Relating spatial and temporal variability in sediment chlorophylla and carbohydrate distribution with erodibility of a tidal flat

Trends in the spatial distribution of chlorophylla (chla) and colloidal and total carbohydrates on the Molenplaat tidal flat in the Westerschelde estuary, Netherlands, reflected spatial differences in physical properties of the sediment. Results from a Spearman Rank Order Correlation indicated that many of the physical and biological measures covaried. Multiple regression analyses describing the relationship between colloidal carbohydrates and sediment properties resulted in several highly significant equations, although in all cases chla was able to predict colloidal carbohydrate content. Relationships between sediment surface chla and colloidal carbohydrate, and sediment erodibility (i.e., critical erosion threshold, U_crit, and mass of sediment eroded at a velocity of 30 cm s^?1) determined in annular flume experiments were examined. Overall sediment erodibility was lowest (i.e., high thresholds, low mass eroded) for the siltiest sediments in June 1996 when chla and colloidal carbohydrates were high (56.9 μg gDW^?1 and 320.6 μg gluc.equ. gDW^?1, respectively), and greatest (i.e., low thresholds, high mass eroded) at the sandier sediments in September 1996, when chla and colloidal carbohydrates were low (1.0 μg gDW^?1 and 5.7 μg gluc.equ. gDW^?1, respectively). When sediments were grouped according to relative silt content, the most significant relationships were found in muddy sand with a finegrained fraction (<63 μm) of 25–50%. Thresholds of erosion increased, while mass of sediment eroded decreased, with increasing chla and colloidal carbohydrate. A similar trend was observed for the sand-muddy sand (63 μm 10–25%). In the sand (63 μm 0–10%), there were no relationships for U_crit, whereas mass eroded appeared to increase with increasing chla and colloidal carbohydrate. The increased carbohydrate may stick sand grains together, altering the nature of erosion from rolling grains to clumps of resuspension.     

Suspended Sediment Transport in the Freshwater Reach of the Hudson River Estuary in Eastern New York

Deposition of Hudson River sediment into New York Harbor interferes with navigation lanes and requires continuous dredging. Sediment dynamics at the Hudson estuary turbidity maximum (ETM) have received considerable study, but delivery of sediment to the ETM through the freshwater reach of the estuary has received relatively little attention and few direct measurements. An acoustic Doppler current profiler was positioned at the approximate limit of continuous freshwater to develop a 4-year time series of water velocity, discharge, suspended sediment concentration, and suspended sediment discharge. This data set was compared with suspended sediment discharge data collected during the same period at two sites just above the Hudson head-of-tide (the Federal Dam at Troy) that together represent the single largest source of sediment entering the estuary. The mean annual suspended sediment–discharge from the freshwater reach of the estuary was 737,000 metric tons. Unexpectedly, the total suspended sediment discharge at the study site in November and December slightly exceeded that observed during March and April, the months during which rain and snowmelt typically result in the largest sediment discharge to the estuary. Suspended sediment discharge at the study site exceeded that from the Federal Dam, even though the intervening reach appears to store significant amounts of sediment, suggesting that 30–40% of sediment discharge observed at the study site is derived from tributaries to the estuary between the Federal Dam and study site. A simple model of sediment entering and passing through the freshwater reach on a timescale of weeks appears reasonable during normal hydrologic conditions in adjoining watersheds; however, this simple model may dramatically overestimate sediment delivery during extreme tributary high flows, especially those at the end of, or after, the “flushing season” (October through April). Previous estimates of annual or seasonal sediment delivery from tributaries and the Federal Dam to the ETM and harbor may be high for those years with extreme tributary high-flow events.     

Internal control of fluid compositions in amphibolite-facies scapolitic calc-silicates,Mary Kathleen,Australia

