Mineralogy and environmental geochemistry of historical iron slag,Hopewell Furnace National Historic Site,Pennsylvania, USA

The Hopewell Furnace National Historic Site in southeastern Pennsylvania, which features an Fe smelter that was operational in the 18th and 19th centuries, is dominated by three slag piles. Pile 1 slag, from the Hopewell Furnace, and pile 2 slag, likely from the nearby Cornwall Furnace, were both produced in cold-blast charcoal-fired smelters. In contrast, pile 3 slag was produced in an anthracite furnace. Ore samples from the nearby Jones and Hopewell mines that fed the smelter are mainly magnetite-rich with some sulfides (pyrite, chalcopyrite, sphalerite) and accessory silicates (quartz, garnet, feldspar, and clay minerals). Slag piles 1 and 2 are similar mineralogically containing predominantly skeletal and dendritic aluminian diopside and augite, skeletal forsteritic olivine, glass, rounded blebs of metallic Fe, and exotic quartz. Olivine is a major phase in all samples from pile 2, whereas it occurs in only a few samples from pile 1. Samples of the <2 mm-size fraction of surface composite slag material or crushed slag from at depth in piles 1 and 2 are mineralogically similar to the large surface slag fragments from those piles with the addition of phases such as feldspars, Fe oxides, and clay minerals that are either secondary weathering products or entrained from the underlying bedrock. Pile 3 slag contains mostly skeletal forsteritic olivine and Ti-bearing aluminian diopside, dendritic or fine-grained subhedral melilite, glass, euhedral spinel, metallic Fe, alabandite–oldhamite solid solution, as well as a sparse Ti carbonitride phase. The bulk chemistry of the slag is dominated by Al₂O₃ (8.5–16.2 wt.%), CaO (8.2–26.2 wt.%), MgO (4.2–24.7 wt.%), and SiO₂ (36.4–59.8 wt.%), constituting between 81% and 97% of the mass of the samples. Piles 1 and 2 are chemically similar; pile 1 slag overall contains the highest Fe₂O₃, K₂O and MnO, and the lowest MgO concentrations. Pile 3 slag is high in Al₂O₃, CaO and S, and low in Fe₂O₃, K₂O and SiO₂ compared to the other piles. In general, piles 1 and 2 are chemically similar to each other, whereas pile 3 is distinct – a conclusion that reflects their mineralogy. The similarities and differences among piles in terms of mineralogy and major element chemistry result from the different smelting conditions under which the slag formed and include the fuel source, the composition of the ore and flux, the type of blast (cold versus hot), which affects the furnace temperature, and other beneficiation methods.     

Pedestal crater heights on Mars: A proxy for the thicknesses of past, ice-rich, Amazonian deposits

Mid-latitude pedestal craters on Mars offer crucial insights into the timing and extent of widespread ice-rich deposits during the Amazonian period. Our previous comprehensive analysis of pedestal craters strongly supports a climate-related formation mechanism, whereby pedestals result from impacts into ice-rich material at mid latitudes during periods of higher obliquity. The ice from this target deposit later sublimates due to obliquity changes, but is preserved beneath the protective cover of the armored pedestal. As such, the heights of pedestals act as a proxy for the thicknesses of the paleodeposits. In this analysis, our measurement of 2300 pedestal heights shows that although pedestals can reach up to ∼260 m in height, ∼82% are shorter than 60 m and only ∼2% are taller than 100 m. Mean pedestal heights are 48.0 m in the northern mid latitudes and 40.4 m in the southern mid latitudes, with the tallest pedestals located in Utopia Planitia, Acidalia Planitia and Malea Planum. We use these data in conjunction with prior climate model results to identify both regional and global trends regarding ice accumulation during obliquity excursions. Our data provide evidence for multiple episodes of emplacement and removal of the mid-latitude ice-rich deposit based on stratigraphic relationships between pedestal craters and the close proximity of pedestals with significantly different heights.     

