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431.
This study explores garnet coronas around hedenbergite, which were formed by the reaction plagioclase + hedenbergite→garnet + quartz, to derive information about diffusion paths that allowed for material redistribution during reaction progress. Whereas quartz forms disconnected single grains along the garnet/hedenbergite boundaries, garnet forms ~20‐μm‐wide continuous polycrystalline rims along former plagioclase/hedenbergite phase boundaries. Individual garnet crystals are separated by low‐angle grain boundaries, which commonly form a direct link between the reaction interfaces of the plagioclase|garnet|hedenbergite succession. Compositional variations in garnet involve: (i) an overall asymmetric compositional zoning in Ca, Fe2+, Fe3+ and Al across the garnet layer; and (ii) micron‐scale compositional variations in the near‐grain boundary regions and along plagioclase/garnet phase boundaries. These compositional variations formed during garnet rim growth. Thereby, transfer of the chemical components occurred by a combination of fast‐path diffusion along grain boundaries within the garnet rim, slow diffusion through the interior of the garnet grains, and by fast diffusion along the garnet/plagioclase and the garnet/hedenbergite phase boundaries. Numerical simulation indicates that diffusion of Ca, Al and Fe2+ occurred about three to four, four and six to seven orders of magnitude faster along the grain boundaries than through the interior of the garnet grains. Fast‐path diffusion along grain boundaries contributed substantially to the bulk material transfer across the growing garnet rim. Despite the contribution of fast‐path diffusion, bulk diffusion through the garnet rim was too slow to allow for chemical equilibration of the phases involved in garnet rim formation even on a micrometre scale. Based on published garnet volume diffusion data the growth interval of a 20‐μm‐wide garnet rim is estimated at ~103–104 years at the inferred reaction conditions of 760 ± 50 °C at 7.6 kbar. Using the same parameterization of the growth law, 100‐μm‐ and 1‐mm‐thick garnet rims would grow within 105–106 and 106–107 years respectively. 相似文献
432.
S.J. Malone J.G. Meert D.M. Banerjee M.K. Pandit E. Tamrat G.D. Kamenov V.R. Pradhan L.E. Sohl 《Precambrian Research》2008,164(3-4):137-159
The utility of paleomagnetic data gleaned from the Bhander and Rewa Groups of the “Purana-aged” Vindhyanchal Basin has been hampered by the poor age control associated with these units. Ages assigned to the Upper Vindhyan sequence range from Cambrian to the Mesoproterozoic and are derived from a variety of sources, including 87Sr/86Sr and δ 13C correlations with the global curves and Ediacara-like fossil finds in the Lakheri–Bhander limestone. New analyses of the available paleomagnetic data collected from this study and previous work on the 1073 Ma Majhgawan kimberlite, as well as detrital zircon geochronology of the Upper Bhander sandstone and sandstones from the Marwar SuperGroup suggest that the Upper Vindhyan sequence may be up to 500 Ma older than is commonly thought. Paleomagnetic analysis generated from the Bhander and Rewa Groups yields a paleomagnetic pole at 44°N, 214.0°E (A95 = 4.3°). This paleomagnetic pole closely resembles the VGP from the well-dated Majhgawan intrusion (36.8°N, 212.5°E, α95 = 15.3°).Detrital zircon analysis of the Upper Bhander sandstone identifies a youngest age population at 1020 Ma. A comparison between the previously correlated Upper Bhander sandstone and the Marwar sandstone detrital suites shows virtually no similarities in the youngest detrital suite sampled. The main 840–920 Ma peak is absent in the Upper Bhander. This supports our assertion that the Upper Bhander is older than the 750–771 Ma Malani sequence, and is likely close to the age of the 1073 Ma Majhgawan kimberlite on the basis of the paleomagnetic similarities. By setting the age of the Upper Vindhyan at 1000–1070 Ma, several intriguing possibilities arise. The Bhander–Rewa paleomagnetic pole allows for a reconstruction of India at 1000–1070 Ma that overlaps with the 1073 ± 13.7 Majhgawan kimberlite VGP. Comparisons between the composite Upper Vindhyan pole (43.9°N, 210.2°E, α95 = 12.2°) and the Australian 1071 ± 8 Ma Bangamall Basin sills and the 1070 Ma Alcurra dykes suggest that Australia and India were not adjacent at this time period. 相似文献
433.
