The mineralogy and mineral associations of platinum group elements and gold in the Platreef at Zwartfontein, Akanani Project, Northern Bushveld Complex, South Africa

The mineralogy of the platinum-group elements (PGE), and gold, in the Platreef of the Bushveld Complex, was investigated using an FEI Mineral Liberation Analyser. Polished sections were prepared from 171 samples collected from two boreholes, for the in-situ examination of platinum group minerals (PGM). PGM and gold minerals encountered include maslovite (PtBiTe, 32 area% of total PGM), kotulskite (Pd(BiTe), 17?%), isoferroplatinum (Pt₃Fe, 15?%), sperrylite (PtAs₂, 11?%), cooperite (PtS, 5?%), moncheite (PtTe₂; 5?%), electrum (AuAg; 5?%), michenerite (PdBiTe; 3?%), Pd alloys (Pd, Sb, Sn; 3?%), hollingworthite ((Rh,Pt)AsS; 2?%), as well as minor (all <1 area% of total PGM) merenskyite (PdBiTe₂), laurite (RuS₂), rustenburgite (Pt_0.4Pd_0.4Sn_0.2), froodite (PdBi₂), atokite (Pd_0.5Pt_0.3Sn_0.2), stumpflite (PtSb), plumbopalladinite (Pd₃Pb₂), and zvyagintsevite (Pd₃Pb). An observed association of all PGM with base metal sulfides (BMS), and a pronounced association of PGE tellurides, arsenides and Pd&Pt alloys with secondary silicates, is consistent with the remobilisation and recrystallisation of some of the PGM’s during hydrothermal alteration and serpentinisation subsequent to their initial (primary) crystallisation from BMS (e.g. Godel et al. J Petrol 48:1569–1604, 2007; Hutchinson and McDonald Appl Earth Sci (Trans Inst Min Metall B) 114:B208–224, 2008).     

Palaeomagnetic results from Mounts Gambier and Schank,South Australia

Palaeomagnetic results are presented for two young volcanoes in southeastern Australia. Directions for the basalt and lava spatter, erupted near the beginning and end of activity at Mt Gambier respectively, are identical and suggest there was no long break in activity. The direction for basalt at Mt Schank differs from that of Mt Gambier by several degrees, and indicates that the two volcanoes differ in age, probably by three centuries or more. Directions for both volcanoes are much shallower than the present‐day geomagnetic direction at the locality. Palaeomagnetic field strength estimates, from baked ash at Mt Gambier and baked sand at Mt Schank, are higher than the present‐day field strength. Comparisons with other late Pleistocene and Holocene results suggest that ages for Mts Gambier and Schank are either greater than 7000 years or between 5000 and 1000 years. These conclusions are consistent with published radiocarbon ages from charcoal in fossil soil horizons sealed beneath ash deposits.     

Explosion craters associated with shallow submarine gas venting off Panarea island, Italy

Explosions of hot water, steam, and gas are common periodic events of subaerial geothermal systems. These highly destructive events may cause loss of life and substantial damage to infrastructure, especially in densely populated areas and where geothermal systems are actively exploited for energy. We report on the occurrence of a large number of explosion craters associated with the offshore venting of gas and thermal waters at the volcanic island of Panarea, Italy, demonstrating that violent explosions similar to those observed on land also are common in the shallow submarine environment. With diameters ranging from 5 to over 100?m, the observed circular seafloor depressions record a history of major gas explosions caused by frequent perturbation of the submarine geothermal system over the past 10,000?years. Estimates of the total gas flux indicate that the Panarea geothermal system released over 70?Mt of CO₂ over this period of time, suggesting that CO₂ venting at submerged arc volcanoes contributes significantly to the global atmospheric budget of this greenhouse gas. The findings at Panarea highlight that shallow submarine gas explosions represent a previously unrecognized volcanic hazard around populated volcanic islands that needs to be taken into account in the development of risk management strategies.     

Extreme sensitivity of crosshole electrical resistivity tomography measurements to geometric errors

The effects of geometric errors on crosshole resistivity data are investigated using analytical methods. Geometric errors are systematic and can occur due to uncertainties in the individual electrode positions, the vertical spacing between electrodes in the same borehole, or the vertical offset between electrodes in opposite boreholes. An estimate of the sensitivity to geometric error is calculated for each of two generic types of four-electrode crosshole configuration: current flow and potential difference crosshole (XH) and in-hole (IH). It is found that XH configurations are not particularly sensitive to geometric error unless the boreholes are closely spaced on the scale of the vertical separation of the current and potential electrodes. However, extremely sensitive IH configurations are shown to exist for any borehole separation. Therefore, it is recommended that XH configurations be used in preference to IH schemes. The effects of geometric error are demonstrated using real XH data from a closely spaced line of boreholes designed to monitor bioremediation of chlorinated solvents at an industrial site. A small fraction of the data had physically unrealistic apparent resistivities, which were either negative or unexpectedly large. However by filtering out configurations with high sensitivities to geometric error, all of the suspect data were removed. This filtering also significantly improved the convergence between the predicted and the measured resistivities when the data were inverted. In addition to systematic geometric errors, the measured data also exhibit a high level of random noise. Despite this, the resulting inverted images correspond reasonably closely with the known geology and nearby cone penetrometer resistivity profiles.     

Book reviews

Detritus and microbial ecology in aquaculture. B7 Editors: D. J. W. Moriarty and R. S. V. Pullin, 1987. Proceedings for the Conference on Detrital Systems for Aquaculture, Italy, August 1985. 420 p. ISSN 0115–4389, ISBN 971–1022–29‐X. Price: US$12.50 surface. Available from ICLARM, MC P. O. Box 1501, Makati, Metro Manila, Philippines.

