Late Weichselian relative sea-level changes and ice sheet history in southeast Greenland

Relative sea-level (RSL) observations from the margins of the Greenland Ice Sheet (GIS) provide information regarding the timing and rate of deglaciation and constraints on geophysical models of ice sheet evolution. In this paper we present the first RSL record for the southeast sector of the GIS based on field observations completed close to Ammassalik. The local marine limit is c. 69 m above sea-level (asl) and is dated to c. 11 k cal. yrs BP (thousand calibrated years before present) and is a minimum date for ice free conditions at the study site. RSL fell to c. 24 m asl by 9.5 k cal. yrs BP and continued to fall at a decreasing rate to reach close to present by 6.5 k cal. yrs BP. Our chronology agrees with radiocarbon dates from offshore cores that indicate ice free conditions on the adjacent mid-shelf by 15 k cal. yrs BP. We compare the new RSL data with predictions generated using two recently published glaciological models of the GIS that differ in the amount and timing of ice loading and unloading over our study area. These two GIS models are coupled to the same Earth viscosity model and background (global) ice model to aid in the data-model comparison. Neither model provides a close fit to the RSL observations. Based on a preliminary sensitivity study using a suite of Earth viscosity models, we conclude that the poor data-model fit is most likely due to an underestimate of the local ice unloading. An improved fit could be achieved by delaying the retreat of a thicker ice sheet across the continental shelf. A thick ice sheet extending well onto the continental shelf is in agreement with other recent observations elsewhere in east and south Greenland.     

Luminescence quenching of dissolved organic matter in seawater

To characterize more fully the nature of the fluorophores present in the dissolved organic matter found in seawater, steady state and time-resolved measurements of the luminescence quenching of a number of samples of marine dissolved organic matter with known quenchers, such as iodide, acrylamide and methyl viologen (MV) (1,1′-dimethyl-4,4′-bipyridinium), were compared. Quenching characteristics of these systems were analyzed using Stern-Volmer plots for both intensity and lifetime measurements. The bimolecular quenching constants, κ_q, for these quenchers were found to decrease in the order MV²⁺ (κ_q 10¹⁰M⁻¹s⁻¹) > I⁻ (κ_q 2 × 10⁹ M⁻¹ s⁻¹) >CH₂CHCONH₂ (κ_q 2 × 10⁸ M⁻¹ s⁻¹) for the samples measured. The results also show that different samples are quenched to differing extents by the quenchers studied, that ionic strength alters the quenching constants, and that both static and diffusional quenching mechanisms may operate.Such studies are appropriate to the quantification of the reactivity of the singlet states of the chromophores found within marine dissolved organic matter. Although excess energy of the singlet state may be readily transferred to another chemical species, the combination of competing physical deactivation paths and the low concentrations of efficient quenches in the oceans serves to lessen the direct chemical impact of this process.     

Restructuring Governance of New Zealand Seaports: Geographical Impacts of Corporatisation

This study examines the rationales for and geographical outcomes of the post 1988 changes in port governance in New Zealand and their implications from a policy perspective. The study offers insights into the interrelationship between global processes and local places in the context of economic deregulation, a devolved infrastructure planning mandate and intra‐industry competitive dynamics. A trend towards port concentration consequent on globalisation has been long recognised in the international literature. In New Zealand, the trend towards port concentration can be described as selective, limited primarily to import trade while export trade is more dispersed. This new port geography is part of wider political and socio‐economic development geographies of the national and global hinterlands and forelands these ports interact with.     