The role of heterogeneous strain in the development and preservation of a polymetamorphic record in high-P granulites, western Canadian Shield 总被引:1,自引:0,他引:1
K. H. MAHAN P. GONCALVES R. FLOWERS M. L. WILLIAMS D. HOFFMAN-SETKA 《Journal of Metamorphic Geology》2008,26(6):669-694
Mafic rocks in the Chipman domain of the Athabasca granulite terrane, western Canadian Shield, provide the first well‐documented record of two distinct high‐P granulite facies events in the same domain in this region. Textural relations and the results of petrological modelling (NCFMASHT system) of mafic granulites are interpreted in terms of a three‐stage tectonometamorphic history. Stage 1 involved development of the assemblage Grt + Cpx + Qtz ± Pl (M1) from a primary Opx‐bearing igneous precursor at conditions of 1.3 GPa, 850–900 °C. Field and microstructural observations suggest that M1 developed synchronously with an early S1 gneissic fabric. Stage 2 is characterized by heterogeneous deformation (D2) and synkinematic partial retrogression of the peak assemblage to an amphibole‐bearing assemblage (M2). Stage 3 involved a third phase of deformation and a return to granulite facies conditions marked by the prograde breakdown of amphibole (Amph2) to produce matrix garnet (Grt3a) and the coronitic assemblage Cpx3b + Opx3b + Ilm3b + Pl3b (M3b) at 1.0 GPa, 800–900 °C. M1 and M3b are correlated with 2.55 and 1.9 Ga metamorphic generations of zircon, respectively, which were dated in a separate study. Heterogeneous strain played a crucial role in both the development and preservation of these rare examples of multiple granulite facies events within single samples. Without this fortuitous set of circumstances, the apparent reaction history could have incorrectly led to an interpretation involving a single‐cycle high‐grade event. The detailed P–T–t–D history constructed for these rocks provides the best evidence to date that much of the east Lake Athabasca region experienced long‐term lower crustal residence from 2.55 to 1.9 Ga, and thus the region represents a rare window into the reactivation and ultimate stabilization processes of cratonic lithosphere. 相似文献
434.
Delineation of groundwater protection zones by the backward particle tracking method: theoretical background and GIS-based stochastic analysis 总被引:1,自引:0,他引:1
Konstadinos N. Moutsopoulos Alexandra Gemitzi Vassilios A. Tsihrintzis 《Environmental Geology》2008,54(5):1081-1090
The backward particle tracking method, an effective and powerful tool that can be used to delineate groundwater protection
zones, is presented. The theoretical background and insights on the applicability of this method are provided. Moreover, the
present work enriches the backward particle tracking method with an uncertainty analysis concerning the porosity values, applying
a Monte Carlo (MC) approach, coupled with the use of geographical information systems (GIS). As an application example, a
wellfield in the Komotini area, Greece, is investigated. The present study may serve as a potential guideline for wellfield
delineation, particularly in areas like Greece where lack of data related to the hydrogeological system is often a problem. 相似文献
435.
In an attempt to delineate heavy metal contamination precincts and to evaluate the extent and degree of toxic levels, besides
their possible sources, 38 water samples from Ankaleshwar Industrial Estate, south Gujarat, India were analyzed. By clutching
geochemical analyses and GIS-based colour composites areas depicting anomalously high concentration of heavy metals (Mo, Zn,
Pb, Ni, Co, Cd, etc.) in the groundwater were revealed. The multicomponent overlays in grey-scale facilitated in identifying
situates of heavy metal ‘hot spots’, and lateral protuberances of the contamination plume around defile stretch of the main
stream Amla Khadi flowing through the area. The multiple pollution plumes emerging from other parts of the area further coincide
with effluent laden streams and small channels indicating industrial establishments as major sources of groundwater contamination.
Influent nature of the streams, accelerated infiltration process, high mass influx and shallow groundwater table are the factors
conducive for easy access of heavy metals to the phreatic aquifers affecting over 20 km2 area. On the basis of P/U ratios (concentration of metals in polluted water to unpolluted water), geogenic and anthropogenic sources have been identified.
Very high levels of technogenic elements present in the ground water raise concerns about possible migration into food crops,
as the area is an important horticultural locale and is highly cultivated. 相似文献
436.
N. Nur Ozyurt 《Environmental Geology》2008,54(4):731-736
Salinity and temperature variations in groundwater discharge from the Altug submarine karst cave have been observed at 28 m
below sea level for every 10 min between November 2004 and August 2005 to determine the drivers that govern the salinization.
Comparisons between temporal trends of salinity and temperature with those of precipitation, air pressure, sea level and wind
velocity revealed an apparent dominance of precipitation regime on the salinity and temperature variations. Spectral analyses
applied to observations showed that the air pressure and sea level oscillations are affected by sun and moon tides which do
not have an appreciable impact on the salinity and temperature variations. Annual rate of salinization in Altug cave seems
inversely related to the inland groundwater head so that the maximum and minimum fresh water contributions occur at mid-spring
and late-summer, respectively. 相似文献
437.
