Interpretation of210Pb profiles and verification of the CRS dating model in PIRLA project lake sediment cores

This paper reports results and analysis of²¹⁰Pb-activity measurements in 51 lake-sediment cores from 32 lakes in the four PIRLA (Paleoecological Investigations of Recent Lake Acidification) project regions (Adirondack Mountains [New York], Northern New England, Northern Florida, and the Northern Great Lakes States). General application of the Constant Rate of Supply (Constant Flux) model for²¹⁰Pb dating is valid for lakes in the PIRLA study, although application of the model is equivocal in a few lakes.²¹⁰Pb inventories and profiles are replicable among closely spaced cores within a lake. Specific²¹⁰Pb activity in surface sediments is negatively correlated with bulk sediment accumulation rate in seepage lakes, but not in drainage lakes. Drainage lakes with lower pH have lower unsupported²¹⁰Pb inventories in sediments, but the relationship does not occur in seepage lakes.²¹⁰Pb profiles in only seven of the cores, all from either the Adirondacks or the northern Great Lakes states, exhibit exponential decay curves. Deviations from an exponential profile include a flattening of the profile in the top few cm or excursions of one or a few measurements away from an exponential curve.²¹⁰Pb dates typically agree with other chronostratigraphic markers, most of which are subject to greater uncertainty. Several hypotheses, including sediment mixing, hydrologic regime, sediment focusing, and acidification, are proposed to explain variation of²¹⁰Pb distribution among lakes and regions. Hydrologic factors exert control on unsupported²¹⁰Pb inventories in PIRLA lakes, and there is a strong focusing effect in drainage lakes but a weak focusing effect in seepage lakes.This is the third of a series of papers to be published by this journal following the 20^th anniversary of the first application of²¹⁰Pb dating of lake sediments. Dr P. G. Appleby is guest editing this series.     

Temporal Variations of Chlorinated Solvents in Abstraction Wells

Data obtained during an organic water quality survey of abstraction (pumping) wells in the Triassic Sandstone Aquifer of Birmingham (U.K.) indicate that there are important variations of chlorinated solvent concentrations with time. Short-term observation of solvent concentrations with elapsed pumping time indicates widely differing well responses; such observations are important in establishing good sampling protocols. Long-term monitoring indicates that solvent concentrations, particularly trichloroethene, are often stable with time. When large solvent variations do occur, these are shown to be due to the variation in the abstraction history of the well or significant migration of solvent plumes during the monitoring period. The latter effect is particularly exemplified by rising trends in 1,1,1-trichlroethane concentrations. The changes observed in solvent concentrations during long-term monitoring of the Birmingham Aquifer are slow to occur, but often large.     

Nickeliferous sulfides in xenoliths,olivine megacrysts and basaltic glass

The composition of olivine and nickeliferous sulfide inclusions from a selection of mafic and ultramafre rocks, xenoliths and megacrysts, including picritic basalts from Kilauea Volcano, Hawaii, kimberlite from Fayette County, Pennsylvania, and megacrysts from Mount Shasta, California are compared with the mean experimental value of the distribution coefficient for Ni/Fe exchange (K_D3=32). Only nine of the forty five olivipe/bulk-sulfide pairs investigated have compositions consistent with equilibration at high temperature, yielding calculated K_D3 values in the range 22 to 41. The remaining pairs have calculated K_D3 values which range from 0 to 19. Bulk-sulfides in disequilibrated assem-blages are consistently depleted in nickel and within both indivudual associations and individual petrographic sections they exhibit a wide variation in NiS content. The bulk copper contents of olivine-and groundmass-hosted sulfides from Kilauea Volcano range from 0.5 to 43 at%, and samples from the Kilauea Iki lava lake are more Fe-and Cu-rich and generally have lower K_D3 values than those from the eruption itself. As with magmatic Ni–Cu sulfide deposits, most nickeliferous sulfide inclusions in mantle-related rocks and xenoliths and in volcanic rocks do not have pristine early-magmatic bulk compositions, and it would seem to be premature to attribute these sulfides solely to either a mantle or an early-magnatic origin.     