Erupted upper teeth in a male sperm whale,Physeter macrocephalus

An adult male sperm whale (Physeter macrocephalus L.) which stranded in Hawke's Bay, New Zealand, was found to have seven erupted teeth in its upper jaw—six on the left side, and one on the right side. Each upper tooth lay in the side of the pit into which the corresponding lower tooth fitted, and two bore a groove consistent with contact with a lower tooth.     

Determining kinematic order and relative age of faulting via flexural‐kinematic restoration: A case study in far western Nepal

Forward modeled, balanced cross sections that account for the flexural response to thrust loading and erosional unloading can verify and refine the kinematic sequence of deformation in fold‐thrust belts as well as help assess the validity of a balanced cross section. Results from flexural‐kinematic reconstructions that indicate either the cross section, the kinematic order or both are invalid include: (a) a predicted final topography that is dramatically different from the actual topography; (b) large normal fault or thrust fault bounded synorogenic basins that are not present in the mapped geology; and/or (c) an exhumation history that is not consistent with provenance records in the basin or measured thermochronometers. Where detailed measured foreland basin sections exist, flexural‐kinematic modeling of fold‐thrust belt deformation, including out‐of‐sequence (OOS) faults can predict a foreland basin evolution that can be compared to measured data. The modeling process creates a “pseudostratigraphy” in the modeled foreland. The pseudostratigraphy and predicted provenance of each modeled stratigraphic increment can be directly compared to measured stratigraphic sections. We present a case study using two cross sections through the Himalaya of far western Nepal (Api and Simikot) to assess the validity of the section geometries and the resulting kinematic histories, displacement rates, flexural wave response and predicted provenance for both sections. Insights from combining the flexural‐kinematic models with existing stratigraphic data include: (a) Changing the order of proposed OOS and normal faults to earlier in the evolution of the fold‐thrust belt was necessary to reproduce the foreland provenance data. We argue that OOS thrust and normal faults in the Api section occurred between 11 and 4 Ma. (b) Published shortening estimates for the Simikot cross section are too high (>50 km), resulting in unrealistic shortening rates up to 80 mm/yr between 25 and 20 Ma. (c) Flexural forward models with and without an additional sediment loading modeling step indicate that while sediment loading does not have a measurable effect on the magnitude and location of erosion within the fold‐thrust belt, it does have a small effect on accumulation rates and thus the predicted age of stratigraphic boundaries when compared to measured stratigraphic thicknesses and age. Thickness difference range from 0.2 to 0.5 km and can result in predicted age differences of ca. 1 Ma. Accounting for both flexural isostacy and erosion can eliminate unviable kinematic sequences and when combined with provenance data from measured stratigraphic sections, can provide insight into the order, age and rate of deformation.     

Mothering urban space,governing migrant women: the construction of intersectional positions in area-based interventions in Berlin

In this paper, we investigate new ways of governing migrant populations in Germany brought forth by social policies on the local level of inner-city neighborhoods. In recent years, numerous initiatives on the local level have constituted the ‘migrant neighborhood’ as a site of governmental attention. One initiative that policymakers consider particularly innovative is the neighborhood mothers program in Berlin, a program that instructs migrant women as agents of neighborhood improvement and encourages them to establish peer-to-peer relations to other migrant women in order to pass on social norms. In the paper, we combine governmentality and intersectionality theory to critically examine the modes of behavior change promoted by the neighborhood mothers program and the political rationalities that are used to justify the governing of (and through) migrant women. We draw particular attention to the spatial dimensions of the neighborhood mothers program, to the ways in which it targets domestic and intimate spaces as sites of inspection and intervention and appoints migrant women as ‘door openers’ for entry of the state into the regulation of families and communities.     

