Mixing of magmas from enriched and depleted mantle sources in the northeast Pacific: West Valley segment,Juan de Fuca Ridge

The 50 km-long West Valley segment of the northern Juan de Fuca Ridge is a young, extension-dominated spreading centre, with volcanic activity concentrated in its southern half. A suite of basalts dredged from the West Valley floor, the adjacent Heck Seamount chain, and a small near-axis cone here named Southwest Seamount, includes a spectrum of geochemical compositions ranging from highly depleted normal (N-) MORB to enriched (E-) MORB. Heck Seamount lavas have chondrite-normalized La/Sm_cn0.3, ⁸⁷Sr/⁸⁶Sr=0.70235–0.70242, and ²⁰⁶Pb/²⁰⁴Pb=18.22–18.44, requiring a source which is highly depleted in trace elements both at the time of melt generation and over geologic time. The E-MORB from Southwest Seamount have La/Sm_cn1.8, ⁸⁷Sr/⁸⁶Sr=0.70245–0.70260, and ²⁰⁶Pb/²⁰⁴Pb=18.73–19.15, indicating a more enriched source. Basalts from the West Valley floor have chemical compositions intermediate between these two end-members. As a group, West Valley basalts from a two-component mixing array in element-element and element-isotope plots which is best explained by magma mixing. Evidence for crustal-level magma mixing in some basalts includes mineral-melt chemical and isotopic disequilibrium, but mixing of melts at depth (within the mantle) may also occur. The mantle beneath the northern Juan de Fuca Ridge is modelled as a plum-pudding, with plums of enriched, amphibole-bearing peridotite floating in a depleted matrix (DM). Low degrees of melting preferentially melt the plums, initially removing only the amphibole component and producing alkaline to transitional E-MORB. Higher degrees of melting tap both the plums and the depleted matrix to yield N-MORB. The subtly different isotopic compositions of the E-MORBs compared to the N-MORBs require that any enriched component in the upper mantle was derived from a depleted source. If the enriched component crystallized from fluids with a DM source, the plums could evolve to their more evolved isotopic composition after a period of 1.5–2.0 Ga. Alternatively, the enriched component could have formed recently from fluids with a less-depleted source than DM, such as subducted oceanic crust. A third possibility is that enriched material might be dispersed as plums throughout the upper mantle, transported from depth by mantle plumes.     

The relation between dilatancy,effective stress and dispersive pressure in granular avalanches

Here we investigate three long-standing principles of granular mechanics and avalanche science: dilatancy, effective stress and dispersive pressure. We first show how the three principles are mechanically interrelated: Shearing of a particle ensemble creates a mechanical energy flux associated with random particle movements (scattering). Because the particle scattering is inhibited at the basal boundary, there is a spontaneous rise in the center of mass of the particle ensemble (dilatancy). This rise is connected to a change in potential energy. When the center of mass rises, there is a corresponding reaction at the base of the flow that is coupled to the vertical acceleration of the ensemble. This inertial stress is the dispersive pressure. Dilatancy is therefore not well connected to effective-stress-type relations, rather the energy fluxes describing the configurational changes of the particle ensemble. The strict application of energy principles has far-reaching implications for the modeling of avalanches and debris flows and other dangerous geophysical hazards.     

Sub-regional snow cover distribution across the southern Appalachian Mountains

Abstract

Snowfall in the Southern Appalachian Mountain region of the eastern US is characterized by much spatiotemporal variability. Annual snowfall totals vary by up to 75 cm, and variations in snowfall intensity can lead to large differences in the local snowfall distribution. Research has shown that the synoptic pattern associated with the snowfall strongly influences the regional-scale distribution of snow cover. However, topographic variability results in locally complex snow cover patterns that are not well understood or documented. In this study, we characterize the snow covered area (SCA) and fractional snow cover associated with different synoptic patterns in 14 individual sub-regions. We analyze 63 snow events using Moderate-resolution Imaging Spectroradiometer standard snow cover products to ascertain both qualitative and quantitative differences in snow cover across sub-regions. Among sub-regions, there is significant variation in the snow cover pattern from individual synoptic classes. Furthermore, the percent SCA follows the regional snowfall climatology, and sub-regions with the highest elevations and northerly latitudes exhibit the greatest variability. Results of the sub-regional analysis provide valuable guidance to forecasters by contributing a deeper understanding of local snow cover patterns and their relationship to synoptic-scale circulation features.     

The effects of diagenesis on the redistribution of strontium isotopes in shales

The rubidium-strontium method has often been used in attempts to date shales, but has yielded mixed results. In order to explore the effects of diagenesis on this system, samples of a Miocene shale section collected from an oil well drilled in coastal Louisiana were separated into fractions and analyzed for Sr⁸⁷/Sr⁸⁶, Rb and Sr. The diagenetic changes involve the destruction of detrital mica and feldspar and the formation of an illite-rich clay from smectite. Strontium from interstitial waters, calcium carbonate and adsorbed on the clay minerals is released and then sequestered by the newly forming phases, together with the strontium mobilized from the silicate minerals. Attending these changes there is a trend towards the homogenization of the shale with respect to its strontium isotopes, but diagenesis and homogenization are not complete in the deepest part (5523 m) of the section studied. Therefore, the interpretation of rubidium-strontium shale dates remains uncertain, but the dates in many cases most probably represent the time equal to or younger than the time of the major construction of new phases and the attendant homogenization of the strontium isotopes.     