Unaltered metasediments of the Mary Kathleen Fold Belt are composed predominantly of layered amphibolite-facies scapolitic calc-silicate rocks in which minimal infiltration of externally derived fluids occurred during regional metamorphism. There were substantial differences in volatile activities between different layers in the layered sequences, in particular: a _CO2/a _{H 2 O} inferred from reaction progress estimates and analysis of biotite-clinopyroxene-fluid phase relations; a _NaCl/a _{H 2 O} inferred from scapolite compositions; and a _HCl/a _{H 2 O} inferred from biotite compositions. In one outcrop in which a clinopyroxene-producing reaction dominated, differences in approximate X _{CO 2}of up to 0.25 occurred between several samples collected over 50 metres. Variations in a _{H 2 O}/a _HCl of up to one order of magnitude are inferred at 1 to 50 m scales from biotite-Cl contents, and variations in NaCl contents of scapolite from 0.0 to up to 0.6 Cl atoms in the Cl–CO₃–SO₄ site reflect a large variation of a _NaCl in the coexisting fluid at similar scales. Most calcsilicate layers internally buffered fluid compositions in the H₂O–CO₂–NaCl–HCl system. Local occurrences of NaCl-rich scapolite suggest that some layers may have been in equilibrium with halite during early prograde metamorphism. At peak metamorphic temperatures, disolution of halite was complete but layers containing high-NaCl scapolite continued to buffer fluid at high values of a _NaCl. Fluid immiscibility does not appear to have affected the progress of the devolatilization reactions. Although fluid was predominantly internally buffered, moderate quantities of fluid were released by prograde mineral reactions in many layers, up to 30 cm³ fluid per 100 cm³ rock. Numerous episodes of fluid escape were required, probably via microfractures, such that the released fluid did not obviously influence reaction progress in the layers through which it passed. The anomaly of beautifully preserved internal buffering signatures and the requirement for produced fluid locally to pass across layers in a deforming rock sequence suggest that the escaping fluid did not leave any readily observable tracks. This is explained by rapid rates of fracture propogation and fluid migration therein. This internally buffered system contrasts strongly with adjacent calc-silicate rocks that show evidence for infiltration of externally derived fluids at high fluid/rock ratios, and highlights the broad range of fluid behaviour that can be expected in deforming, heterogeneous rock sequences.     

A record of ductile syn-intrusional fabrics to post solidification cataclasis: Magnetic fabric analysis of neoproterozoic Mirpur and Mt. Abu Granitoids,NW India

The Mirpur granite body represents a relatively small (10 km²) pluton intruded along the northern margin of the adjacent Mt. Abu batholith (∼125 km²) in NW India. It is a visibly undeformed alkali feldspar rich pink granite; in contrast, the Mt. Abu is a composite granitoid body and variably deformed. Both are intruded by rhyolitic dykes and the terminal magmatic events in both the cases are mafic dykes. The AMS (Anisotropy of Magnetic Susceptibility) data identify the Mt. Abu with SE-dipping foliations and subvertical lineations as a single structural domain while the Mirpur granite body shows two domains characterized by predominantly E — W trend of magnetic foliation in the eastern part (domain I) and N — S orientations in the western part (domain II). The domain I shows magmatic fabrics, typical for the peraluminous granites of Malani Igneous Suite (MIS). Change in fabric orientation in the domain II has resulted from cataclasis wherein the samples show destruction of the original E — W fabric and complete transposition by N — S trends. The foliations in the Mt. Abu granites have been related to SE orientation of maximum horizontal stress. The same maximum stress direction can be inferred from dyke orientation in the Mirpur granite, which is interpreted as continuation of the tectonic imprint in this region during emplacement of both the granites. Age of the cataclastic overprint with a predominant N — S orientation is not yet constrained but corresponds with the trend of the nearby Sindreth basin within the Malani Igneous Suite. The Neoproterozoic tectonic scenario for the region has been interpreted in terms of an ongoing crustal convergence and granitic magma emplacement against the back stop offered by the rigid Delhi Fold Belt.     

Morphometric comparisons between automated and manual karst depression inventories in Apalachicola National Forest,Florida, and Mammoth Cave National Park,Kentucky, USA

Karst depression catalogs are critical to assessing the hydrology and geohazards of an area; yet, the delineation of these features within a landscape can be a difficult, time-consuming and subjective task. This study evaluates the efficacy of karst depression inventorying using an automated fill-difference method operating on high-resolution lidar-derived digital elevation models (DEMs). The resulting catalog is compared with existing karst depression inventories for two low-development areas of the USA, Mammoth Cave National Park (MACA) and Apalachicola National Forest (ANF), where karst depressions have been mapped previously using a manual closed-contour approach. The automated fill method captures 93 and 85 % of these previously mapped karst depressions at MACA and ANF, respectively. Field observations and topographic analysis suggest that the omitted features were likely misclassified within the existing catalogs. The automated routine returns 797 and 3377 additional topographic depressions, at MACA and ANF, respectively, which are not included in the existing catalogs. While the geology of ANF is mostly homogenous Quaternary deposits, the newly identified, typically smaller-scale depressions found within MACA tend to be disproportionally located in non-carbonate-dominated formations, where the development of karst may be restricted by geologic heterogeneity. Within both areas, the size distributions of the two inventories are statistically identical for features larger than ~10³ m² in area or ~3 m in depth. For individual depressions captured by both methods at MACA, the automated fill-difference routine tends to return a slightly larger estimate of depression size and aggregate small depressions into larger ones. Conversely, at ANF, some low-relief depressions may be disaggregated by the fill-difference technique, with a trend toward smaller estimated depression areas when the automated method is employed. The automated fill-difference method, operating on high-resolution lidar-derived DEMs, can reproduce and expand the existing inventories of karst depressions, while minimizing false detections that may be inherent within pre-existing catalogs.     