Assessment of putative endocrine disrupters in an in vivo crustacean assay and an in vitro insect assay

Concern over endocrine disrupters in coastal ecosystems has stimulated global efforts to understand their potential impacts on fish and invertebrate communities. Given that marine crustaceans are sensitive to the effects of alkylphenols and other xenobiotics, we are currently investigating whether these responses may be caused via an endocrine mechanism. Tisbe battagliai (Copepoda: Harpacticoida) is representative of an ecologically important group of meiofauna, is sensitive to toxicants and is used as an international test species in marine ecotoxicology. A 21-day life-cycle test that incorporates assessment of survival, development, reproduction and sex ratios, has shown that populations of T. battagliai are not significantly affected by environmentally relevant levels of steroidal oestrogen agonists, or by related synthetic receptor agonists. The absence of in vivo effects due to these steroid agonists and antagonists prompted in vitro studies of ecdysteroid receptor activity of a range of reference compounds and environmental contaminants with an ecdysteroid receptor (EcR/USP)-based screening assay derived from the BII haemocyte line of Drosophila melanogaster. The implications for environmental monitoring of endocrine disrupters are discussed.     

Comparison of central pit craters on Mars,Mercury, Ganymede,and the Saturnian satellites

We report on the first results of a large‐scale comparison study of central pit craters throughout the solar system, focused on Mars, Mercury, Ganymede, Rhea, Dione, and Tethys. We have identified 10 more central pit craters on Rhea, Dione, and Tethys than have previously been reported. We see a general trend that the median ratio of the pit to crater diameter (D_p/D_c) decreases with increasing gravity and decreasing volatile content of the crust. Floor pits are more common on volatile‐rich bodies while summit pits become more common as crustal volatile content decreases. Uplifted bedrock from below the crater floor occurs in the central peak upon which summit pits are found and in rims around floor pits, which may or may not break the surface. Peaks on which summit pits are found on Mars and Mercury share similar characteristics to those of nonpitted central peaks, indicating that some normal central peaks undergo an additional process to create summit pits. Martian floor pits do not appear to be the result of a central peak collapse as the median ratio of the peak to crater diameter (D_pk/D_c) is about twice as high for central peaks/summit pits than D_p/D_c values for floor pits. Median D_pk/D_c is twice as high for Mars as for Mercury, reflecting differing crustal strength between the two bodies. Results indicate that a complicated interplay of crustal volatiles, target strength, surface gravity, and impactor energy along with both uplift and collapse are involved in central pit formation. Multiple formation models may be required to explain the range of central pits seen throughout the solar system.     

Swimming abilities of wild-caught,late-stage larvae of Diplodus capensis and Sarpa salpa (Pisces: Sparidae) from temperate South Africa

Understanding the movement of marine fish larvae in coastal habitats requires an assessment of active swimming abilities. The critical speed (U-crit) and endurance swimming of late-stage larvae of Diplodus capensis and Sarpa salpa (Family Sparidae), common inshore recreational linefish species, were measured in a laboratory swimming chamber. Postflexion and settlement-stage larvae were collected from the wild in a small bay on the warm temperate coast of South Africa. Larvae were allowed to acclimate in captivity and were tested soon after capture. For the endurance tests a speed of 18 cm s⁻¹ was selected, as this approximated the mean current speed observed in the coastal environment of the area. The mean U-crit value (maximum swimming speed) for D. capensis (19 cm s⁻¹) was similar to that of S. salpa (18 cm s⁻¹), and similarly mean endurance (km swum) for S. salpa (8 km) was similar to that of D. capensis (6 km). The increase in critical speed and endurance swimming abilities with standard length was best described by a linear relationship. At lengths between 12 and 15 mm BL, D. capensis was the better swimmer, whereas S. salpa was the better swimmer between 15 and 16 mm BL. Of all the larvae that swam at critical speed, 90% were in an inertial environment. These swimming speeds exceed the modal current velocities observed in the shallow nearshore of the study region where these larvae occur abundantly. These swimming abilities provide larvae with the potential to influence their dispersal trajectories and ultimately influence their distribution in their nearshore nursery areas.