Hydrological response characteristics of Mediterranean catchments at different time scales: a meta-analysis

ABSTRACT

This work examines 140 hydrological studies conducted in the Mediterranean region. It identifies key characteristics of the hydrological responses of Mediterranean catchments at various time scales and compares different methods and modelling approaches used for individual-catchment studies. The study area is divided into the northwestern (NWM), eastern (EM) and southern (SM) Mediterranean. The analysis indicates regional discrepancies in which the NWM shows the most extreme rainfall regime. A tendency for reduced water resources driven by both anthropogenic and climatic pressures and a more extreme rainfall regime are also noticeable. Catchments show very heterogeneous responses over time and space, resulting in limitations in hydrological modelling and large uncertainties in predictions. However, few models have been developed to address these issues. Additional studies are necessary to improve the knowledge of Mediterranean hydrological features and to account for regional specificities.

Editor D. Koutsoyiannis Associate editor A. Efstratiadis     

Fast mapping of magnetic basement depth,structure and nature using aeromagnetic and gravity data: combined methods and their application in the Paris Basin

Assessment of deep buried basin/basement relationships using geophysical data is a challenge for the energy and mining industries as well as for geothermal or CO₂ storage purposes. In deep environments, few methods can provide geological information; magnetic and gravity data remain among the most informative and cost‐effective methods. Here, in order to derive fast first‐order information on the basement/basin interface, we propose a combination of existing and original approaches devoted to potential field data analysis. Namely, we investigate the geometry (i.e., depth and structure) and the nature of a deep buried basement through a case study SW of the Paris Basin. Joint processing of new high‐resolution magnetic data and up‐to‐date gravity data provides an updated overview of the deep basin. First, the main structures of the magnetic basement are highlighted using Euler deconvolution and are interpreted in a structural sketch map. The new high‐resolution aeromagnetic map actually offers a continuous view of regional basement structures and reveals poorly known and complex deformation at the junction between major domains of the Variscan collision belt. Second, Werner deconvolution and an ad hoc post‐processing analysis allow the extraction of a set of magnetic sources at (or close to) the basin/basement interface. Interpolation of these sources together with the magnetic structural sketch provides a Werner magnetic basement map displaying realistic 3D patterns and basement depths consistent with data available in deep petroleum boreholes. The last step of processing was designed as a way to quickly combine gravity and magnetic information and to simply visualize first‐order petrophysical patterns of the basement lithology. This is achieved through unsupervised classification of suitably selected gravity and magnetic maps and, as compared to previous work, provides a realistic and updated overview of the cartographic distribution of density/magnetization of basement rocks. Altogether, the three steps of processing proposed in this paper quickly provide relevant information on a deep buried basement in terms of structure, geometry and nature (through petrophysics). Notwithstanding, limitations of the proposed procedure are raised: in the case of the Paris Basin for instance, this study does not provide proper information on Pre‐Mesozoic basins, some of which have been sampled in deep boreholes.     

GIS-based impact assessment of land-use changes on groundwater quality: study from a rapidly urbanizing region of South India

This study attempts to assess the influence of changing land-use patterns on the groundwater quality of the hard rock aquifer system in the Maheshwaram watershed, near Hyderabad, India. The study area is a rapidly urbanizing region with land development progressing at a fast pace. To study the impact of this rapid urbanization and overall land-use transition, a groundwater quality index (GQI) was prepared within a geographical information system (GIS). The GQI integrates the different water quality parameters to give a final index value that can be used for spatio-temporal comparisons. The land-use transitions were closely monitored from 2003 to 2008 using multispectral satellite images. The land-use pattern has changed drastically with an increase in the built-up area at the expense of other land uses. The analysis reveals a rapid deterioration of groundwater quality related mainly to the increase in built-up land with unsewered sanitation and poultry farms. Seasonal variability of the groundwater quality was also assessed. Mean GQI decreased from 84.16 to 83.26 over a period of 5 years from 2003 to 2008, while seasonal variability of water quality increased. GQI and Seasonal Variability of water quality were integrated in GIS to yield a groundwater sustainability map, in terms of water quality. Zones of sustainable and unsustainable groundwater use were demarcated for better decision making related to municipal land allotment in this rapidly urbanizing region.     

A first deep seismic survey in the Sea of Marmara: Deep basins and whole crust architecture and evolution

Increased source strength, streamer length and dense spatial coverage of seismic reflection profiles of the SEISMARMARA Leg 1 allow to image the deep structure of the marine North Marmara Trough (NMT) on the strike-slip North Anatolian Fault (NAF) west of the destructive Izmit 1999 earthquake. A reflective lower crust and the Moho boundary are detected. They appear upwarped on an E-W profile from the southern Central Basin eastwards, towards more internal parts of the deformed region. Thinning of the upper crust could use a detachment suggested from an imaged dipping intracrustal reflector that would allow upper crustal material to be dragged from beneath it and above the lower crust, accounting for the extensional component but also southwest motion of the southern margin of the NMT. Sections across the eastern half of the NMT, crossing the Cinarcik and Imrali basins, reveal several faults that are active reaching into the basement and have varying strike and proportions of normal and strike-slip displacement. They might be viewed as petals of a large scale negative flower-structure that spreads over a width of 30 km at surface and is rooted deeper in the lithosphere. Under the Central Basin a very thick sediment infill is revealed and its extensional bounding faults are active and imaged as much as 8 km apart down to 6 km depth. We interpret them as two deep-rooted faults encompassing a foundering basement block, rather than being merely pulled-apart from a jog in a strike-slip above a décollement. The deep-basin lengthening would account for only a modest part of the proposed 60 km finite motion since 4 Myr along the same direction oblique to the NMT that sidesteps the shear motion from its two ends. Thus differential motion occurred much beyond the deep basins, like subsidence involving the NMT bounding faults and the intracrustal detachments. The complex partitioned motion localized on active faults with diverse natures and orientations is suggested to represent the overburden deformation induced from horizontal plane simple shear occurring in depth at lithospheric scale, and in front of the North Anatolian Fault when it propagated through the region.     

