Benthic Carbon Mineralization and Nutrient Turnover in a Scottish Sea Loch: An Integrative In Situ Study

Based on in situ microprofiles, chamber incubations and eddy covariance measurements, we investigated the benthic carbon mineralization and nutrient regeneration in a ~65-m-deep sedimentation basin of Loch Etive, UK. The sediment hosted a considerable amount of infauna that was dominated by the brittle star A. filiformis. The numerous burrows were intensively irrigated enhancing the benthic in situ O₂ uptake by ~50 %, and inducing highly variable redox conditions and O₂ distribution in the surface sediment as also documented by complementary laboratory-based planar optode measurements. The average benthic O₂ exchange as derived by chamber incubations and the eddy covariance approach were similar (14.9 ± 2.5 and 13.1 ± 9.0 mmol m^?2 day^?1) providing confidence in the two measuring approaches. Moreover, the non-invasive eddy approach revealed a flow-dependent benthic O₂ flux that was partly ascribed to enhanced ventilation of infauna burrows during periods of elevated flow rates. The ratio in exchange rates of ΣCO₂ and O₂ was close to unity, confirming that the O₂ uptake was a good proxy for the benthic carbon mineralization in this setting. The infauna activity resulted in highly dynamic redox conditions that presumably facilitated an efficient degradation of both terrestrial and marine-derived organic material. The complex O₂ dynamics of the burrow environment also concurrently stimulated nitrification and coupled denitrification rates making the sediment an efficient sink for bioavailable nitrogen. Furthermore, bioturbation mediated a high efflux of dissolved phosphorus and silicate. The study documents a high spatial and temporal variation in benthic solute exchange with important implications for benthic turnover of organic carbon and nutrients. However, more long-term in situ investigations with like approaches are required to fully understand how environmental events and spatio-temporal variations interrelate to the overall biogeochemical functioning of coastal sediments.     

Conditions of Quaternary magmatism at Spitsbergen Island

Petrological and geochemical data obtained on the Quaternary lavas of volcanoes at Spitsbergen Island indicate that the rocks were produced via the deep-seated crystallization of parental alkaline magmas at 8–10 kbar. The character of clinopyroxene enrichment in incompatible elements indicates that the mineral crystallized from more enriched melts than those inferred from the composition of the host lavas. These melts were close to the parental melts previously found as veinlets in mantle hyperbasite xenoliths in the lavas. According to the character of their enrichment in Pb and Sr radiogenic isotopes and depletion in Nd, the basalts from Spitsbergen Island define a single trend with the weakly enriched tholeiites of the Knipovich Ridge, a fact suggesting the closeness of the enriched sources beneath the continental margin of Spitsbergen and beneath the spreading zone. Magmatic activity at Spitsbergen was related to the evolution of the Norwegian-Greenland basin, which evolved in pulses according to the shift of the spreading axes. The most significant of the latter events took place in the Neogene, when the Knipovich Ridge obtained its modern position near the western boundary of Spitsbergen. Early in the course of the evolution, the emplacement of alkaline melts generated at Spitsbergen into the oceanic mantle could form the enriched mantle, which was later involved in the melting process beneath the spreading zone.     

Stable carbon-isotopic compositions of lipids isolated from the ammonia-oxidizing chemoautotroph Nitrosomonas europaea

For the ammonia-oxidizing bacterium Nitrosomonas europaea, grown autotrophically using semicontinuous culturing, average biomass was depleted in ¹³C relative to CO₂ dissolved in the medium by ca. 20‰ and the total-lipid extract was depleted in ¹³C relative to biomass by 3.7‰. The n-alkyl lipids (weighted average of fatty acids) and isoprenoid lipids (weighted average of hopanoids) were both depleted in ¹³C relative to biomass by about 9‰. The large depletion in the isoprenoid lipids seems to indicate that isotopic fractionations associated with the biosynthesis of methylerythritol phosphate (MEP) affected at least two carbon positions in each isoprene unit. Among the fatty acids, trans-9-hexadecenoic acid was most depleted (13.0‰ relative to biomass), followed by cis-9- hexadecenoic acid (9.6‰) and hexadecanoic acid (6.9‰). Isotopic relationships between the three acids suggest that significant isotope effects were associated with the desaturation and cis to trans isomerization of fatty acids. Given these observations, hopanoids produced by ammonia-oxidizing bacteria growing in natural waters are likely to be depleted in ¹³C by 26–30‰ relative to dissolved CO₂. Since CO₂ at aquatic oxyclines is often depleted in ¹³C, the range of δ values expected for hopanoids is ca. −34‰ to −55‰. The δ values of geohopanoids observed in numerous studies and attributed to unspecified chemoautotrophs fall within this range.     