M. Draoui J. Vias B. Andreo K. Targuisti J. Stitou El Messari 《Environmental Geology》2008,54(3):455-463
This paper presents the results of a comparative study relating to the application of four vulnerability mapping methods,
GOD, AVI, DRASTIC and SINTACS, in a pilot detritic aquifer situated in NW Morocco, known as the Martil–Alila aquifer. The
principal objective of this work is to determine the most suitable such methods for this aquifer type within a Mediterranean
context, and to show the effect of the rainfall variations that are characteristic of the Mediterranean climate on the degree
of vulnerability. The methods applied distinguish five classes of vulnerability, these being irregularly divided up in space,
with the division varying according to the method in question. The vulnerability maps obtained by the different methods strongly
suggest that the eastern half of the aquifer is more vulnerable to contamination than the western half, for all hydrological
situations. The effect of climatic conditions on the degree of vulnerability is well represented by the DRASTIC, according
to which the aquifer is moderately to strongly vulnerable during humid hydrological years and weakly to moderately vulnerable
during dry ones. For the other methods, this climatic effect is limited to the area occupied by the two predominant classes
(“High” and “Low” for GOD and “High” and “Moderate” for SINTACS) while it is null for AVI. In conclusion, DRASTIC appears
the most suitable for mapping the vulnerability to contamination of Mediterranean coastal detritic aquifers such as the Martil–Alila
aquifer. 相似文献
438.
Georadiochemical evidence to weathering of mining residues of the Mansfeld mining district,Germany 总被引:1,自引:0,他引:1
Mining heaps are used as archives for the investigation of weathering processes. Aim of this work was to investigate the different
weathering behavior of heap materials derived from Kupferschiefer mining with respect to environmental hazard. For this purpose,
Kupferschiefer and slag material of two heaps of different age were examined regarding to the radionuclide distribution and
geochemical composition. By measuring of the local dose rate, performing digital autoradiography and gamma spectrometry the
radiological load of the heaps and the heap materials was determined. The geochemical characterization of the samples was
performed by XRF, ICP–OES and ICP–MS. The results show a clear higher radionuclide load of the younger slag heap. A depletion
of chalcophile and lithophile elements in the older slag was determined. Apart from a homogeneous radionuclide distribution,
considerable radionuclide enrichments in fossil fragments could be proven. The results reveal a different weathering behavior
of slag material in comparison to the Kupferschiefer depending on the chemical binding of the elements on organic and inorganic
species. Natural organic matter as well as apatite in Kupferschiefer act as retention barrier for some metals. 相似文献
439.
Phosphorus transport in shallow groundwater in peri-urban Kampala, Uganda: results from field and laboratory measurements 总被引:1,自引:0,他引:1
To understand Phosphorus (P) sources and transport processes in the subsurface in Bwaise III Parish, Kampala, P attenuation
and adsorption capacities of soils were studied in situ and from laboratory measurements. Relationships between sorption parameters
and soil matrix properties, rates and mechanism of the adsorption process and soil P fractions were also investigated. P was
generally higher in the wet than the dry season, but for both seasons, the maximum was 5 mgP/l. P transport mechanisms appeared
to be a combination of adsorption, precipitation, leaching from the soil media and by colloids with the latter two playing
an important role in the wet season. The sorption process comprised two phases with the first stage rate constants being about
fourfold those of the second stage. The Langmuir isotherm described the sorption data well (R
2 ≥ 0.95) with the second soil layer exhibiting the highest sorption maximum (C
max) (average value 0.6 ± 0.17 mgP/gDW). The best prediction of C
max had organic carbon, Ca, available P and soil pH. Residual P consisting mostly of organics was the main fraction in all the
layers followed by inorganic HCl-P and NaOH-P in the top and middle layers, respectively. Loosely bound P (NH4Cl-P) was the least fraction (<0.4% of total P) in all layers indicating the high binding capacity of P by the soils. The
study results suggest that P dynamics is related to Ca, Fe and organic carbon content of the soils. 相似文献
440.
Investigations were carried out at three underground coal mines in India to study the response of surface structures to underground
blasting and the likelihood of damage to the structures. The structures in the vicinity of the underground blasting area were
single and multistoried residential houses. The amplitudes of vibration due to underground blasting were monitored simultaneously
on the ground surface near the foundation of the structures and on various floors of the structures. The vibrations were also
monitored near the important surface installations. It was observed that the magnitude of vibration in structures decreased
with the increase in the height of the structures. The frequency of blast vibration from underground blasting was higher than
the natural frequency of the structures. Little energy was transmitted into the structures, which caused reduction in the
vibration level in the structures. The reduction in the vibration levels was up to 45% in the houses. It indicates that the
dominant frequency of blast vibration plays an important role in persistence of vibration and its amplification or reduction
characteristics in the structures. This paper deals with the effect of the vibrations on structures/houses standing above
the blasting faces in underground workings and their potential to likely damage to the structures at different Indian geo-mining
conditions. 相似文献