role of the land surface to non-surface energy balance components, or components (such as carbon) that are not considered here.