Late Pleistocene vertebrate-bearing deposits at San Teodoro Cave (North-Eastern Sicily): Preliminary data on faunal diversification and chronology

This paper deals with the chronology and the possible correlations among levels of different excavated areas in the Pleistocene vertebrate-bearing deposits at the large San Teodoro Cave (North-Eastern Sicily). Two trenches have been excavated along the eastern side of the cave, located at a distance from the entrance, respectively, of 8 m (α trench) and 28 m (β trench) and at different depths. Lithological features, biometrical data from small mammals and ecological data from molluscs point to similar environmental conditions for the α trench deposits and those located along the eastern wall of the cave in the eastern part of the β trench. The same evidence, and the taphonomic features of large mammals, points to different environmental conditions and perhaps to different ages for the deposits located in the western part of the β trench. The survival of elephants in Sicily up to 32,000 years ago is a new significant result of the ²³⁰Th/²³⁴U dating carried out from a concretionary stratum from the β trench and represents the youngest elephant survival in the western Mediterranean islands.     

Room-temperature equation of state of Li<Subscript>2</Subscript>VOSiO<Subscript>4</Subscript> up to 8.5 GPa

High-pressure single-crystal X-ray diffraction measurements of lattice parameters of the compound Li₂VOSiO₄, which crystallises with a natisite-type structure, has been carried out to a pressure of 8.54(5) GPa at room temperature. Unit-cell volume data were fitted with a second-order Birch-Murnaghan EoS (BM-EoS), simultaneously refining V ₀ and K ₀ using the data weighted by the uncertainties in V. The bulk modulus is K ₀ = 99(1) GPa, with K′ fixed to 4. Refinements of third order equations-of-state yielded values of K′ that did not differ significantly from 4. The compressibility of the unit-cell is strongly anisotropic with the c axis (K ₀(c) = 49.7 ± 0.5 GPa) approximately four times more compressible than the a axis (K ₀(a) = 195 ± 3 GPa).     

Accurate ionospheric delay model for real-time GPS-based positioning of LEO satellites using horizontal VTEC gradient estimation

Ionospheric delays compensation is a mandatory step for precise absolute and relative positioning of Low Earth Orbit Satellites (LEO) by GPS measurements. The most frequently used ionosphere model for real-time GPS-based navigation in LEO is an isotropic model proposed by Lear, which uses the Vertical Total Electron Content (VTEC) above the receiver and a mapping function for TEC evaluation along a given ray path. Based on significant assessed results available for ground-based GPS receivers, we propose the use of a different model relying on the thin shell assumption and a bilinear horizontal variation of the VTEC as a function of latitude and longitude in the shell. It is expected that this model is capable of better describing horizontal gradients in the ionosphere, thus improving ionospheric delay estimation, especially in intense ionospheric conditions. This model is referred to as Linear Thin Shell (LTS). LTS performance in estimating undifferenced and double-differenced ionospheric delays is checked by comparing measured and predicted delays computed using flight data from the GRACE mission. Results show that the LTS always outperforms the isotropic model, especially in case of high solar activity. Moreover, the LTS model provides a higher performance uniformity over a wide range of ionospheric delays, thus ensuring good performance in different conditions. The results obtained demonstrate that the LTS model improves the ionosphere delays estimation accuracy by 20 and 40% for undifferenced and double-differenced delays, respectively. This suggests the LTS model can effectively contribute to improving precision in LEO positioning applications.     

On the Transits of Solar System Objects in the Forthcoming Planck Mission: Data Flagging and Coeval Multi-Frequency Observations

In the context of current and future microwave surveys mainly dedicated to the accurate mapping of Cosmic Microwave Background (CMB), mm and sub-mm emissions from Solar System will represent a potential source of contamination as well as an opportunity for new Solar System studies. In particular, the forthcoming ESA Planck mission will be able to observe the point-like thermal emission from planets and some large asteroids as well as the diffused Zodiacal Light Emission (ZLE). After a brief introduction to the field, we focus on the identification of Solar System discrete objects in the Planck time ordered data.     