Lithofacies succession of maar crater deposits in the Eifel area (Germany)

ABSTRACT Maar craters often contain exceptionally preserved fossils and maar sediments may reflect detailed environmental changes. Volcanosedimentary processes in a Middle Eocene maar crater lake are illustrated by the deposits of Eckfeld Maar in the Tertiary Hocheifel Volcanic Field (Rhenish Massif, Germany). The maar origin of the basin is evident from a circular negative gravity anomaly which indicates a low-density funnel-shaped basin filling. From the facies analysis of an Eocene (Eckfeld) and a Pleistocene (Döttingen) maar we develop a lithozone classification for the interpretation of maar sediments: syn-/post-eruptive breccias are followed by a fining-upwards sequence of lacustrine mud with coarse layers and final swamp deposits. From the facies analysis and regional geological data we reconstruct the pre- to post-eruptive history of a maar crater prior to post-Eocene uplift. These observations can be used for the interpretation of Tertiary and Quaternary maar craters that are ideal fossil and sediment traps.     

Petrology of the tin-bearing granite-leucogranites of the Piaoak Massif, Northern Vietnam

The Piaoak tin-bearing granite-leucogranites located in the Caobang Province of Northern Vietnam compose a stock-like hypabyssal body. Host rocks are represented by Early Devonian carbonate sequences and Early Triassic ??black?? shales. The geochronological age of the Piaoak granite-leucogranites corresponds to the Late Cretaceous: T = 83.5 ± 6.2 Ma, ⁸⁷Rb/⁸⁶Sr method; T = 89.7 ± 1.0 Ma, ³⁹Ar/⁴⁰Ar method. The massif has a simple basic to acid order: two-mica and muscovite granite-leucogranite ?? raremetal aplites, pegmatites ?? tin-bearing greisens and hydrothermal veins. The petrographic and microstructural studies revealed a sharp change in crystallization conditions of the granite-leucogranite magma at the late magmatic stage and formation of muscovite via incongruent melting of protolithionite. The study of melt and coexisting fluid inclusions showed that solidus crystallization occurred under fluid-saturated conditions at 635?C600°C. In composition, the granite-leucogranites of the Piaoak Massif correspond to the raremetal-plumasite geochemical type (according to L.V. Tauson), and reach Li-F facies in terms of their rare-element composition. The composition of aplites and pegmatites demonstrates that granite-leucogranite magma did not accumulate lithophile and volatile components in the residual melt during differentiation, but was initially enriched in rare-metals. It is most probable that the melt was generated from Proterozoic lithotectonic complexes and overlaying Lower Triassic ??black?? shales.     

Metal content and environmental risk assessment around high-altitude mine sites

Gold mining activities in Apolobamba area, northwest of La Paz, Bolivia have created serious environmental concern and great risk to human health. The current methods used to extract gold are too primitive resulting in metal contamination of soil and water. The objectives of this study were to: (1) determine the degree of metal pollution, and (2) assess the risk to human health and environment in the Apolobamba area. Soil, water, sediment samples, and mine spills were collected and analyzed. Metals including Pb, Cu, Zn, Cd, and Hg concentrations were higher in surface soils than in subsurface soils indicating active atmospheric deposition of metals. Sediment samples had elevated levels of metals probably from mine spills discharged into the Sunchulli River. Surface soils in the Sunchulli community show the highest levels of Pb and Hg in all soil samples and may pose a risk to the health of the human population and environment.     

