Effects of biochar, cow bone, and eggshell on Pb availability to maize in contaminated soil irrigated with saline water

Toxicity of heavy metals adversely affects environment and human health. Organic materials derived from natural matters or wastes have been applied to soils to reduce the mobility of contaminants such as heavy metals. However, the application of cow bone powder (CB), biochar (BC), and eggshell powder (ES) is rarely investigated for the reduction of Pb bioavailability in soils irrigated with saline water. The objective of this study was to assess the effectiveness of CB, BC, and ES additions as immobilizing substances on Pb bioavailability in shooting range soil irrigated with deionized and saline water. Each additive of CB, BC, and ES at 5 % (w/w) was mixed with soils and then the deionized and saline water were irrigated for 21 days. With deionized water irrigation, the soils treated with CB, BC, and ES exhibited higher pH when compared with saline water irrigation. With saline water irrigation, the electrical conductivity, water-soluble anions, and cations were significantly increased in soils treated with CB, BC, and ES. The water-soluble Pb in soils treated with CB, BC, and ES was significantly decreased with saline water irrigation. On the other hand, the water-soluble Pb in soil treated with CB was increased with deionized water irrigation. Only BC with saline water irrigation decreased the Pb concentration in maize shoots.     

Contrasting geochemical signatures on land from the Middle and Late Permian extinction events

The end of the Palaeozoic is marked by two mass‐extinction events during the Middle Permian (Capitanian) and the Late Permian (Changhsingian). Given similarities between the two events in geochemical signatures, such as large magnitude negative δ¹³C anomalies, sedimentological signatures such as claystone breccias, and the approximate contemporaneous emplacement of large igneous provinces, many authors have sought a common causal mechanism. Here, a new high‐resolution continental record of the Capitanian event from Portal Mountain, Antarctica, is compared with previously published Changhsingian records of geochemical signatures of weathering intensity and palaeoclimatic change. Geochemical means of discriminating sedimentary provenance (Ti/Al, U/Th and La/Ce ratios) all indicate a common provenance for the Portal Mountain sediments and associated palaeosols, so changes spanning the Capitanian extinction represent changes in weathering intensity rather than sediment source. Proxies for weathering intensity chemical index of alteration, ?W and rare earth element accumulation all decline across the Capitanian extinction event at Portal Mountain, which is in contrast to the increased weathering recorded globally at the Late Permian extinction. Furthermore, palaeoclimatic proxies are consistent with unchanging or cooler climatic conditions throughout the Capitanian event, which contrasts with Changhsingian records that all indicate a significant syn‐extinction and post‐extinction series of greenhouse warming events. Although both the Capitanian and Changhsingian event records indicate significant redox shifts, palaeosol geochemistry of the Changhsingian event indicates more reducing conditions, whereas the new Capitanian record of reduced trace metal abundances (Cr, Cu, Ni and Ce) indicates more oxidizing conditions. Taken together, the differences in weathering intensity, redox and the lack of evidence for significant climatic change in the new record suggest that the Capitanian mass extinction was not triggered by dyke injection of coal‐beds, as in the Changhsingian extinction, and may instead have been triggered directly by the Emeishan large igneous province or by the interaction of Emeishan basalts with platform carbonates.     

Double injection events of mafic magma into supersolidus Yucheon granites to produce two types of mafic enclaves in the Cretaceous Gyeongsang Basin,SE Korea

Petrographic and geochemical features of the Cretaceous Yucheon granites and their mafic microgranular/magmatic enclaves (MMEs), SE Korea, reveal that the MMEs originated from magma mixing. Mesoscopic and microscopic features indicate that mechanical mixing operated heterogeneously to produce the MMEs with a wide range of sizes and textures. Chemical compositions of amphibole, biotite, and plagioclase rims of both the MMEs and host granites are almost identical, indicating that chemical homogenization took place to some extent after the mechanical mixing. Plagioclase cores, however, have various compositions depending on the host rocks and/or sampling locations, suggesting their sluggish re-equilibration. The MMEs are divided into Type A (low TiO₂, very fine-grained, chilled margins) and Type B (high TiO₂, fine- to medium-grained, no chilled margins). The lower TiO₂ MMEs cooled more rapidly and interacted with granitic magma for a shorter period of time than the higher TiO₂ MMEs. Additionally, the former are less enriched in HREEs than the latter. Zoned plagioclase has two zones of increased An content. These features are indicative of double injection events of mafic magma. A previous model explains the magma mixing as resulting from the generation of a slab window due to Kula-Pacific ridge subduction. The model cannot, however, explain the eastward younging of the granites in Korea, necessitating a new, more elaborate model of Cretaceous geodynamics and magmatism in East Asia.     

A GNSS interference identification using an adaptive cascading IIR notch filter

A low-complexity time-domain approach for global navigation satellite systems is proposed to detect and identify single-tone, multi-tone, swept continuous wave interference (CWI) and band-limited white Gaussian noise (BLWN). An adaptive notch filter and adaptive cascading filter structure are employed to identify the type of interference signals. The number of the cascading stages is selected by comparing the total power in receiver bandpass, and after, passing the adaptive notch filter. For this reason, the proposed filter structure is more efficient in identifying and mitigating interference signals than the conventional filter structure. In addition, the automatic gain control gain is used to detect the existence of continuous wave interference. The performance of the interference detection and identification method is evaluated for the cases of GPS signal in the presence of single-tone, multi-tone, swept CWI and BLWN.     