Spatial and diurnal distribution of invertebrate and fish fauna of a Zostera marina bed and nearby unvegetated sediments in Damariscotta River, Maine (USA)

Fish, epibenthos and macroinfauna were collected in a Zostera marina bed and nearby unvegetated sediments in the estuary of the Damariscotta River, on the mid-coast of Maine. Samples of epibenthic fauna and fish were collected at low tides both during day and night, and samples of infauna at low tides during the day. The mean density of Zostera shoots in the study area was 335 m⁻². Abundance and species number of fish were greater at night than during the day and greater in eelgrass beds (Z. marina) than in unvegetated habitats. Daytime fish collections were dominated by Atlantic silversides (Medinia medinia), while juvenile winter flounder (Pseudopleuronectes americanus) dominated night collections. Also Zostera-associated epifaunal abundances and number of species were significantly higher at night than during the day. Mysis stenolepis, Idotea balthica and Littorina obtusata were dominant species in the epifauna samples. Of the total of 37 invertebrate species encountered, only five occurred both in the infaunal and epifaunal samples. Nineteen different taxa were collected from the benthic core samples. The most abundant invertebrate infaunal taxa were sipunculids, the polychaete Nereis virens, and oligochaetes. Infaunal invertebrate abundances and species diversity were significantly higher in eelgrass beds than in unvegetated sediments. The abundance and number of species of benthic invertebrates were also positively correlated to seagrass biomass. Community diversity values (H′) were relatively low but fit well in the general pattern of decreasing diversity towards northern latitudes.     

Weathering of the New Albany Shale, Kentucky: II. Redistribution of minor and trace elements

During weathering, elements enriched in black shale are dispersed in the environment by aqueous and mechanical transport. Here a unique evaluation of the differential release, transport, and fate of Fe and 15 trace elements during progressive weathering of the Devonian New Albany Shale in Kentucky is presented. Results of chemical analyses along a weathering profile (unweathered through progressively weathered shale to soil) describe the chemically distinct pathways of the trace elements and the rate that elements are transferred into the broader, local environment. Trace elements enriched in the unweathered shale are in massive or framboidal pyrite, minor sphalerite, CuS and NiS phases, organic matter and clay minerals. These phases are subject to varying degrees and rates of alteration along the profile. Cadmium, Co, Mn, Ni, and Zn are removed from weathered shale during sulfide-mineral oxidation and transported primarily in aqueous solution. The aqueous fluxes for these trace elements range from 0.1 g/ha/a (Cd) to 44 g/ha/a (Mn). When hydrologic and climatic conditions are favorable, solutions seep to surface exposures, evaporate, and form Fe-sulfate efflorescent salts rich in these elements. Elements that remain dissolved in the low pH (<4) streams and groundwater draining New Albany Shale watersheds become fixed by reactions that increase pH. Neutralization of the weathering solution in local streams results in elements being adsorbed and precipitated onto sediment surfaces, resulting in trace element anomalies.Other elements are strongly adsorbed or structurally bound to solid phases during weathering. Copper and U initially are concentrated in weathering solutions, but become fixed to modern plant litter in soil formed on New Albany Shale. Molybdenum, Pb, Sb, and Se are released from sulfide minerals and organic matter by oxidation and accumulate in Fe-oxyhydroxide clay coatings that concentrate in surface soil during illuviation. Chromium, Ti, and V are strongly correlated with clay abundance and considered to be in the structure of illitic clay. Illite undergoes minimal alteration during weathering and is concentrated during illuvial processes. Arsenic concentration increases across the weathering profile and is associated with the succession of secondary Fe(III) minerals that form with progressive weathering. Detrital fluxes of particle-bound trace elements range from 0.1 g/ha/a (Sb) to 8 g/ha/a (Mo). Although many of the elements are concentrated in the stream sediments, changes in pH and redox conditions along the sediment transport path could facilitate their release for aqueous transport.