Structural variations in derivatives of the bacteriochlorophylls of Chlorobiaceae: impact of stratigraphic resolution on depth profiles as revealed by methanolysis

Bacteriochlorophylls c and d, recovered from two sedimentary sequences, were converted to bacteriophaeophorbide methyl esters by methanolysis and analysed by atmospheric pressure chemical ionisation liquid chromatography-multistage mass spectrometry (APCI LC-MSⁿ). The distributions in both settings, a moderately consolidated sediment from Kirisjes Pond, Antarctica, and in a finely laminated microbial mat from Les Salines de la Trinitat, Spain, show significant variations within a narrow depth interval. The overall bacteriophaeophorbide c to d ratios in the two sediments are different, as are the ratios of particular C-3¹ diastereoisomers, indicating distinct differences between the bacterial communities that contributed to each sediment. Furthermore, a shift towards more extensive alkylation in homologues within each sediment is consistent either with changing environmental conditions in the depositional environments, or development-related changes in the structure of the bacterial community, leading to increased competition for light or nutrients.     

The Eltanin asteroid impact: possible South Pacific palaeomegatsunami footprint and potential implications for the Pliocene–Pleistocene transition

Large asteroid impacts are rare, and those into the deep ocean are rarer still. The Eltanin asteroid impact around 2.51 ± 0.07 Ma occurred at a time of great climatic and geological change associated with the Pliocene–Pleistocene boundary. Numerical models of the event indicate that a megatsunami was generated, although there is debate concerning its magnitude and the region‐wide extent of its influence. We summarise the existing evidence for possible Eltanin megatsunami deposits in Antarctica, Chile and New Zealand, while also examining other potential sites from several locations, mainly around the South Pacific region. In reviewing these data we note that these events were unfolding at the same time as those associated with the Pliocene–Pleistocene boundary and, as such, most of the geological evidence from that time has a climatic interpretation. The potential climatic and geological ramifications of the Eltanin asteroid impact, however, have failed to be considered by most researchers studying this time period. Although we are not advocating that all geological activity at that time is connected with the Eltanin asteroid impact, it raises interesting questions about the role potentially played by such catastrophic events in contributing to or even triggering epochal transitions. Copyright © 2012 John Wiley & Sons, Ltd.     

Geometrical focusing as a mechanism for significant amplification of ground motion in sedimentary basins: analytical and numerical study

We study the geometrical and material conditions which lead to focusing of seismic waves traveling across a concave velocity interface representing the boundary of a sedimentary basin within a denser rock. We approximate, using geometrical analysis for plane-waves, the combination of interface eccentricities and velocity ratios for which the seismic rays converge to a near surface region of the basin. 2-D finite difference modeling is used to compute Peak Ground Velocity (PGV) and spectral amplification across the basin. We show that effective geometrical focusing occurs for a narrow set of eccentricities and velocity ratios, where seismic energy is converged to a region of $\pm $ 0.5 km from surface. This mechanism leads to significant amplification of PGV at the center of the basin, up to a factor of 3; frequencies of the modeled spectrum are amplified up to the corner frequency of the source. Finally, we suggest a practical method for evaluating the potential for effective geometrical focusing in sedimentary basins.     

Characteristics of secondary circulations over an inhomogeneous surface simulated with large-eddy simulation

Large-eddy simulation is used to study secondary circulations in the convective boundary layer modulated as a result of horizontally varying surface properties and surface heat fluxes over flat terrain. The presence of heat flux heterogeneity and its alignment with respect to geostrophic wind influences the formation, strength and orientation of organized thermals. Results show boundary-attached roll formation along heat flux maxima in the streamwise direction. The streamwise organization of the updrafts and downdrafts formed downwind of heterogeneities leads to counter-rotating secondary circulations in the crosswind plane. The distribution of resolved-scale pressure deviations shows large pressure gradients in the crosswind plane. Spanwise and vertical velocity variances and heat flux profiles depict considerable spatial variability compared to a homogeneous forest simulation. Secondary circulations are observed for various ambient wind scenarios parallel and perpendicular to heterogeneities. In the presence of increased wind speed, thermals emerging from the heat flux heterogeneity are elongated, and organize along and downwind of large-scale heterogeneity in the streamwise direction. Simulation with a reduced heat flux shows a shallower circulation with a lower aspect ratio. Point measurements of heat flux inside the roll circulation could be overestimated by up to 15–25% compared to a homogeneous case.     

