Climate teleconnections influence on West Africa's terrestrial water storage

There is some evidence of rapid changes in the global atmosphere and hydrological cycle caused by the influence of climate variability. In West Africa, such changes impact directly on water resources leading to incessant extreme hydro‐meteorological conditions. This study examines the association of three global climate teleconnections—El‐Niño Southern Oscillation (ENSO), Indian Ocean Dipole (IOD), and Atlantic Multi‐decadal Oscillation (AMO) with changes in terrestrial water storage (TWS) derived from both Modern‐Era Retrospective Analysis for Research and Applications (MERRA, 1980–2015) and Gravity Recovery and Climate Experiment (GRACE, 2002–2014). In the Sahel region, positive phase of AMO coincided with above‐normal rainfall (wet conditions) and the negative phase with drought conditions and confirms the observed statistically significant association (r = 0.62) between AMO and the temporal evolutions of standardised precipitation index. This relationship corroborates the observed presence of AMO‐driven TWS in much of the Sahel region (though considerably weak in some areas). Although ENSO appears to be more associated with GRACE‐derived TWS over the Volta basin (r =?0.40), this study also shows a strong presence of AMO‐ and ENSO‐induced TWS derived from MERRA reanalysis data in the coastal West African countries and most of the regions below latitude 10°N. The observed presence of ENSO‐ and AMO‐driven TWS is noticeable in tropical areas with relatively high annual/bimodal rainfall and strong inter‐annual variations in surface water. The AMO has a wider footprint and sphere of influence on the region's TWS and suggests the important role of North Atlantic Ocean. IOD‐related TWS also exists in West Africa and its influence on the region's hydrology maybe secondary and somewhat complementary. Nonetheless, presumptive evidence from the study indicates that ENSO and AMO are the two major climatic indices more likely to impact on West Africa's TWS.     

Riddle of the Nautilus: Specific Structural Features of Its Shell

The shells of the chambered nautilus (Nautilus pompilius) are studied by X-ray structure analysis (XRD) and electron microscopy (SEM and TEM). The shell structure is examined in a nanometer scale using XRD and synchrotron-based small angle X-ray scattering (SAXS). The mineral composition of shells includes 98–99 wt % aragonite, ~1 wt % organic substance (conchiolin), 1 wt % strontianite, and 0.5 wt % calcite. Trace elements comprise Na, Mg, Al, K, Si, Fe, P, S, Zn, Sr, Ba, and Cl. The laminated layers are composed of aragonite crystals with a width of 5–10 μm and a thickness of 0.5–1 μm; the prismatic layers, with a length of 7–12 μm long and a width of 1–3 μm. According to XRD and SAXS assays, the aragonite layers are formed of flawless monocrystals lacking any internal structuring. The shell conchiolin is a polymer formed of a system of parallel fibers folded with a step of approximately 100 nm without longitudinal structuring. Presumably, the unique structure of the nautilus shells has determined the existence of Nautiloidea over 500 Ma and their preservation as fossils for over 100 Ma.     

To what extent can a long-term temperature target guide near-term climate change commitments?

The question of appropriate timing and stringency of future greenhouse gas (GHG) emission reductions remains an issue in the discussion of mitigation responses to the climate change problem. It has been argued that our near-term action should be guided by a long-term vision for the climate, possibly a long-term temperature target. In this paper, we review proposals for long-term climate targets to avoid ‘dangerous’ climate change. Using probability estimates of climate sensitivity from the literature, we then generate probabilistic emissions scenarios that satisfy temperature targets of 2.0, 2.5, and 3.0°C above pre-industrial levels with no overshoot. Our interest is in the implications of these targets on abatement requirements over the next 50 years. If we allow global industrial GHG emissions to peak in 2025 at 14 GtCeq, and wish to achieve a 2.0°C target with at least 50% certainty, we find that the low sensitivity estimate in the literature suggests our industrial emissions must fall to 9 GtCeq by 2050: equal to the level in 2000. However, the average literature sensitivity estimate suggests the level must be less than 2 GtCeq; and in the high sensitivity case, the target is simply unreachable unless we allow for overshoot. Our results suggest that in light of the uncertainty in our knowledge of the climate sensitivity, a long-term temperature target (such as the 2.0°C target proposed by the European Commission) can provide limited guidance to near-term mitigation requirements.     

The Pacific Decadal Oscillation

The Pacific Decadal Oscillation (PDO) has been described by some as a long-lived El Niño-like pattern of Pacific climate variability, and by others as a blend of two sometimes independent modes having distinct spatial and temporal characteristics of North Pacific sea surface temperature (SST) variability. A growing body of evidence highlights a strong tendency for PDO impacts in the Southern Hemisphere, with important surface climate anomalies over the mid-latitude South Pacific Ocean, Australia and South America. Several independent studies find evidence for just two full PDO cycles in the past century: “cool” PDO regimes prevailed from 1890–1924 and again from 1947–1976, while “warm” PDO regimes dominated from 1925–1946 and from 1977 through (at least) the mid-1990's. Interdecadal changes in Pacific climate have widespread impacts on natural systems, including water resources in the Americas and many marine fisheries in the North Pacific. Tree-ring and Pacific coral based climate reconstructions suggest that PDO variations—at a range of varying time scales—can be traced back to at least 1600, although there are important differences between different proxy reconstructions. While 20th Century PDO fluctuations were most energetic in two general periodicities—one from 15-to-25 years, and the other from 50-to-70 years—the mechanisms causing PDO variability remain unclear. To date, there is little in the way of observational evidence to support a mid-latitude coupled air-sea interaction for PDO, though there are several well-understood mechanisms that promote multi-year persistence in North Pacific upper ocean temperature anomalies.     