The fast variable maser source IRAS 05338-0624

A new OH maser was detected in January 2008 toward the infrared source IRAS 05338-0624 in the dark cloud L1641N. The observations were carried out on the Nan cay Radio Telescope (France) in the 1667 and 1665 MHz OH lines. In the spectra of both lines, thermal OH emission from the surrounding molecular cloud is present at radial velocities V _LSR = 6–9 km/s. In addition, a narrow maser feature is present in both lines at V _LSR = 2 km/s in the profiles obtained on January 7, 2008; the peak flux densities at 1667 and 1665 MHz are 1.5 and 0.4 Jy, respectively. No OH maser emission was detected in February–July 2008. Then, a maser feature was again observed in the 1665 MHz line on August 20, 2008, at the same velocity as in January, V _LSR = 2 km/s, with a peak flux density of 0.4 Jy. No 1667 MHz counterpart was observed with an upper limit of ～0.1 Jy. Emission in both OH lines was again absent on September 18. The source was also observed in the H₂O line at λ = 1.35 cm on the 22-m radio telescope of the Pushchino Radio Astronomy Observatory (Russia) on February 7 and 13, 2008. In both cases, a maser feature was detected at V _LSR = 9 km/s, with peak flux densities of 35 and 15 Jy, respectively. After the its apparent absence in April, H₂O maser emission reappeared on May 14, 2008, at V _LSR = 7 km/s with a flux density of about 15 Jy. The history of previous observations of the object in the OH and H₂O lines is traced. The maser displays strong and rapid flux variability in the lines of both molecules, as is typical of young low-luminosity stellar objects at early stages of their evolution.     

STAMP: spatial–temporal analysis of moving polygons

Research questions regarding temporal change in spatial patterns are increasingly common in geographical analysis. In this research, we explore and extend an approach to the spatial–temporal analysis of polygons that are spatially distinct and experience discrete changes though time. We present five new movement events for describing spatial processes: displacement, convergence, divergence, fragmentation and concentration. Spatial–temporal measures of events for size and direction are presented for two time periods, and multiple time periods. Size change metrics are based on area overlaps and a modified cone-based model is used for calculating polygon directional relationships. Quantitative directional measures are used to develop application specific metrics, such as an estimation of the concentration parameter for a von Mises distribution, and the directional rate of spread. The utility of the STAMP methods are demonstrated by a case study on the spread of a wildfire in northwestern Montana.      

On the multi-century Southern Hemisphere response to changes in atmospheric CO2-concentration in a Global Climate Model

Summary The transient response of the Southern Hemisphere to climate change is examined using an intermediate complexity climate model. Unlike previous studies, the Southern Ocean response on the centennial to multi-centennial time-scale is assessed in some detail. It is shown that changes in atmospheric CO₂-concentrations lead to an increase in the strength of the Antarctic Circumpolar Current (ACC) by ∼20 Sv by 2750 for an atmospheric CO₂-concentration of 750 ppm. This increase is predominantly the result of an enhanced steric height gradient. The increase in the strength of the ACC induces changes in its steering around topographic features. This change in ACC pathway causes increased surface flow of colder waters into some regions (reducing the rate of warming) and increased surface flow of warmer waters into others (increasing the rate of warming). This meridional shifting of the ACC causes changes in atmospheric temperature in the Southern Hemisphere to be nonuniform. It is also shown that the strength and location of the Antarctic Bottom Water (AABW) overturning cell is affected by increased atmospheric CO₂. For a CO₂-concentration scenario increasing gradually to 750 ppm, AABW production initially decreases, then recovers and eventually increases. New production zones form, which extend AABW production all the way from the Weddell Sea eastward into the Ross Sea. These new production zones are the result of increased areas of atmosphere-ocean interactions, due to decreased sea-ice coverage, although the overturned waters are now warmer and fresher due to climate change. A new production zone of Antarctic Intermediate water is also established in the Southeast Pacific Ocean, poleward of its present-day location.