Coastal fishes of New Zealand, a diver's identification guide. By Malcolm Francis, 1988. Heinemann Reed, Octopus Publishing Group Ltd., Auckland. 63 p. Price: $29.95. ISBN 0–7900–0013‐X.

Lake managers handbook. Editor: W. N. Vant 1987, Water Quality Centre, Ministry of Works and Development, Hamilton. Water & Soil Miscellaneous Publication 103, 230 p., 53 figures, 12 colour plates. Price: $38.50. ISSN 0110–4705. Available from DSIR Publishing, P.O. Box 9741, Wellington, New Zealand.     

Effects of small ponds on stream water quality and macroinvertebrate communities

Six small constructed ponds (surface area 500–7500 m², catchment area 28–158 ha) in rural and native forest catchments in the Auckland region had poorer water quality than the streams they replaced. Temperature (24°C) and dissolved oxygen (DO) (4 mg/litre) criteria were exceeded for up to 46% and 84% of days, respectively, during a critical 40‐day summer period. The poor conditions found in ponds, even within undeveloped native forest catchments, indicated that the physical characteristics of ponds (e.g., lack of shade, organic sediments) affected water quality independently of other factors (e.g., land use, riparian protection). The frequency and severity of the exceedences were related to pond size, retention time, and catchment land use; the most degraded conditions were found in rural ponds with largest surface areas and longest retention times. Ponds affected water quality and macroinvertebrate communities downstream. Exceedences of temperature and DO criteria occurred more frequently and were more severe downstream than upstream of ponds. Ponds in rural catchments increased mean daily stream temperatures 3.1–6.6°C during the critical summer period, and temperature differences were three times higher than those in bush catchments (0.8–2.0°C). Elevated temperatures were observed for hundreds of metres downstream owing to the slow rate of cooling (1°C/ 100 m), expanding the extent of adverse effects well beyond the “footprint” of the pond. Macroinvertebrate community composition (sample area 1–3 m²) and values of four commonly used metrics appeared to be significantly affected by ponds in rural and native forest catchments. These finding have important management implications that should lead to modifications (e.g., breaching dams) of the estimated 4500 existing ponds in the Auckland region, where possible, and restrictions on proposals for new “on‐line” ponds.     

Riparian protection and on‐farm best management practices for restoration of a lowland stream in an intensive dairy farming catchment: A case study

Abstract

Poor water quality (high concentrations of nitrogen (N), phosphorus (P), suspended solids (SS), and faecal bacteria) in Waiokura Stream, southern Taranaki, New Zealand, is attributed to diffuse and point source (PS) inputs from dairy farming. Trend analysis of concentration time‐series data (2001–2008) and annual yields (i.e., stream load divided by catchment area) showed that significant improvements occurring since 2001 may be attributed to changes in farming practices and riparian management. Yields of filterable reactive P, total P and SS declined by 25–40% as a result of increased riparian protection, a reduction in dairy shed effluent (DSE) pond discharges from 8 to 6 with conversion to land irrigation, and a 25% reduction in the average application rate of P fertiliser. Median annual Escherichia coli concentrations declined at a rate of 116 per 100 ml per year, as a result of fewer PS discharges and improved riparian management. Thus, improvements in stream water quality were attributed to adoption of on‐farm best management practices, fewer DSE discharges and riparian management involving permanent livestock exclusion from stream banks and riparian planting to mitigate runoff from pasture. During 2001–06, N fertiliser use increased by 30% and, with a 130% increase in supplementary cattle feed during 2003–08, led to an increase in average milk solids production 1021 to 1262 kg ha^?1 during 2001–06 with the increased production likely associated with increased N leaching losses. Total N and nitrate‐N concentrations and yields increased during 2001–07 as a result of the intensification in land use and increased N cycling. Stream invertebrate surveys using the macroinvertebrate community index (MCI) metric showed little improvement in MCI during 2002–07, probably because of the relatively short timeframe of this study and because water temperatures were not a limiting factor for invertebrate communities. The absence of native forest streams in the proximity of Waiokura Stream that might act as sources of sensitive species to recolonise the restored stream should also be considered as a constraint to improvements in biological community structure.     

Imaging of the Antarctic ionosphere: Experimental results

Ground-based dual-frequency GPS observations can be used to create images of electron density. This is well established for the Arctic ionosphere; here one of the first results is presented for the Antarctic. In this study, the GPS receivers in the Antarctic are supplemented with another GPS receiver onboard CHAMP. The aim of the study is to demonstrate the technique for investigating geophysical events, for example, an ionospheric disturbance period on 11 February 2004. The images have been validated by in-situ measurements from DMSP and CHAMP satellites, as well as Super Dual Auroral Radar Network (SuperDARN) convection patterns, which are able to confirm the location, presence, and transportation of large-scale plasma patches. This study indicates that although the convection still dominates in the high-latitude ionosphere, soft precipitation within the polar cap may play a role in the evolution of the polar patches. It also illustrates the potential for future multi-instrument studies of the Antarctic.     

Improving stability of regional numerical ocean models

An operational limited-area ocean modelling system was developed to supply forecasts of ocean state out to 3 days. This system is designed to allow non-specialist users to locate the model domain anywhere within the Australasian region with minimum user input. The model is required to produce a stable simulation every time it is invoked. This paper outlines the methodology used to ensure the model remains stable over the wide range of circumstances it might encounter. Central to the model configuration is an alternative approach to implementing open boundary conditions in a one-way nesting environment. Approximately 170 simulations were performed on limited areas in the Australasian region to assess the model stability; of these, 130 ran successfully with a static model parameterisation allowing a statistical estimate of the model’s approach toward instability to be determined. Based on this, when the model was deemed to be approaching instability a strategy of adaptive intervention in the form of constraint on velocity and elevation was invoked to maintain stability.