Gridded Croatian climatology for 1961–1990

In climatology, one of the most important pieces of information about the climate of a place or a region is information about the Climatological Normals (CLINO)—the average values of meteorological elements for a 30-year period. This kind of information usually comes in tables and is available for different observation sites from national meteorological services or from World Meteorological Organisation publications. The key issue, then, becomes how to interpolate these values over the entire area of interest to get reliable and accurate estimates (maps) of climatic elements. Here, the regression kriging framework has been applied for mapping of 20 climatological parameters for the 1961–1990 period for the 56,594 km² of Croatian territory, with a resolution of 1 km. In total, 152 main and climatological and 567 precipitation-measuring stations have been used in the analysis. Extensive pre-processing of metadata on station co-ordinates has been done, as well as completion of missing monthly averages. The final results are 20 climatological maps available in high resolution together with error maps and accuracy assessment measures.     

Polycyclic aromatic hydrocarbons and their molecular diagnostic ratios in urban atmospheric respirable particulate matter

Atmospheric concentrations of polycyclic aromatic hydrocarbons (PAHs) in Santiago de Chile city were evaluated to study particulate PAHs profiles during cold and spring weather periods. Urban atmospheric particulate matter PM10 was collected using High Volume PM10 samplers. Fifteen samples of 24 h during austral winter and 20 samples of 24 h during spring, 2000 were collected at two sampling sites (North–East and Central areas of the city) whose characteristics were representative of the prevailing conditions. Seventeen PAHs were quantified and total PAHs concentration ranged from 1.39 to 59.98 ng m⁻³, with a seasonal variation (winter vs. spring ratio) from 0.5 to 12.6 ng m⁻³. Molecular diagnostic ratios were used to characterize and identify PAHs emission sources such as combustion and biogenic emissions. Results showed that the major sources of respirable organic aerosol PM10 in Santiago are mobile and stationary ones.     

Genetic and chemical relationships between berthierine,chlorite and cordierite in nodules associated to granitic pegmatites of Sierra Albarrana (Iberian Massif,Spain)

Chlorite and berthierine occur through alteration of cordierite within enclaves of metamorphic rocks transformed by the Sierra Albarrana pegmatites. The coexistence of both phyllosilicates allows us to study their stability relationships and to compare their chemical compositions. Samples showing incipient replacement of cordierite by small cryptocrystalline aggregates can be identified by X-ray diffraction (XRD) as berthierine with small quantities of chlorite. Electron Microprobe (EMP) analyses give mixed compositions of berthierine and cordierite. Samples with extensive replacement of cordierite by aggregates show similar characteristics to those with incipient replacement, but some small crystals are present. The last type of sample shows complete replacement of cordierite by crystals showing optical properties of chlorite and EMPA compositions coherent with chlorite or berthierine. Their XRD pattern corresponds to chlorite and their high resolution transmission electron microscopy (HRTEM) images only show perfect sequences of 14 Å lattice fringes. The cryptocrystalline aggregates of the samples with incipient and extensive replacement present coexistent areas of 14 Å and 7 Å lattice fringes that are intergrown at different levels: (1) large areas (> 1 m) of 7 Å layers; (2) packets of 7 Å layers between 14 Å layer areas, with visible 7 Å to 14 Å lateral changes; (3) random mixed-layers 7 Å/14 Å. Chlorite is the final stable product of alteration of cordierite, with berthierine as an intermediate metastable phase. Energy dispersive X-ray spectrometry microanalyses of 14 Å, 7 Å and (14+7) Å areas show lack of systematic differences in chemical compositions between both phyllosilicates which may be considered as true polymorphs.     

A note on the performance of the multiply-upstream semi-Lagrangian advection schemes for one-dimensional nonlinear momentum conservation equation

