Numerical modelling-based comparison of longitudinal dispersion coefficient formulas for solute transport in rivers

River water quality models usually apply the Fischer equation to determine the longitudinal dispersion coefficient (D_x) in solving the advection–dispersion equation (ADE). Recently, more accurate formulas have been introduced to determine D_x in rivers, which could strongly affect the accuracy of the ADE results. A numerical modelling-based approach is presented to evaluate the performance of various D_x formulas using the ADE. This approach consists of a finite difference approximation of the ADE, a MATLAB code and a MS Excel interface; it was tested against the analytical ADE solution and demonstrated using eight well-known D_x formulas and tracer study data for the Chattahoochee River (USA), the Severn (UK) and the Athabasca (Canada). The results show that D_x has an important effect on tracer concentrations simulated with the ADE. Comparison between the simulated and measured concentrations confirms the appropriate performance of Zeng and Huai’s formula for D_x estimation. Use of the newly proposed equations for D_x estimation could enhance the accuracy of solving the ADE.     

Chemometric Differentiation of Oil Families and Their Potential Source Rocks in the Gulf of Suez

Natural Resources Research - An oil–oil and oil–source rock correlation study was carried out using chemometric methods applied to geochemical data for 123 Upper Cretaceous—Lower...     

Assessment of persistent organochlorine pollutants in sediments from Lake Manzala, Egypt

Organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs) were determined in surface and core sediment samples collected from Manzala Lake, the largest of the Egyptian coastal lakes. Total concentrations of OCPs and ∑7 PCBs (ICES) in sediments ranged from 0.63 to 31.31 ng/g and 0.26 to 31.27 ng/g, respectively. Geographical distribution indicates that levels of contaminants were significantly higher in areas which are mainly influenced by municipal discharge, indicating significant sources of these compounds in urbanised areas. The composition of DDT and its metabolites suggest old input of DDT. The levels of contaminants in Manzala Lake were similar or lower than those observed in comparable areas worldwide. The profiles of ∑OCPs and ∑PCBs in a core from a site heavily impacted by sewage discharge have highest concentrations in the surface core section indicating recent inputs. Assessment of ecotoxicological risk indicated that sediments in two sites were likely to pose potential biological adverse impact.     

A new method for processing of low-grade monazite concentrates

It is very tedious to separate thorium and rare earth elements from their accompanying constituents in low-grade monazite (concentrate 50%) containing large amount of phosphorus species, illiminite, silica and zircon. Therefore, trials have been suggested to develop a new procedure to enhance the separation process of the light lanthanides from low-grade Egyptian monazite concentrates. The first point is focused on the removal of phosphorus species from the digested low-grade monazite with sulfuric acid in order to get more convenient separation. The removal was accomplished by extractive washing of sulfate paste with different alcohols. The results showed that the extractive removal of phosphorus species was not effective due to the complex nature of low-grade monazite concentrate. The second point is focused on the enhancement of separation process of uranium, thorium and rare earth elements by new ratio of sulfuric acid and develops the classical separation process. By this modified procedure, the overall results obtained revealed that the unleached residue contains mainly Si, Fe, Zr, and Ti while the elements of main consideration such as uranium, thorium and light rare earth elements were completely leached. Thorium and light rare earth elements (LREEs) were directly separated as white precipitate while the uranium was moved to the green acid solution with most of phosphorus species. This throws light on the possibility of separation of thorium and light rare earth elements from uranium, which represents a novel method.     

The impact of climatic variability and change in the hydroclimatology of Lake Winnipeg watershed

The hydroclimatology of prairie‐dominated portions of the Lake Winnipeg watershed was investigated to determine the possible presence of trends and shifts in variables that may influence the streamflow regimes and water quality of Lake Winnipeg. The total annual streamflow, precipitation, runoff ratio and daily maximum streamflow in the two major tributaries of the Assiniboine River and Red River were analysed for a range of nonstationary behaviours. Each of these rivers has been gauged for more than 90 years. The methods used included a nonparametric Mann–Kendall test modified to account for diverse memory properties (i.e. short term versus long term) and a Bayesian change point detection model to identify possible segments of time series with inconsistent nonstationary behaviour. Although there is no evidence of statistically significant trends in precipitation and streamflow in the Assiniboine River watershed, a shift‐type nonstationarity in annual runoff and runoff ratio was observed in this area, which is manifested in the form of a sequence of wet and dry spells during the last century. Precipitation and runoff metrics in the American portion of the study area (i.e. Red River watershed) were characterised with both gradual and abrupt changes with an extremely increasing rate of streamflow beyond that of intensified precipitation. The nonproportional watershed runoff response is attributed to the dynamic nature of contributing areas that, together with the semiarid climate, leads to sudden changes of streamflow due to major or even some times minor changes in climate inputs. It is evident that streamflow in the depression‐dominated landscapes of the semiarid glaciated plains of North America is particularly sensitive and vulnerable to minor climate variability and change. This study provides valuable insights into the highly complex precipitation–runoff relationship in depression‐dominated landscapes and could have important implications for water management in this part of North America and comparable regions. Copyright © 2011 John Wiley & Sons, Ltd.     