The Role of Zooplankton Grazing and Nutrient Loading in the Occurrence of Harmful Cyanobacterial Blooms in Florida Bay,USA

Florida Bay is Florida’s (USA) largest estuary and has experienced harmful picocyanobacteria blooms for nearly two decades. While nutrient loading is the most commonly cited cause of algal blooms in Florida Bay, the role of zooplankton grazing pressure in bloom occurrence has not been considered. For this study, the spatial and temporal dynamics of cyanobacteria blooms, the microbial food web, microzooplankton and mesozooplankton grazing rates of picoplankton, and the effects of nutrients on plankton groups in Florida Bay were quantified. During the study, cyanobacteria blooms (>3 × 10⁵ cells mL⁻¹) persisted in the eastern and central regions of Florida Bay for more than a year. Locations with elevated abundance of cyanobacteria hosted microzooplankton grazing rates on cyanobacteria that were significantly lower (p < 0.001) and less frequently detectable compared to sites without blooms. Consistent with this observation, cyanobacteria abundances were significantly correlated with ciliates and heterotrophic nanoflagellates at low cyanobacteria densities (p < 0.001) but were not correlated during bloom events. The experimental enrichment of mesozooplankton abundance during blooms yielded a significant decrease in the net growth rate of picoplankton but had the opposite effect when blooms were absent, suggesting that the cascading effect of mesozooplankton grazing on the microbial food web was also altered during blooms. While inorganic nutrient enrichment significantly increased the net growth rates of eukaryotic phytoplankton and heterotrophic bacteria, such nutrient loading had no effect on the net growth rates of cyanobacteria. Hence, this study demonstrates that low rates of zooplankton grazing and low rates of inorganic nutrient loading contribute to the persistence of cyanobacteria blooms in Florida Bay.     

Predicting post-fire debris flow grain sizes and depositional volumes in the Intermountain West,United States

Post-fire debris flows represent one of the most erosive consequences associated with increasing wildfire severity and investigations into their downstream impacts have been limited. Recent advances have linked existing hydrogeomorphic models to predict potential impacts of post-fire erosion at watershed scales on downstream water resources. Here we address two key limitations in current models: (1) accurate predictions of post-fire debris flow volumes in the absence of triggering storm rainfall intensities and (2) understanding controls on grain sizes produced by post-fire debris flows. We compiled and analysed a novel dataset of depositional volumes and grain size distributions (GSDs) for 59 post-fire debris flows across the Intermountain West (IMW) collected via fieldwork and from the literature. We first evaluated the utility of existing models for post-fire debris flow volume prediction, which were largely developed for Southern California. We then constructed a new post-fire debris flow volume prediction model for the IMW using a combination of Random Forest modelling and regression analysis. We found topography and burn severity to be important variables, and that the percentage of pre-fire soil organic matter was an essential predictor variable. Our model was also capable of predicting debris flow volumes without data for the triggering storm, suggesting that rainfall may be more important as a presence/absence predictor, rather than a scaling variable. We also constructed the first models that predict the median, 16th percentile, and 84th percentile grain sizes, as well as boulder size, produced by post-fire debris flows. These models demonstrate consistent landscape controls on debris flow GSDs that are related to land cover, physical and chemical weathering, and hillslope sediment transport processes. This work advances our ability to predict how post-fire sediment pulses are transported through watersheds. Our models allow for improved pre- and post-fire risk assessments across diverse ranges of watersheds in the IMW.     

Response of estuarine meio- and macrofauna to in situ bioremediation of oil-contaminated sediment

Numerous studies have demonstrated the efficacy of bioremediation for enhancing oil removal but the ecological effect on shoreline biota is unclear. Therefore, a field experiment was designed at an intertidal sandflat in SW England to assess the effects of nutrient addition to oiled sediments on meio- and macrofauna for a period of up to 45 weeks. Natural assemblages were exposed to different types of experimental treatments (no oil, oil alone, oil treated with slow-release fertiliser or liquid fertiliser). Bioremediation stimulated the microbial population and increased oil biodegradation. This, however, did not result in faster recolonisation rates of fertilised versus non-fertilised oiled sediments. Mild effects of oil and bioremediation treatments on benthic fauna were observed, including short-term shifts in dominance patterns. Decreased abundance of dominant species in the oiled compared to unoiled sediments resulted in significantly higher evenness of benthic assemblages within the first 11 weeks of the experiment.