High-resolution observations of aggregate flux during a sub-polar North Atlantic spring bloom

An aggregate flux event was observed by ship and by four underwater gliders during the 2008 sub-polar North Atlantic spring bloom experiment (NAB08). At the height of the diatom bloom, aggregates were observed as spikes in measurements of both particulate backscattering coefficient (b_bp) and chlorophyll a fluorescence. Optical sensors on the ship and gliders were cross-calibrated through a series of simultaneous profiles, and b_bp was converted to particulate organic carbon. The aggregates sank as a discrete pulse, with an average sinking rate of ∼75 m d⁻¹; 65% of aggregate backscattering and 90% of chlorophyll fluorescence content was lost between 100 m and 900 m. Mean aggregate organic carbon flux at 100 m in mid-May was estimated at 514 mg C m⁻² d⁻¹, consistent with independent flux estimates. The use of optical spikes observed from gliders provides unprecedented coupled vertical and temporal resolution measurements of an aggregate flux event.     

Improved moraine age interpretations through explicit matching of geomorphic process models to cosmogenic nuclide measurements from single landforms

The statistical distributions of cosmogenic nuclide measurements from moraine boulders contain previously unused information on moraine ages, and they help determine whether moraine degradation or inheritance is more important on individual moraines. Here, we present a method for extracting this information by fitting geomorphic process models to observed exposure ages from single moraines. We also apply this method to 94 ¹⁰Be apparent exposure ages from 11 moraines reported in four published studies. Our models represent ¹⁰Be accumulation in boulders that are exhumed over time by slope processes (moraine degradation), and the delivery of boulders with preexisting ¹⁰Be inventories to moraines (inheritance). For now, we neglect boulder erosion and snow cover, which are likely second-order processes. Given a highly scattered data set, we establish which model yields the better fit to the data, and estimate the age of the moraine from the better model fit. The process represented by the better-fitting model is probably responsible for most of the scatter among the apparent ages. Our methods should help resolve controversies in exposure dating; we reexamine the conclusions from two published studies based on our model fits.     

Towards understanding paleosols in Southern Levantine eolianites: Integration of micromorphology, environmental magnetism and mineralogy

The paper addresses the controversial question of the role of clay-sized dust in the formation of paleosols in coastal eolianites, Israel. At the Habonim type section, the pedocomplex dated by archaeology and luminescence to 45-135 ka ago shows at least three paleosols, not separated by non-soil sediments. The oldest reddish paleosol （apparently related to MIS 5） is magnetically enhanced, leached from carbonates, with signs of bioturbation and strongly aged clay coatings. The reddening is due to very fine, -20 nm, poorly crystallized, superparamagnetic （SP） hematite, as determined by Mossbauer studies. In subsoil, lithorelics of eolianite are found. Over time, the soil surface aggraded due to accelerated fine dust accumulation alongside local slope wash. On younger materials formed magnetically depleted vertisols, dominated by smectite-type expandable paramagnetic clays. In thin sections, vertisols exhibit strong stipple-speckled and striated b-fabric due to shrink-swell processes, impregnative calcite nodules and Fe-Mn redistribution. The uppermost hydric vertisol shows the strongest expression of juxtaposed features of recurrent calcite and Fe precipitation. This paleosol developed on colluvial soil materials, as evidenced by mixing of clay coated and uncoated grains of quartz and calcite allochems. M6ssbauer spectra show high amounts of Fe（III） incorporated in the clay structure, low amounts of SP goethite and absence of SP hematite. Whilst magnetic susceptibility drops in vertisols to minimal values, increase. The latter along ferrimagnetie grain sizes with differences in the hierarchy of microfabric features is taken as indication for lithologic discontinuities which may have resulted from continuous, albeit variable and low-intensity, input of eolian clay from both remote Saharan and local sources, roughly dated to the earlier to middle part of the Last Glacial.     

Heavy metal levels in New Zealand molluscs

Cadmium, lead, copper, mercury, zinc and iron were analysed by atomic absorption spectrophotometry in 13 species of edible molluscs from 199 sites around New Zealand; these included all molluscs commonly eaten in New Zealand. From each sampling site, a minimum of 14 specimens were combined and analysed together, so that the result would be representative of the population in that area. Wide variations are shown to occur in heavy metals from one location to another, and explanations for some of these variations are given.     

A mixed-layer paragonite/phengite of low-grade metamorphic origin

A mixed-layer paragonite/phengite from low-grade metamorphic slates is described, showing strong tendency to regular mixed-layering with a paragonite/phengite ratio of about 64. It is suggested that the mixed-layer paragonite/phengite is an intermediate phase in the formation of paragonite from Na-bearing illite or montmorillonite.