Evaluation of a numerical model of the British–Irish ice sheet using relative sea‐level data: implications for the interpretation of trimline observations

The glacial isostatic adjustment (GIA) of the British Isles is complex due to the interplay between local and non‐local signals. A number of recent studies have modelled the GIA response of the British Isles using relative sea‐level data. This study extends these previous analyses by using output from a numerical glaciological model as input to a GIA model. This is a necessary step towards more realistic GIA models, and although there have been similar studies for the major late Pleistocene ice sheets, this is the first study to do so for the British Isles. We test three reconstructions, classed as ‘minimal’, ‘median’ and ‘maximal’ in terms of their volume at maximum extent, and find it is possible to obtain good data–model fits. The minimal reconstruction is clearly preferred by the sea‐level data. The ice reconstructions tested were not constrained by geomorphological information of past ice extent (lateral and vertical). As a consequence, the reconstructions extend further than much of this information suggests, particularly in terms of ice thickness. It is notable, however, that the reconstructions produce good fits to many sea‐level data from central, mountainous regions (e.g. Scottish highlands), which lends support to the suggestion that trimlines, often used as an constraint on the palaeo ice surface location, are in fact features formed at the transition from warm‐ to cold‐based ice and so mark a minimum constraint on the ice surface altitude. Based on data–model misfits, suggestions are made for improving the ice model reconstructions. However, in many locations, the cause of the misfit could be due to non‐local, predominantly Fennoscandian ice and so interpretation is not straightforward. As a result, we suggest that future analyses of this type consider models and observations for both Fennoscandia and the British Isles. Copyright © 2012 John Wiley & Sons, Ltd.     

Postglacial relative sea‐level observations from Ireland and their role in glacial rebound modelling

The British Isles have been the focus of a number of recent modelling studies owing to the existence of a high‐quality sea‐level dataset for this region and the suitability of these data for constraining shallow earth viscosity structure, local to regional ice sheet histories and the magnitude/timing of global meltwater signals. Until recently, the paucity of both glaciological and relative sea‐level (RSL) data from Ireland has meant that the majority of these glacial isostatic adjustment (GIA) modelling studies of the British Isles region have tended to concentrate on reconstructing ice cover over Britain. However, the recent development of a sea‐level database for Ireland along with emergence of new glaciological data on the spatial extent, thickness and deglacial chronology of the Irish Ice Sheet means it is now possible to revisit this region of the British Isles. Here, we employ these new data to constrain the evolution of the Irish Ice Sheet. We find that in order to reconcile differences between model predictions and RSL evidence, a thick, spatially extensive ice sheet of ～600–700 m over much of north and central Ireland is required at the LGM with very rapid deglaciation after 21 k cal. yr BP. Copyright © 2007 John Wiley & Sons, Ltd.     

Combining visual and geochemical analyses to source chert on Southern Baffin Island,Arctic Canada

A combined methodological approach using visual and geochemical methods is introduced and preliminary results of a study illustrating its effectiveness to determine chert source provenance are presented. This study focuses on lithic debitage and raw chert samples collected from the interior of southern Baffin Island, Arctic Canada. Chert is abundant throughout this region yet it occurs as small, scattered surface nodules that are highly variable in color. Prior to this study, little was known about the provenance of this local toolstone and whether it derived from local outcrops, glacial till sheets, or both. Given the pronounced variability exhibited by this chert, we use individual attribute analysis and petrography to impose some kind of analytical order upon an otherwise random aggregation of rocks. Thereafter, inductively coupled plasma mass spectrometry and secondary ion mass spectrometry are used to test the validity of these color categories to determine from how many geochemically distinct sources they derive. Using a standard that measures Al to a ratio of Ga/Zr, our results indicate that all of the raw chert samples derive from a single local source, while the debitage derives from four different sources, including the one that is local. We are confident that this combined methodological approach can be applied in other regions where chert variability is pronounced and source provenance is unknown. © 2009 Wiley Periodicals, Inc.     

Wavelet Transforms Applied to Irregularly Sampled Soil Data

Wavelet transforms have been used widely to analyse environmental data. These data typically comprise a series of measurements taken at regular intervals in time or space. The analysis offers a decomposition of the data that distinguishes components at different spatial scales but also, unlike Fourier analysis, can resolve local intermittent features. Most wavelet methods require the data to be sampled at regular intervals and little attention has been paid to developing methods for data that are not. In this paper, we derive a discrete Haar wavelet transform for irregularly sampled data and show how the resulting wavelet coefficients can be used to estimate contributions of variance. We discuss the interpretation of these statistics using data on apparent soil electrical conductivity of soil measured across a landscape as an example.