Semiperiodic variations in CO2 abundance on Venus

Photoelectric spectral scans of the P branch of the 8689 Å CO₂ band on Venus were made using the 107-inch coude scanner during seven observing periods in the past 2 years. The relative CO₂ line strength was determined for each scan, then normalized to remove the spatial variations leaving only temporal variations.The 4-day periodicity in the relative CO₂ line strength noted by Young et al. (1973) is not unique; we do confirm their 4-day periodicity in August 1973. Four other observing periods rule out a 4-day periodicity.A definite North-South asymmetry in the relative CO₂ line strength is noted during 1973, in most cases with the same periodicity present in both hemispheres. When the slit positions are referred to the equator of Venus, particularly near inferior conjunction, the large asymmetrics between the slit positions can be explained by a greater CO₂ line strength over the polar regions and weaker over the equatorial latitudes. The amplitude of variation of each position on the crescent is much greater near inferior conjunction either because we are sampling a smaller area on the planet or because the upper atmospheric abundance is more sensitive to the mechanism causing the variation in the smaller regions sampled at inferior conjunction.Simultaneous H₂O measurementsduring several of the observing runs indicate a lack of correlation in the relative CO₂ line strengths and the H₂O abundance.     

Induction of zona radiata and vitellogenin genes in estradiol and nonylphenol exposed male sheepshead minnows (Cyprinodon variegatus)

Several genes normally induced by estradiol (E(2)) in female fish, those for vitellogenins (VTGs) and zona radiata proteins (ZRPs), are also inducible in males exposed to estrogenic chemicals. Male sheepshead minnows (SHM) were exposed to both E(2) and para-nonylphenol (NP), at several doses and times to determine a dose-response. Quantitative real time PCR was used to measure mRNA for VTG1, VTG2, ZRP2 and ZRP3. Both E(2) and NP elicited a dose-response increase in all of the mRNAs tested. Exposure to both chemicals resulted in VTG2 expression at about a 10-fold lower level than VTG1, and ZRP2 expression at a lower level than ZRP3.     

Refining P nuclear magnetic resonance spectroscopy for marine particulate samples: Storage conditions and extraction recovery

Solution ³¹P nuclear magnetic resonance (NMR) spectroscopy has recently been used to characterize phosphorus species within marine particles. However, the effects of sample collection, storage and preparation have not been thoroughly examined. In this study, samples of settling particulates collected from a 1200-m sediment trap located in Monterey Bay, California, were subjected to various storage options (i.e., no storage, refrigeration, freezing, and oven-drying and grinding) prior to extraction for solution ³¹P-NMR spectroscopy. Freezing, refrigerating and drying samples for periods of up to 6 months prior to extraction with 0.25 M NaOH + 0.05 M Na₂EDTA increased the concentration of extracted P by an average of 16% relative to samples extracted without storage. Pre-extraction storage also introduced some minor changes in P speciation, by increasing the percentage of orthophosphate by up to 15% and decreasing the percentage of pyrophosphate by up to 5%, relative to the abundances of these P species in samples extracted without storage. Drying caused the biggest changes in speciation, specifically decreasing more extensively the relative percentage of pyrophosphate compared to other treatments. Nevertheless, observed changes in speciation due to sample storage within a specific sample were small relative to differences observed among samples collected sequentially in the same area, or reported differences among samples collected at different locations. Samples were also analyzed by solid-state ³¹P-NMR spectroscopy before and after extraction, to examine extraction-related changes in P speciation. Comparison of solution with solid-state ³¹P NMR indicates that extraction with NaOH–EDTA removes the majority of organic esters, but only a variable portion of phosphonates (39–67%). In addition, there was preferential extraction of Ca-associated phosphate over Mg-, Fe- and Al-associated phosphate. Solution ³¹P NMR enables much higher resolution of P species within samples, particularly when it is important to speciate orthophosphate monoesters and diesters, or if polyphosphates are present. However, combining solid-state ³¹P NMR with solution ³¹P NMR spectroscopy for marine particles should be conducted when examining inorganic P speciation and the abundance of phosphonates.     

Field tests of seasat bathymetric detections

Knowledge of the locations and sizes of seamounts is of great importance in applications such as inertial navigation and ocean mining. The quality and density of bathymetry data in the equatorial regions and the southern hemisphere are, unifortunately, highly variable. Our present knowledge of bathymetry, and in particular of seamount locations and characteristics, is based upon ship surveys, which are both time-consuming and expensive. It is likely that a significant number of uncharted seamounts exist throughout the oceans, and remote-sensing techniques may be the most effective means of locating them.