Metabolic and physiological regulation of Chlorella sp. (Trebouxiophyceae,Chlorophyta) under nitrogen deprivation

Journal of Oceanology and Limnology - A freshwater green microalgae Chlorella sp., UMACC344 was shown to produce high lipid content and has the potential to be used as feedstock for biofuel...     

Synthesis of Calix(aza)crown and its Oligomeric Analogue for the Extraction of Selected Metal Cations and Dichromate Anions

The present study reports the synthesis of a novel ionophore, calix[4]azacrown ( 5 ) bearing two amino groups at the lower rim along with its oligomeric analogue ( 6 ). The liquid‐liquid extraction properties of these compounds towards selected metal cations and dichromate anions have been evaluated. It is observed that ( 5 ) and ( 6 ) are good extractants for the selected metal cations. However, in the case of dichromate anion, only species ( 5 ) shows remarkable extraction properties at low pH, whereas species ( 6 ) shows poor extraction behavior. The results have importance especially in wastewater treatment to obtain environmentally safe industrial effluent and they should also assist supramolecular chemists in designing and synthesizing more sophisticated host molecules for the removal of toxic pollutants.     

Equilibrium,Thermodynamic, and Kinetic Studies on Lead (II) Biosorption from Aqueous Solution by Saccharomyces cerevisiae Biomass

This paper presents a biosorption procedure for the preconcentration of Pb²⁺ ions using Saccharomyces cerevisiae biomass. The influence of several factors including pH, biomass dosage, contact time, and temperature on biosorption efficiency were optimized. At optimum value of all the equilibrium, thermodynamic, and kinetic parameters of Pb²⁺ ion biosorption was investigated by testing the Langmuir and Freundlich models and first and second order kinetic models were applied. The biosorption capacity of S. cerevisiae biomass was determined 89.6 mg/g, while the retained Pb²⁺ ions by S. cerevisiae were reversibly eluted using 5 mol/L HNO₃. Due to the high stability of S. cerevisiae the applied biomass can be used successively ten times with a slightly decrease (about 20%) in the recovery of Pb²⁺ ions. The calculated thermodynamic parameters, ΔG°, ΔH°, and ΔS° showed that the biosorption of Pb²⁺ ion onto S. cerevisiae biomass was feasible, spontaneous, and endothermic under examined conditions. The results of kinetic analysis showed that the biosorption processes of Pb²⁺ ions onto S. cerevisiae biomass followed pseudo second order kinetics.     

Implications of 2007’s Earthquake Activity in Eğirdir Lake (SW Anatolia) Based on Moment Tensor Solutions and Inversion of Stress State

We analyzed the waveforms of the small- to moderate-sized earthquakes that took place in the northern part of the inner Isparta Angle (IA) to retrieve their source parameters and combine these results with the focal mechanism solutions of the larger events that occurred in 2007 in E?irdir Lake at the apex of IA. In total, source mechanisms of 20 earthquakes within the magnitude range 3.5 < M < 5.0 were calculated using a regional moment tensor inversion technique. The inversion of the focal mechanisms yields an extensional regime with a NNE–SSW (N38°E) trending σ ₃ axis. Inversion results are related to a mainly WNW–ESE oriented normal fault beneath E?irdir Lake. The R value of a NNE–SSW extensional regime is 0.562 showing a triaxial stress state in the region. The current stress regime results from complex subduction processes such as slab pull, slab break-off, roll-back and/or retreating mechanism along the Hellenic and Cyprus arcs and the southwestward extrusion of the Anatolian block since the early Pliocene.     

Earthquake performance assessment and rehabilitation of two historical unreinforced masonry buildings

The paper describes the earthquake performance assessment of two historical buildings located in Istanbul exposed to a M_w = 7+ earthquake expected to hit the city and proposes solutions for their structural rehabilitation and/or strengthening. Both buildings are unreinforced clay brick masonry (URM) structures built in 1869 and 1885, respectively. The first building is a rectangular-shaped structure rising on four floors. The second one is L-shaped with one basement and three normal floors above ground. They survived the 1894, M_s = 7.0 Istanbul Earthquake, during which widespread damage to URM buildings took place in the city. Earthquake ground motion to be used in performance assessment and retrofit design is determined through probabilistic and deterministic seismic hazard assessment. Strength characteristics of the brick walls are assessed on the basis of Schmidt hammer test results and information reported in the literature. Dynamic properties of the buildings (fundamental vibration periods) are measured via ambient vibration tests. The buildings are modelled and analyzed as three-dimensional assembly of finite elements. Following the preliminary assessment based on the equivalent earthquake loads method, the dynamic analysis procedure of FEMA 356 (Pre-standard and commentary for the seismic rehabilitation of buildings, American Society of Civil Engineers, Reston, 2000) and ASCE/SEI 41-06 (Seismic rehabilitation of existing buildings, American Society of Civil Engineers, Reston, 2007) is followed to obtain dynamic structural response of the buildings and to evaluate their earthquake performance. In order to improve earthquake resistance of the buildings, reinforced cement jacketing of the main load carrying walls and application of fiber reinforced polymer bands to the secondary walls are proposed.     