Chemistry of alkali extraction of brown coals—I. Kinetics, characterisation and implications to coalification

Three Australian brown coals have been separated into humin and humic acid fractions and studied by high resolution solid state ¹³C NMR spectroscopy and Fourier transform IR spectroscopy. The aromatic rings of the humic acids are highly substituted showing that extensive cross linking must have occurred during formation from wood lignin and tannin. However, the humins contain more aliphatic carbon and hydrogen than the corresponding humic acids. This shows that little cross linking has occurred with other components of the brown coal such as resins, waxes cutin and algal detritus, and cross linking has not rendered the aromatics alkali insoluble. The kinetics of extraction are complex and not simple first order. This is reflected in the chemical composition of the humic acid which is extraction temperature dependent. We also observed that there is a conversion of aromatic carbon to aliphatic carbon and gas during extraction, probably by alkaline oxidation, resulting in ring opening. A range of suitable model compounds have been studied to confirm this finding. Such a mechanism may account for the modification of lignin in oxidising environments such as those occurring in the initial stages of coalification (lignite or brown coal formation) and in soils.     

Large-scale floodplain modelling

A two-dimensional horizontal finite element numerical model (RMA-2) was applied to a 24 km river channel-floodplain reach in West Germany. Initial results indicate that finite element schemes may successfully estimate inundation in large-scale floodplain applications. Potentially, the resulting detailed velocity vector distributions and identification of inundation zones throughout storm events could provide an insight into the present day sedimentary environment on the floodplain.     

Complete chemical analyses of metamorphic hornblendes: implications for normalizations,calculated H2O activities,and thermobarometry

Twenty-two hornblendes separated from amphibolites and granulites of the Grenville Orogen of Ontario have been quantitatively analyzed for major and minor elements by electron microprobe, for FeO/Fe₂O₃ by wet chemistry, and for H₂O by manometric measurement as H₂. Hornblende formulae were calculated on the basis of 24O+OH+Cl+F. Most samples are magnesio-hornblendes, ferroan pargasitic hornblendes and ferroan hastingsitic hornblendes, with weight fractions of Fe³⁺/(Fe²⁺+Fe³⁺) ranging from 0.15 to 0.50. An oxy-amphibole component of 0–25 mol%, with an average value of 17 mol%, is obtained for these complete analyses. When compared with structural formulae determined solely from microprobe data, normalization based on 13=Si+Ti+Al+Fe+Mn+Mg cations provides the best approximation to hornblende formulae calculated from the complete analyses. Less satisfactory agreement is obtained from a normalization scheme based on 15=Si+Ti+Al+Fe+Mn+Mg+Ca, while worst agreement is obtained from normalization to 23 oxygens assuming all Fe is Fe²⁺. No normalization scheme based on microprobe data alone consistently replicates the measured FeO, Fe₂O₃, and H₂O; accurate determination of these values requires complete chemical analysies. Ionic solution models previously have been proposed to evaluate the activity of Ca₂Mg₅Si₈ O₂₂(OH)₂(a _Trem) in hornblende for use in equilibria that constrain the activity of H₂O (a _{H 2}O) in igneous and metamorphic rocks. Application of ionic models to typical hornblendes produces low a _Trem (usually<0.01), consequetly yielding extremely low a _{H 2}O. If an oxy-amphibole component is present, the calculated a _Trem and H₂O is further reduced. An oxy-amphibole component of 25% reduces the calculated H₂O activity and that of any hydroxyl-amphibole component by 50% below that calculated with simplified assumptions regarding X _OH in the hydroxyl site (i.e., X _OH=1, or X _OH=1–X _Cl–X _f). Thus, methods of amphibole normalizations appear to have a substantial effect on calculated amphibole and H₂O activites. Before quantitative hornblende thermobarometry can be calibrated and applied, the amounts of FeO, Fe₂O₃ and H₂O must be measured in order to fully characterize hornblende solid solutions.Contribution No. 478 from the Mineralogical Laboratory, University of Michigan     

Intrusion of basaltic magma into a crystallizing granitic magma chamber: The Cordillera del Paine pluton in southern Chile