Complex origin for the south-western Zamboanga metamorphic basement complex, Western Mindanao, Philippines

Abstract Amphibolites unconformably overlain by a metasedimentary sequence of quartz-muscovite-feldspar-kyanite schists, metagraywackes and epidote-bearing amphibolites occur in the northern portion of the south-western Zamboanga metamorphic basement complex, western Mindanao. These amphibolites (here identified as the Mount Dansalan amphibolites) display relict magmatic textures inherited from cumulate gabbro protoliths. Bulk-rock major and trace-element data are consistent with this hypothesis. Together with the chemistry of relict igneous clinopyroxenes, they indicate a magmatic arc-related signature for the gabbro protoliths. Geochemical data allow us to identify various sources for the associated metasediments: the gabbro themselves for the metagraywackes and a continental basement for the quartz-muscovite-feldspar-kyanite schists. Both sources contributed to the genesis of the epidote-amphibolite metasediments. The compositions of the metamorphic mineral assemblages suggest that the rocks have undergone metamorphism at temperatures ranging from 550°C to 700°C and pressures probably in the range of 5–9 kbar. ⁴⁰K–⁴⁰Ar isotopic study of amphibole separates from the Mount Dansalan samples document a metamorphic event dated at 24.6 ± 1.4, 22.2 ± 1.4 and 21.2 ± 1.2 Ma. Our results are in agreement with plate tectonic models which describe the south-western Zamboanga metamorphic basement as a continental terrane. However, its evolution was not as simple as it was usually considered. In particular the basement incorporated slivers of magmatic arc crust, which cannot be unambiguously related to any of the Tertiary arcs documented in the area.     

Impact of nitrogenous fertilizers on carbonate dissolution in small agricultural catchments: Implications for weathering CO2 uptake at regional and global scales

The goal of this study was to highlight the occurrence of an additional proton-promoted weathering pathway of carbonate rocks in agricultural areas where N-fertilizers are extensively spread, and to estimate its consequences on riverine alkalinity and uptake of CO₂ by weathering. We surveyed 25 small streams in the calcareous molassic Gascogne area located in the Garonne river basin (south-western France) that drain cultivated or forested catchments for their major element compositions during different hydrologic periods. Among these catchments, the Hay and the Montoussé, two experimental catchments, were monitored on a weekly basis. Studies in the literature from other small carbonate catchments in Europe were dissected in the same way. In areas of intensive agriculture, the molar ratio (Ca + Mg)/HCO₃ in surface waters is significantly higher (0.7 on average) than in areas of low anthropogenic pressure (0.5). This corresponds to a decrease in riverine alkalinity, which can reach 80% during storm events. This relative loss of alkalinity correlates well with the content in surface waters. In cultivated areas, the contribution of atmospheric/soil CO₂ to the total riverine alkalinity (CO_{2 ATM-SOIL}/HCO₃) is less than 50% (expected value for carbonate basins), and it decreases when the nitrate concentration increases. This loss of alkalinity can be attributed to the substitution of carbonic acid (natural weathering pathway) by protons produced by nitrification of N-fertilizers (anthropogenic weathering pathway) occurring in soils during carbonate dissolution. As a consequence of these processes, the alkalinity over the last 30 years shows a decreasing trend in the Save river (one of the main Garonne river tributaries, draining an agricultural catchment), while the nitrate and calcium plus magnesium contents are increasing.We estimated that the contribution of atmospheric/soil CO₂ to riverine alkalinity decreased by about 7-17% on average for all the studied catchments. Using these values, the deficit of CO₂ uptake can be estimated as up to 0.22-0.53 and 12-29 Tg¹ yr⁻¹ CO₂ on a country scale (France) and a global scale, respectively. These losses represent up to 5.7-13.4% and only 1.6-3.8% of the total CO₂ flux naturally consumed by carbonate dissolution, for France and on a global scale, respectively. Nevertheless, this loss of alkalinity relative to the Ca + Mg content relates to carbonate weathering by protons from N-fertilizers nitrification, which is a net source of CO₂ for the atmosphere. This anthropogenic CO₂ source is not negligible since it could reach 6-15% of CO₂ uptake by natural silicate weathering and could consequently partly counterbalance this natural CO₂ sink.     

Concentrations of the elements Ag,Al, Ca,Cd, Cu,Fe, Mg,Mn, Pb and Zn,and the radionuclides 210Pb and 210Po in the digestive gland of the squid Nototodarus gouldi

Ag, Al, Ca, Cd, Cu, Fe, Mg, Mn, Pb and Zn concentrations and ²¹⁰Po and ²¹⁰Pb activities were measured in 26 specimens of the squid Nototodarus gouldi taken from the waters of Bass Strait in one jigging operation. All the elements show wide ranges in concentrations in specimens apparently subject to the same environmental conditions. Copper concentration was 27-1 200 μg/g, and ²¹⁰Po activity 4·8–24·2 Bq/g. The animal wet weights, the elements Ag, Al, Cd, Fe and Zn, and the radionuclide ²¹⁰Po have coefficients of variation in the range 40–60%; Ca, Mg and Mn show the smallest variability (CV = < 30%), and Cu the greatest (CV = 12%). Significant correlations (p < 0·001) were found between the following pairs of elements: Cd-Zn, Cd-Cu, Zn-Cu, Mg-Mn, Fe-Mn, Ca-Mg and Fe-²¹⁰Po.