Application of fuzzy Delphi AHP method for the estimation and classification of Ghomrud tunnel from groundwater flow hazard

Water inflow and water pressure controls are needed in the design, construction, and exploitation of tunnels. The objective of this paper is to present a new system which can be appropriate for rating tunnel sites to evaluate the potential of groundwater inflow according to the preliminary site investigation data. In this paper, an evaluation model based on combining the analytic hierarchy process and the fuzzy Delphi method has been presented for assessing tunnel site rating from the groundwater hazard point of view. This research treats the tunnel site classification as a group decision problem and applies the fuzzy logic theory as the criterion to calculate the weighting factors. Afterward, the proposed method was successfully applied to determine the amount of groundwater inflow into tunnels. Results of several case studies in various geological conditions roughly show that it can be used to determine the groundwater inflow into tunnels. The introduced method has been examined successfully in Ghomroud tunnel. Results from the proposed method, analytical equations, and observed groundwater inflow into Ghomrud tunnel have been compared. Results show that, because most of parameters regulating groundwater inflow into tunnels have been considered in the method, results from the method are very close to the observed groundwater inflow. Applying this method, according to preliminary investigations conducted by the designers, provides a more suitable design of the drainage system, drilling method, and tunnel support.     

Structural and biological control of the Cenozoic epithermal uranium concentrations from the Sierra Pe?a Blanca, Mexico

Epithermal uranium deposits of the Sierra Pe?a Blanca are classic examples of volcanic-hosted deposits and have been used as natural analogs for radionuclide migration in volcanic settings. We present a new genetic model that incorporates both geochemical and tectonic features of these deposits, including one of the few documented cases of a geochemical signature of biogenic reducing conditions favoring uranium mineralization in an epithermal deposit. Four tectono-magmatic faulting events affected the volcanic pile. Uranium occurrences are associated with breccia zones at the intersection of fault systems. Periodic reactivation of these structures associated with Basin and Range and Rio Grande tectonic events resulted in the mobilization of U and other elements by meteoric fluids heated by geothermal activity. Focused along breccia zones, these fluids precipitated under reducing conditions several generations of pyrite and uraninite together with kaolinite. Oxygen isotopic data indicate a low formation temperature of uraninite, 45–55°C for the uraninite from the ore body and ～20°C for late uraninite hosted by the underlying conglomerate. There is geochemical evidence for biological activity being at the origin of these reducing conditions, as shown by low δ³⁴S values (～?24.5‰) in pyrites and the presence of low δ¹³C (～?24‰) values in microbial patches intimately associated with uraninite. These data show that tectonic activity coupled with microbial activity can play a major role in the formation of epithermal uranium deposits in unusual near-surface environments.     

Numerical simulation of waves in the Caspian Sea: calibration and verification of the observation-based source terms

Ocean Dynamics - Third-generation models employ a host of parameterization schemes to consider the input wind forcing and the wave energy dissipation under different physical settings and...     

Groundwater potential modelling using remote sensing and GIS: a case study of the Al Dhaid area,United Arab Emirates

The Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) DEM and LANDSAT images of spatial resolution 30?m were used to construct groundwater potential zones (GPZ) map by integrating geological fractures, drainage network, slope and relief, and convergence index maps of the study area. Weight and score of each map were developed according to their level of contribution toward groundwater accumulation and spatial distribution of groundwater wells. The area that has very high potential for groundwater is located at the foot of Oman Mountains and Al Dhaid Depression covering an area of about 59.33?km², which is 4.40% of the study area. Further hydrological map and data on hydraulic properties of shallow aquifer, as recorded from observation wells in the regions, have been used to validate the produced GPZ map. The validation result showed sufficient agreement between the produced GPZ map.