Variations in dissolved CO2 and CH4 in a first‐order stream and catchment: an investigation of soil–stream linkages

Spatial and seasonal variations in CO₂ and CH₄ concentrations in streamwater and adjacent soils were studied at three sites on Brocky Burn, a headwater stream draining a peatland catchment in upland Britain. Concentrations of both gases in the soil atmosphere were significantly higher in peat and riparian soils than in mineral soils. Peat and riparian soil CO₂ concentrations varied seasonally, showing a positive correlation with air and soil temperature. Streamwater CO₂ concentrations at the upper sampling site, which mostly drained deep peats, varied from 2·8 to 9·8 mg l^?1 (2·5 to 11·9 times atmospheric saturation) and decreased markedly downstream. Temperature‐related seasonal variations in peat and riparian soil CO₂ were reflected in the stream at the upper site, where 77% of biweekly variation was explained by an autoregressive model based on: (i) a negative log‐linear relationship with stream flow; (ii) a positive linear relationship with soil CO₂ concentrations in the shallow riparian wells; and (iii) a negative linear relationship with soil CO₂ concentrations in the shallow peat wells, with a significant 2‐week lag term. These relationships changed markedly downstream, with an apparent decrease in the soil–stream linkage and a switch to a positive relationship between stream flow and stream CO₂. Streamwater CH₄ concentrations also declined sharply downstream, but were much lower (<0·01 to 0·12 mg l^?1) than those of CO₂ and showed no seasonal variation, nor any relationship with soil atmospheric CH₄ concentrations. However, stream CH₄ was significantly correlated with stream flow at the upper site, which explained 57% of biweekly variations in dissolved concentrations. We conclude that stream CO₂ can be a useful integrative measure of whole catchment respiration, but only at sites where the soil–stream linkage is strong. Copyright © 2004 John Wiley & Sons, Ltd.     

Hydrogeologic controls on summer stream temperatures in the McKenzie River basin,Oregon

Stream temperature is a complex function of energy inputs including solar radiation and latent and sensible heat transfer. In streams where groundwater inputs are significant, energy input through advection can also be an important control on stream temperature. For an individual stream reach, models of stream temperature can take advantage of direct measurement or estimation of these energy inputs for a given river channel environment. Understanding spatial patterns of stream temperature at a landscape scale requires predicting how this environment varies through space, and under different atmospheric conditions. At the landscape scale, air temperature is often used as a surrogate for the dominant controls on stream temperature. In this study we show that, in regions where groundwater inputs are key controls and the degree of groundwater input varies in space, air temperature alone is unlikely to explain within-landscape stream temperature patterns. We illustrate how a geologic template can offer insight into landscape-scale patterns of stream temperature and its predictability from air temperature relationships. We focus on variation in stream temperature within headwater streams within the McKenzie River basin in western Oregon. In this region, as in other areas of the Pacific Northwest, fish sensitivity to summer stream temperatures continues to be a pressing environmental issue. We show that, within the McKenzie, streams which are sourced from deeper groundwater reservoirs versus shallow subsurface flow systems have distinct summer temperature regimes. Groundwater streams are colder, less variable and less sensitive to air temperature variation. We use these results from the western Oregon Cascade hydroclimatic regime to illustrate a conceptual framework for developing regional-scale indicators of stream temperature variation that considers the underlying geologic controls on spatial variation, and the relative roles played by energy and water inputs. Copyright © 2007 John Wiley & Sons, Ltd.     

Are all maps mental maps?

The article focuses on the way in which map content reflects the cartographer's World view and system of values. Different World views are illustrated historically. Examples of topographical, land-use and vegetation maps from different parts of the World indicate the prevalence of Eurocentric perceptions in cartography. Different geological maps of Norden show how the visual image depends on the classification system adopted. All maps are mental maps in that their content is culturally determined and ethnocentric in origin.     

Spectral reflectance of highland rock types at Apollo 17: Evidence from Boulder 1, Station 2

Many of the non-mare rock types at Apollo 17 can be identified uniquely by their spectral reflectance properties. Mineralogical and textural information is present in the spectral curves of samples from Boulder 1, Station 2. It should be possible to determine the regional extent of rocks similar to the boulder using reflectance spectra from a spacecraft in lunar orbit.     

Inadequacies of the straits' passage regime in the LOS draft

Appraisers of recent sessions of the Law of the Sea Conference have directed their attention, sometimes at the expense of other critical issues, to the emerging regime to govern seabed mining. For one reason or another, a general Western consensus has emerged that the draft treaty's textual arrangements for traditional and innovative maritime and aerial passage are satisfactory. That complacent consensus may rest on perilously unrealistic assumptions.     

A simple contact–friction interface element with applications to buried culverts

A simple friction–contact interface element is introduced which simulates frictional slippage, separation, and re-bonding of two bodies initially mating at a common interface and subsequently deforming with an arbitrary static loading schedule. Constraint equations between initially mating node pairs and the general principle of virtual work are used to formulate the interface element for a finite element solution procedure. Some advantages of the interface element include; easy implementation intostandard finite element programs, direct determination of interface forces without round-off problems, and the generality afforded by the virtual work formulation to include other non-conservative models in the system. The application of the interface element to an idealized buried culvert problem illustrates that the model behaves properly. A second application, for a long-span culvert installation with incremental soil loading, demonstrates the importance of modelling slippage at the culvert–soil interface in order to conform with experimental observations.     

An evaluation of the use of halogen and water abundances in efforts to distinguish mineralized and barren intrusive rocks

Analysis of the chlorine, fluorine and water content of approximately 200 samples from a total of fourteen mineralized and ten barren intrusive rocks from the Caribbean and Central America indicates that abundances of these constituents fail to distinguish mineralized rocks from barren rocks. Variations in background abundances arise from the increase in halogen content of potassium-rich rocks and from the depletion of halogens in altered and porphyritic rocks. A particularly well developed potassium-fluorine covariance is observed in tin-bearing granites, but such a covariance cannot be used to distinguish intrusive rocks associated with porphyry copper mineralization.