Shock temperatures in anorthite glass

Summary. Temperatures of CaAl₂Si₂O₈ (anorthite glass) shocked to pressures between 48 and 117 GPa have been measured in the range from 2500 to 5600 K, using optical pyrometry techniques. The pressure dependence of the shock temperatures deviates significantly from predictions based on a single high-pressure phase. Either a variable specific heat, or the existence of three phase transitions, at pressures of about 55, 85 and 100 GPa and with transition energies of about 0.5 MJ kg⁻¹ each (∼ 1.5 MJ kg⁻¹ total) can explain the shock-temperature data. The proposed phase transition at 100 GPa can possibly be identified with the stishovite melting transition. Theoretical models of the time dependence of the thermal radiation from the shocked anorthite based on the geometry of the experiment and the absorptive properties of the shocked material yield good agreement with observations, indicating that it is not necessary to invoke intrinsic time dependences to explain the data in many cases. Observed time dependences were used to calculate absorption coefficients of the shocked material of from about 2 mm⁻¹ to greater than 24 mm⁻¹– an increasing function of shock pressure. The assumption that the shocked material radiates as a black body is supported by the theoretical model, and by the close agreement between measured and calculated black body spectral radiance as a function of wavelength.     

A Teleseismic Delay Time Study Across the Central African Shear Zone In the Adamawa Region of Cameroon, West Africa

Summary. P -wave relative teleseismic residuals were measured for a network of seismological stations along a 300 km profile across the Adamawa Plateau and the Central African Shear Zone of central Cameroon, to determine the variation in crust and upper mantle velocity associated with these structures. A plot of the mean relative residuals for the stations shows a long wavelength (> 300 km) variation of amplitude 0.45 s. the slowest arrivals are located over and just to the north, of the faulted northern margin of the Adamawa Plateau. the residuals do not correlate with topography, surface geology or the previously determined crustal structure, in any simple way.
The Aki inversion technique has been used to invert the relative residuals into a 3-D model of velocity perturbations from a mean earth model. the results show the region is divided roughly into three blocks by two subvertical boundaries, striking ENE and traversing both the crust and upper mantle down to depths greater than 190km. the central block, which is 2 per cent slower than the adjacent blocks, roughly corresponds to the Central African Shear Zone. the Adamawa Plateau, as an individual uplifted area, is explained by the interaction of a regional anomalous upper mantle associated with the West African Rift System, and the Central African Shear Zone, which provided a conduit for heat flow to the surface.     

Distribution coefficients of210Pb and210Po in laboratory and natural aquatic systems

We have measured the distribution coefficient (Kd) of²¹⁰Po and²¹⁰Pb in laboratory systems and in natural freshwater systems. In the laboratory systems, an inverse relationship was observed between the particle concentration of sand or lake sediment, and the distribution coefficients of²¹⁰Po and²¹⁰Pb. The slope of the log-linearK _d vs particle concentration relation is consistent with existingK _d-particle concentration theories. These laboratory observations are consistent with similar measurements in two lakes. TheK _d values of Po and Pb for the bottom sediment-pore water system with a high particle concentration were 10 to 100 times lower than those for dilute concentrations of particles suspended in the lake water. TheK _d of²¹⁰Pb in the sediments was >10⁴ so that the diffusive transport of²¹⁰Pb has only a small influence on the interpretation of²¹⁰Pb concentration-depth profiles and the²¹⁰Pb dating of these sediments.This is the second of a series of papers to be published by this journal following the 20^th anniversary of the first application of²¹⁰Pb dating of lake sediments. Dr P. G. Appleby is guest editing.     

Late Quaternary palaeolimnology of a tropical marl lake: Wallywash Great Pond,Jamaica

Wallywash Great Pond (17° 57 N, 77° 48 W, 7 m a.s.l.) is the largest perennial lake in Jamaica. It occupies a fault trough within the karstic White Limestone. The Great Pond is a hardwater lake with a pH of 8.2–8.6 and an alkalinity of 3.6–3.9 meq 1^–1. Its chemistry is strongly influenced by the spring discharge from the limestone. The lake water is subject to degassing, evaporation and bicarbonate assimilation by submerged plants and algae, resulting in marl precipitation. A 9.23 m core (WGP2), taken from a water depth of 2.8 m, was analysed for magnetic susceptibility, loss-on-ignition, carbonate content, mole % MgCO₃ in calcite, and stable isotopes in the fine carbonate fraction. The chronology is based on ten¹⁴C and four U/Th dates. Four main sediment types alternate in the core: marl; organic, calcareous mud; organic mud or peat; and earthy, brown, calcareous mud. The marls represent periods of wet/warm climate during sea-level highstands and the organic deposits, shallower, swampy conditions. In contrast, the brown, calcareous muds were laid down when the lake was dry or ephemeral. The last interglacial (120 000- 106 000 yr BP) is represented by three distinct marl units. After a dry interval, stable, wet/warm conditions set in from 106 000 to 93 000 yr BP. A dry/cool climate prevailed between 93 000 and at least 9500 yr BP. Three subsequent cycles of alternating wet and dry conditions culminated in flooding of the basin by the Black River during the late Holocene. These recent events cannot be accurately dated by¹⁴C due to significant and temporally-variable inputs of dead carbon from the springs.     

Simple analytical Green's functions for ray perturbations in layered media

The total Green's function for two-point boundary-value problems can be related to the propagator for initial-value problems. A very simple expression for the Green's function is obtained when the unperturbed medium may be described by material with a constant gradient in quadratic slowness. The derivation requires a correct understanding of assumptions made in the propagator solution. Expressions are also obtained for Green's function in multilayered media.