Summary Two-time-level multiply-upstream semi-Lagrangian schemes were examined in the case of the self-advecting, one-dimensional nonlinear momentum conservation equation. The shock formation process was analyzed. It is pointed out that the shocks cannot be created in the truncated systems satisfying the Pudykiewicz, Benoit and Staniforth criterion.The numerical integrations were restricted to 12 h. It was shown that, at least in the sub-CFL range, increased complexity of the scheme can compensate reduced horizontal resolution. A considerable sensitivity of the schemes with respect to the time step was detected. In the super-CFL mode, several windows on various time scales were found within which the Pudykiewicz, Benoit and Staniforth criterion was satisfied. The time step of 1.44 times the maximum time step allowed by the CFL criterion was used in the semi-Lagrangian runs.The super-CFL, semi-Lagrangian solutions were diverging progressively from the sub-CFL ones as the forecasts advanced. This was also reflected in the energy spectra.Unacceptably large energy losses were encountered in the super-CFL, semi-Lagrangian runs. Most of these losses could be explained by the reduced mean wind speed, i.e., the amplitude of the zero wavenumber wave. At the same time, the energy content in the shorter waves increased. In a more complex model, such a situation would resemble a loss of zonal, and an increase of transient eddy kinetic energy.A trajectory error measure was defined as the maximum absolute value of the distance between the actual arriving point of the particle originating at the estimated departure point, and the grid point assumed to be the arrival point in the semi-Lagrangian procedure. In contrast to the sub-CFL regime, this measure could reach a considerable fraction of the grid distance in the computations with the super-CFL time steps.In the physical system considered, the trajectories are determined only by the velocities at the departure points. With the semi-Lagrangian schemes the distances traveled by the particles are estimated on the basis of the velocities at the points downstream with respect to the departure points. Thus, unless the solution is smooth (in space and time) on the scales of the extrapolation distances/times, the upstream extrapolation does not promise the convergence of the solution.With 16 Figures     

中国北京地区大气臭氧层的基本状态及其与气象要素的相关分析

本文第一次分析研究并给出了中国北京地区大气臭氧层的基本状态:它的总含量、空间分布和时间变化特征;以及这些变化和大气环流及某些气象要素之间可能存在的相关.     

Propagation of the Rossby waves on two dimensional rectangular grids

Summary A simple two-dimensional quasi-geostrophic linearized model of the atmosphere is used to investigate the behaviour of the quasi-geostrophic modes for five horizontal rectangular grids. Numerical expressions for frequencies of Rossby waves for all grids are evaluated. It was found that the B and C grids produce only negative frequencies as well as the continuous case. The D grid has negative and zero frequencies. Finally, it was found that the A and E grids produce positive frequencies and eastward moving Rossby waves.With 2 Figures     

Runoff and sediment yield from land under various uses in a Mediterranean mountain area: long‐term results from an experimental station

In this study we analyzed runoff and sediment yield from land under various traditional and current land uses in Mediterranean mountain areas, using long‐term data from an experimental station in the Aísa Valley, Central Spanish Pyrenees. Monitoring at this station has provided 20 years of data that can help explain the hydrological and geomorphological changes that have been observed at larger spatial scales, and also the changes that have occurred to some of the most characteristic landscapes of the Mediterranean middle mountains. In spite of the problems associated with the use of small experimental plots, the results obtained are consistent with other studies in the Mediterranean region, and confirm the strong influence of land use changes on runoff generation and sediment yield. The results indicate that: (i) cereal cultivation on steep slopes (both alternating cereal cultivation and fallow on sloping fields and shifting agriculture on the steepest slopes) represents a major problem for soil conservation. This explains the occurrence throughout the Mediterranean mountains of many degraded hillslopes, which show evidence of sheet wash erosion, rilling, gullying and shallow landsliding; (ii) farmland abandonment has led to a marked reduction in runoff and sediment yield as a consequence of rapid plant recolonization, particularly by dense shrubs; (iii) the natural transformation of abandoned fields into grazing meadows has reduced runoff and sediment yield. Land use trends in the Mediterranean mountains are mainly characterized by generalized farmland abandonment and a decrease in livestock pressure. From a hydrological and geomorphological point of view the main consequences have been a reduction in overland flow from the hillslopes, and a reduction in sediment sources, with differences up to one order of magnitude in sediment yield from dense shrub cover and grazing meadow areas compared with areas under shifting agriculture. Copyright © 2012 John Wiley & Sons, Ltd.     

Some Insights into Topographic,Elastic and Self-gravitation Interaction in Modelling Ground Deformation and Gravity Changes in Active Volcanic Areas

Surface displacements and gravity changes due to volcanic sources are influenced by medium properties. We investigate topographic, elastic and self-gravitation interaction in order to outline the major factors that are significant in data modelling. While elastic-gravitational models can provide a suitable approximation to problems of volcanic loading in areas where topographic relief is negligible, for prominent volcanoes the rough topography could affect deformation and gravity changes to a greater extent than self-gravitation. This fact requires the selection, depending on local relief, of a suitable model for use in the interpretation of surface precursors of volcanic activity. We use the three-dimensional Indirect Boundary Element Method to examine the effects of topography on deformation and gravity changes in models of magma chamber inflation/deflation. Topography has a significant effect on predicted surface deformation and gravity changes. Both the magnitude and pattern of the geodetic signals are significantly different compared to half-space solutions. Thus, failure to account for topographic effects in areas of prominent relief can bias the estimate of volcanic source parameters, since the magnitude and pattern of deformation and gravity changes depend on such effects.