The Cordillera del Paine pluton in the southernmost Andes of Chile represents a deeply dissected magma chamber where mafic magma intruded into crystallizing granitic magma. Throughout much of the 10x15 km pluton, there is a sharp and continuous boundary at a remarkably constant elevation of 1,100 m that separates granitic rocks (Cordillera del Paine or CP granite: 69–77% SiO₂) which make up the upper levels of the pluton from mafic and comingled rocks (Paine Mafic Complex or PMC: 45–60% SiO₂) which dominate the lower exposures of the pluton. Chilled, crenulate, disrupted contacts of mafic rock against granite demonstrate that partly crystallized granite was intruded by mafic magma which solidified prior to complete crystallization of the granitic magma. The boundary at 1,100 m was a large and stable density contrast between the denser, hotter mafic magma and cooler granitic magma. The granitic magma was more solidified near the margins of the chamber when mafic intrusion occurred, and the PMC is less disrupted by granites there. Near the pluton margins, the PMC grades upward irregularly from cumulate gabbros to monzodiorites. Mafic magma differentiated largely by fractional crystallization as indicated by the presence of cumulate rocks and by the low levels of compatible elements in most PMC rocks. The compositional gap between the PMC and CP granite indicates that mixing (blending) of granitic magma into the mafic magma was less important, although it is apparent from mineral assemblages in mafic rocks. Granitic magma may have incorporated small amounts of mafic liquid that had evolved to >60% SiO₂ by crystallization. Mixing was inhibited by the extent of crystallization of the granite, and by the thermal contrast and the stable density contrast between the magmas. PMC gabbros display disequilibrium mineral assemblages including early formed zoned olivine (with orthopyroxene coronas), clinopyroxene, calcic plagioclase and paragasite and later-formed amphibole, sodic plagioclase, mica and quartz. The early formed gabbroic minerals (and their coronas) are very similar to phenocrysts in late basaltic dikes that cut the upper levels of the CP granite. The inferred parental magmas of both dikes and gabbros were very similar to subalkaline basalts of the Patagonian Plateau that erupted at about the same time, 35 km to the east. Mafic and silicic magmas at Cordillera del Paine are consanguineous, as demonstrated by alkalinity and trace-element ratios. However, the contemporaneity of mafic and silicic magmas precludes a parent-daughter relationship. The granitic magma most likely was derived by differentiation of mafic magmas that were similar to those that later intruded it. Or, the granitic magma may have been contaminated by mafic magmas similar to the PMC magmas before its shallow emplacement. Mixing would be favored at deeper levels when the cooling rate was lower and the granitic magma was less solidified.     

Zooplankton abundance and community structure in a mesohaline North Carolina estuary

The lower Neuse River Estuary is a temperate mesohaline system which forms the major southern tributary of Pamlico Sound, North Carolina. The crustacean zooplankton of this well-mixed system were sampled for a 20-month period from May 1988 through December 1989. A submersible pump was used to sample both the entire water column and the sediment surface. Seasonal dominants included the calanoid copepodsAcartia tonsa andParacalanus crassirostris in summer, the cyclopoid copepodOithona colcarva in fall, the cladoceranPodon polyphemoides in winter, and harpacticoid copepods in spring. Non-naupliar biomass over the study period consisted of 38.8%A. tonsa, 7.7%P. crassirostris, 21.2%O. colcarva 23.6% harpacticoid copepods, and 6.0% cladocerans. The remainder of the biomass consisted ofPseudodiaptomus coronatus and barnacle nauplii. Mean total copepod densities ranged from 600 m^?3 in May 1988 to 180,000 m^?3 in August 1988. Mean copepod densities for 1989 were 25,000 m^?3. Maximum densities during both years occurred during summer, with subsequent descreases throughtout the year until early spring. Abundances of total copepods, and ofAcartia tonsa in particular, were significantly correlated with water temperature, but with neither chlorophylla, phytoplankton productivity, nor any of an array of other physical or chemical variables. Regression analyses using data from this investigation, and supported by results from other regional studies, indicate that water temperature is likely the single most important variable predicting zooplankton temporal abundance in North Carolina estuaries.