Potential Occurrence of MTBE and BTEX in Groundwater Resources of Amman–Zarqa Basin,Jordan

This study investigates potential occurrence, distribution, and sources of the newly added gasoline oxygenate, methyl‐tert‐butyl ether (MTBE) and the petroleum derivatives benzene, toluene, ethylbenzene, and xylenes called collectively, BTEX, in Jordan's heavily populated Amman–Zarqa Basin (AZB). It presents the first data on the levels of MTBE and BTEX in the aquifers of this basin. One hundred and seventy‐nine (179) groundwater wells were sampled near petrol service stations, oil refinery storage tanks, car wrecks, bus stations, and chemical industries at different locations in the basin. Headspace GC and purge and trap GC–MS were utilized to determine the target substances in the samples. Concentrations of BTEX varied between no‐detection (minimum) for all of them to 6.6 µg/L (maximum) for ethylbenzene. MTBE was found in few samples but none has exceeded the regulated levels; its concentrations ranged between no‐detection to 4.1 µg/L. However, though the contamination levels are very low they should be considered alarming.     

An investigation on the formation of submerged bar under surges in sandy coastal region

Cross-shore sediment transport rate exposed to waves is very important for coastal morphology,the design of marine structures such as seawalls,jetties,breakwaters etc,and the prevention of coastal erosion and accretion due to on-off shore sediment transportation.In the present study,the experiments on cross-shore sediment transport are carried out in a laboratory wave channel with initial beach slopes of 1/8,1/10 and 1/15.By using the regular waves with different deep-water wave steepnesses generated by a pedal-type wave generator,the geometrical characteristics of beach profiles under storm conditions and the parameters affecting on-off shore sediment transport are investigated for the beach materials with medium diameters of d50=0.25,0.32,0.45,0.62 and 0.80 mm.The offshore bar geometric characteristics are the horizontal distances from the shoreline to the bar beginning(Xb),crest(Xt),and ending(Xs) points,the depth from the bar crest to the still water level(ht),and the bar volume(Vbar).The experimental results have indicated that when the deep-water steepness(H0/L0) increased,the net movement to seaside increased.With the increasing wave steepness,the bars moved to widen herewith the vertical distances from still water level to the bar beginning(Xb),crest(Xt) and ending(Xs) points and the horizontal distances from the coast line to the bar beginning,crest and ending points increased.It was also shown from experimental results that the horizontal distances from the bar beginning and ending points to the coast line increased with the decrease of the beach slope.The experimental results obtained from this study are compared with previous experimental work and found to be of the same magnitude as the experimental measurements and followed the expected basic trend.     

Spectrophotometric Determination of Gold (III) after Liquid–Liquid Extraction and Selective Pre‐concentration with a Novel Dibenzo‐18‐Crown‐6 Derivative

A selective and sensitive method for the extraction and spectrophotometric determination of gold with N,N′‐6,7,9,10,17,18,20,21‐octahydrodibenzo[b,k][1,4,7,10,13,16] hexaoxacyclo‐octadecine‐2,13–diylbis(2‐chloroacetamide) (ODBOCA) is described. The ODBOCA–Au(III) complex was extracted from a slightly acidic aqueous solution (pH 5) into a chloroform layer and then the absorbance of the extract was measured using a UV–Vis spectrophotometer with 1.0 cm quartz cells at 540 nm. An enrichment factor of 200 was achieved. In the chloroform medium at 540 nm, the molar absorptivity and Sandell’s sensitivity were 4.12 × 10³ l mol^?1 cm^?1 and 0.048 μg cm^?2, respectively. Beer’s law was obeyed in the range of 0.5–15 μg ml^?1 in the measured solution. The relative standard deviation for ten replicate samples at the 1.0 μg ml^?1 level was 3.0%. The limit of detection, based on 3s, was 0.5 μg l^?1 in the original sample. The effects of pH, ligand concentration and shaking time were studied. The ratio of the metal ion to ligand molecules in the complex was found to be 1:2 according to the Job Method. The effects of interference by a number of metal ions were investigated. The method was verified with certified reference materials and spiked tests, and quantitative recovery values were obtained. The method was fast, accurate, selective and precise, and was applied to the determination of gold in water and ore with good results.     

Runoff and sediment yield modeling by means of WEPP in the Bautzen dam catchment,Germany

Soil erosion by water is one of the most widespread forms of soil degradation in Europe. There are many undesirable consequences of soil erosion due to water such as loss of water storage capacity in reservoirs and transfer of pollutants from farmland to water bodies. The objectives of this study were to calibrate and validate the Water Erosion Prediction Project watershed model (WEPP 2012.8) in the Bautzen dam catchment area with monthly and daily single events for runoff and sediment yield. This is to our knowledge the first study using WEPP in Germany. The catchment (310 km²) was subdivided into small sub-catchments with an area of <260 ha as recommended in WEPP. A sensitivity analysis revealed that the runoff is highly sensitive to the effective hydraulic conductivity in Bautzen, whereas the sediment yield is highly sensitive to rill erodibility, critical shear stress, and to the effective hydraulic conductivity as well. All these parameters were initially calculated using WEPP’s built-in equations and parameters, which, however, produced very poor results for both runoff and sediment yield. Therefore, the model was calibrated for 2 years (2005–2007) and validated for another 2 years (2008–2009) against monthly measurements, in addition to 14 daily single events from the calibration period and 2010. The monthly results were compared with the monthly measurements on the basis of a continuous simulation. Results of calibration and validation periods show a satisfactory performance of WEPP with a determination coefficient R ² above 0.6 and Nash–Sutcliffe efficiency coefficients above 0.50 for runoff and sediment yield. Thus, the model could be used to simulate runoff and sediment yield, and used in scenario studies in the Bautzen dam catchment area.