Identification of buried sinkholes using refraction tomography at Ft. Campbell Army Airfield,Kentucky

Karst aquifers are highly susceptible to contamination, with numerous points of entry for contaminants through recharge features such as sinkholes, swallow holes and solutionally enlarged fractures. These recharge features may be filled or obscured at the surface, requiring the use of geophysical or remote sensing techniques for their identification. This study uses seismic refraction data collected at the Ft. Campbell Army Airfield (CAAF), Kentucky, USA, to test the hypothesis that refraction tomography is a useful tool for imaging bedrock depressions beneath thick overburden (greater than 20 m of unconsolidated sediment). Southeast of the main taxiway of CAAF seismic velocity tomograms imaged a bedrock low, possibly a closed depression, at a depth of 25 m that had been earlier identified through delay-time analysis of the same refraction data. Tomography suggests the bedrock low is about 250-m wide by 10-m deep at its widest point. High rates of contaminant vapor extraction over the western extension of this feature suggest a high concentration of contaminants above, and within, this filled bedrock low, the base of which may contain solutionally enlarged fractures (i.e. karst conduits) that could funnel these contaminants to the upper or lower bedrock aquifers. This study thus demonstrates the viability of seismic refraction tomography as a tool for identification of filled sinkholes and bedrock depressions in karst areas.     

Data selection using support vector regression

Geophysical data sets are growing at an ever-increasing rate, requiring computationally efficient data selection(thinning)methods to preserve essential information. Satellites, such as Wind Sat, provide large data sets for assessing the accuracy and computational efficiency of data selection techniques. A new data thinning technique, based on support vector regression(SVR), is developed and tested. To manage large on-line satellite data streams, observations from Wind Sat are formed into subsets by Voronoi tessellation and then each is thinned by SVR(TSVR). Three experiments are performed. The first confirms the viability of TSVR for a relatively small sample, comparing it to several commonly used data thinning methods(random selection, averaging and Barnes filtering), producing a 10% thinning rate(90% data reduction), low mean absolute errors(MAE) and large correlations with the original data. A second experiment, using a larger dataset, shows TSVR retrievals with MAE < 1 m s-1and correlations 0.98. TSVR was an order of magnitude faster than the commonly used thinning methods. A third experiment applies a two-stage pipeline to TSVR, to accommodate online data. The pipeline subsets reconstruct the wind field with the same accuracy as the second experiment, is an order of magnitude faster than the nonpipeline TSVR. Therefore, pipeline TSVR is two orders of magnitude faster than commonly used thinning methods that ingest the entire data set. This study demonstrates that TSVR pipeline thinning is an accurate and computationally efficient alternative to commonly used data selection techniques.     

Holocene climate and cultural evolution in late prehistoric-early historic West Asia

The precipitation climatology and the underlying climate mechanisms of the eastern Mediterranean, West Asia, and the Indian subcontinent are reviewed, with emphasis on upper and middle tropospheric flow in the subtropics and its steering of precipitation. Holocene climate change of the region is summarized from proxy records. The Indian monsoon weakened during the Holocene over its northernmost region, the Ganges and Indus catchments and the western Arabian Sea. Southern regions, the Indian Peninsula, do not show a reduction, but an increase of summer monsoon rain across the Holocene. The long-term trend towards drier conditions in the eastern Mediterranean can be linked to a regionally complex monsoon evolution. Abrupt climate change events, such as the widespread droughts around 8200, 5200 and 4200 cal yr BP, are suggested to be the result of altered subtropical upper-level flow over the eastern Mediterranean and Asia.The abrupt climate change events of the Holocene radically altered precipitation, fundamental for cereal agriculture, across the expanse of late prehistoric-early historic cultures known from the archaeological record in these regions. Social adaptations to reduced agro-production, in both dry-farming and irrigation agriculture regions, are visible in the archaeological record during each abrupt climate change event in West Asia. Chronological refinement, in both the paleoclimate and archaeological records, and transfer functions for both precipitation and agro-production are needed to understand precisely the evident causal linkages.     

Reconstruction of paleocoastlines for the northwestern South China Sea since the Last Glacial Maximum

The range of relative sea level rise in the northwestern South China Sea since the Last Glacial Maximum was over 100 m. As a result, lowland regions including the Northeast Vietnam coast, Beibu Gulf, and South China coast experienced an evolution from land to sea. Based on the principle of reconstructing paleogeography and using recent digital elevation model, relative sea level curves, and sediment accumulation data, this paper presents a series of paleogeographic scenarios back to 20 cal. ka BP for the northwestern South China Sea. The scenarios demonstrate the entire process of coastline changes for the area of interest. During the late glacial period from 20 to 15 cal. ka BP, coastline slowly retreated, causing a land loss of only 1×10⁴ km², and thus the land-sea distribution remained nearly unchanged. Later in 15–10 cal. ka BP coastline rapidly retreated and area of land loss was up to 24×10⁴km², causing lowlands around Northeast Vietnam and South China soon to be underwater. Coastline retreat continued quite rapidly during the early Holocene. From 10 to 6 cal. ka BP land area had decreased by 9×10⁴km², and during that process the Qiongzhou Strait completely opened up. Since the mid Holocene, main controls on coastline change are from vertical crustal movements and sedimentation. Transgression was surpassed by regression, resulting in a land accretion of about 10×10⁴km². Supported by Key Laboratory of Marginal Sea Geology, Chinese Academy of Sciences (Grant No. MSGL0711), the Guangdong Natural Science Foundation (Grant No. 04001309) and Open Fund of the Key Laboratory of Marine Geology and Environment, Chinese Academy of Sciences (Grant No. MGE2007KG04)