Time‐scale analysis in unsaturated porous media under external wave loads

Extreme waves caused by tsunamis and storm surges can lead to soil failures in the near‐shore region, which may have severe impact on coastal environments and communities. Multiphase flows in deformable porous media involve several coupled processes and multiple time scales, which are challenging for numerical simulations. The objective of this study is to investigate the roles of the various processes and their interactions in multiphase flows in unsaturated soils under external wave loading, via theoretical time‐scale analysis and numerical simulations. A coupled geomechanics–multiphase flow model based on conservation laws is used. Theoretical analysis based on coupled and decoupled models demonstrates that transient and steady‐state responses are governed by pore pressure diffusion and saturation front propagation, respectively, and that the two processes are essentially decoupled. Numerical simulations suggest that the compressibility of the pore fluids and the deformation of the soil skeleton are important when the transient responses of the media are of concern, while the steady‐state responses are not sensitive to these factors. The responses obtained from the fully coupled numerical simulations are explained by a simplified time‐scale analysis based on coupled and decoupled models. Copyright © 2010 John Wiley & Sons, Ltd.     

The impact of highly permeable layer on hydraulic system in a coastal aquifer

This study is aimed to understand the hydraulic mechanism of coastal aquifer systems that include highly permeable layers (HPLs). These hydrologic conditions can be found in many volcanic islands that are composed of a series of lava flows discharged into sea or other standing body of water. In the first part, we developed a numerical model based on the geologic and hydrologic data obtained from the eastern Jeju Island, Korea, of which the aquifer contains clinker and hyaloclastite layers. The simulation results reproduced spatial location of fresh‐saline water interface, especially the abrupt decline of interface at the inland part and the thickness variation of transition zone along the cross‐section observed at the eastern Jeju coastal aquifer. We were able to find out that these phenomena are strongly related to the presence of the HPL. In the second part, quantitative analyses were conducted with the use of hypothetical models in order to understand the dynamic characteristics of coastal system that includes HPLs. A series of sensitivity studies were conducted to assess the effect of the horizontal length and vertical depth of HPL on the spatial location of the interface toe and the configuration of transition zone. Various case studies have shown that the seawater intruded into the inland more as the horizontal length of HPL was increased and its vertical depth was decreased. In other simulations including two HPLs, the vertical distance between these two HPLs primarily controlled the flow regime, flux variations, and the configuration of the transition zone. Finally, we performed simulations to evaluate the effect of a rising sea‐level. This study provides more understanding of how the presence of HPL controls the seawater intrusion processes, and the spatial configurations of fresh‐saline water interface at coastal aquifers. Copyright © 2012 John Wiley & Sons, Ltd.     

Central England temperature since AD 1850: the potential of stable carbon isotopes in British oak trees to reconstruct past summer temperatures

In regions with seasonal temperate climatic regimes, tree growth is rarely controlled by any single environmental factor. As a consequence, the development of robust palaeoclimate reconstructions has proved challenging. Tree‐ring stable carbon isotope ratios (δ¹³C), however, are controlled primarily by photosynthetic rate, not by net growth. Therefore, at sites where climatic controls on tree‐ring growth are not strongly expressed, a robust (isotopic) palaeoclimate signal may still potentially be preserved. This hypothesis was tested using a 160‐year record of δ¹³C measured from the pooled latewood cellulose of six Quercus petraea L. (sessile oak) trees from Allt Lan‐las in West Wales, UK. Raw δ¹³C values were corrected for changes in the isotopic ratio of atmospheric carbon dioxide and for changes in the behaviour of trees due to the increasing availability of atmospheric CO₂ since AD 1850. Strong correlations with local summer temperature and sunshine are reported, and also with the Central England Temperature record over the full length of the isotopic chronology (AD 1850–2010) (r = 0.69, P < 0.001). We conclude that tree‐ring stable isotopes can be used to extract strong palaeoclimate signals even from oak trees growing in a temperate maritime climate. This demonstrates the potential for extracting robust palaeoclimatic information from the very long and well‐replicated oak chronologies which have been developed in western and central Europe primarily for dating rather than palaeoclimatic research purposes. Copyright © 2012 John Wiley & Sons, Ltd.     

A complete relativistic ionized accretion disc in Cygnus X-1

The galactic black hole candidate Cygnus X-1 is observed to be in one of two X-ray spectral states: either the low/hard (low soft X-ray flux and a flat power-law tail) or high/soft (high blackbody-like soft X-ray flux and a steep power-law tail) state. The physical origin of these two states is unclear. We present here a model of an ionized accretion disc, the spectrum of which is blurred by relativistic effects, and fit it to the ASCA , Ginga and EXOSAT data of Cygnus X-1 in both spectral states. We confirm that relativistic blurring provides a much better fit to the low/hard state data and, contrary to some previous results, find the data of both states to be consistent with an ionized thin accretion disc with a reflected fraction of unity extending to the innermost stable circular orbit around the black hole. Our model is an alternative to those that, in the low/hard state, require the accretion disc to be truncated at a few tens of Schwarzschild radii, within which there is a Thomson-thin, hot accretion flow. We suggest a mechanism that may cause the changes in spectral state.