Fluid-mobile trace element constraints on the role of slab melting and implications for Archaean crustal growth models

We use published and new trace element data to identify element ratios which discriminate between arc magmas from the supra-subduction zone mantle wedge and those formed by direct melting of subducted crust (i.e. adakites). The clearest distinction is obtained with those element ratios which are strongly fractionated during refertilisation of the depleted mantle wedge, ultimately reflecting slab dehydration. Hence, adakites have significantly lower Pb/Nd and B/Be but higher Nb/Ta than typical arc magmas and continental crust as a whole. Although Li and Be are also overenriched in continental crust, behaviour of Li/Yb and Be/Nd is more complex and these ratios do not provide unique signatures of slab melting. Archaean tonalite-trondhjemite-granodiorites (TTGs) strongly resemble ordinary mantle wedge-derived arc magmas in terms of fluid-mobile trace element content, implying that they did not form by slab melting but that they originated from mantle which was hydrated and enriched in elements lost from slabs during prograde dehydration. We suggest that Archaean TTGs formed by extensive fractional crystallisation from a mafic precursor. It is widely claimed that the time between the creation and subduction of oceanic lithosphere was significantly shorter in the Archaean (i.e. 20 Ma) than it is today. This difference was seen as an attractive explanation for the presumed preponderance of adakitic magmas during the first half of Earth's history. However, when we consider the effects of a higher potential mantle temperature on the thickness of oceanic crust, it follows that the mean age of oceanic lithosphere has remained virtually constant. Formation of adakites has therefore always depended on local plate geometry and not on potential mantle temperature.     

Oxygen Isotope Evidence for Chemical Interaction of Ki lauea Historical Magmas with Basement Rocks

Klauea historical summit lavas have a wide range in matrix ¹⁸O_VSMOWvalues (4·9–5·6) with lower values in rockserupted following a major summit collapse or eruptive hiatus.In contrast, ¹⁸O values for olivines in most of these lavasare nearly constant (5·1 ± 0·1). The disequilibriumbetween matrix and olivine ¹⁸O values in many samples indicatesthat the lower matrix values were acquired by the magma afterolivine growth, probably just before or during eruption. BothMauna Loa and Klauea basement rocks are the likely sources ofthe contamination, based on O, Pb and Sr isotope data. However,the extent of crustal contamination of Klauea historical magmasis probably minor (< 12%, depending on the assumed contaminant)and it is superimposed on a longer-term, cyclic geochemicalvariation that reflects source heterogeneity. Klauea's heterogeneoussource, which is well represented by the historical summit lavas,probably has magma ¹⁸O values within the normal mid-ocean ridgebasalt mantle range (5·4–5·8) based on thenew olivine ¹⁸O values. KEY WORDS: Hawaii; Klauea; basalt; oxygen isotopes; crustal contamination     

Palaeosecular variation over the past 5 Myr based on a new generalized database

A generalized database of global palaeomagnetic data from 3719 lava flows and thin dykes of age 0–5 Ma has been constructed for use with a relational database management system. The database includes all data whose virtual geomagnetic poles (VGP) lie within 45 of the spin axis and can be used for studies of palaeosecular variation and for geomagnetic field modelling. Because many of these data were collected and processed more than 15–20 years ago, each result has been characterized according to the demagnetization procedures carried out. Analysis of these data in terms of the latitude variation of the angular dispersion of VGPs (palaeosecular variation from lavas) strongly suggests that careful data selection is required and that many of the older studies may need to be redone using more modern methods. Differences between the angular dispersions for separate normal- and reverse-polarity data sets confirm that many older studies have not been adequately cleaned magnetically. Therefore, the use of the database for geomagnetic field modelling should be carried out with some caution. Using a VGP cut-off angle that varies with latitude, the best data set consists of 2636 results that show a smooth increase of VGP angular dispersion with latitude. Model G for palaeosecular variation, which is based on modelling of the antisymmetric (dipole) and symmetric (quadrupole) dynamo families, provides a good fit to these results.     

Short- and long-term sediment transport in western Bohai Bay and coastal areas

Sediment cores (∼40–100 cm) were collected at 12 locations in the western Bohai Bay, the Haihe River estuary, the Yongding River estuary and the Tianjin Harbor, China, during 24–26 July 2007, and analyzed for ⁷Be and ²¹⁰Pb activities. Due to localized hydrodynamic patterns and frequent disturbance from dredging activities, steady-state sedimentation features were not observed in this study. As demonstrated in the ⁷Be and ²¹⁰Pb profiles, the temporal and spatial variations of these radionuclides support a non-steady state depositional environment in the study area. By comparing ⁷Be and ²¹⁰Pb inventories in the sediments with those of the atmospheric source, we found that: 1) sediments dredged from the Tianjin Harbor or eroded from nearby estuarine and coastal areas are retained in the western Bohai Bay for relatively short intervals (several months), as reflected in the relatively high ⁷Be inventories in the western Bohai Bay; 2) over the long-term (years to decades), ²¹⁰Pb inventories in the sediments imply that there is a net on-shore transport of sediments, and the sediments are mass-balanced in the entire study area. Overall, our results suggest that the sediments are retained in the estuaries and the western Bohai Bay despite local variability in sediment dynamics and disturbance due to human activities.     

Carbon and nitrogen isotope,and mineral inclusion studies on the diamonds from the Pozanti–Karsanti chromitite,Turkey

The Pozanti–Karsanti ophiolite (PKO) is one of the largest oceanic remnants in the Tauride belt, Turkey. Micro-diamonds were recovered from the podiform chromitites, and these diamonds were investigated based on morphology, color, cathodoluminescence, nitrogen content, carbon and nitrogen isotopes, internal structure and inclusions. The diamonds recovered from the PKO are mainly mixed-habit diamonds with sectors of different brightness under the cathodoluminescence images. The total δ¹³C range of the PKO diamonds varies between ??18.8 and ??28.4‰, with a principle δ¹³C mode at ??25‰. Nitrogen contents of the diamonds range from 7 to 541 ppm with a mean value of 171 ppm, and the δ¹⁵N values range from ??19.1 to 16.6‰, with a δ¹⁵N mode of ??9‰. Stacking faults and partial dislocations are commonly observed in the Transmission Electron Microscopy foils whereas inclusions are rather rare. Combinations of (Ca_0.81Mn_0.19)SiO₃, NiMnCo-alloy and nano-sized, quenched fluid phases were observed as inclusions in the PKO diamonds. We believe that the ¹³C-depleted carbon signature of the PKO diamonds derived from previously subducted crustal matter. These diamonds may have crystallized from C-saturated fluids in the asthenospheric mantle at depth below 250 km which were subsequently carried rapidly upward by asthenospheric melts.     

Decadal‐Scale Changes of the Ödenwinkelkees,Central Austria,Suggest Increasing Control of Topography and Evolution Towards Steady State

Small mountain glaciers have short mass balance response times to climate change and are consequently very important for short‐term contributions to sea level. However, a distinct research and knowledge gap exists between (1) wider regional studies that produce overview patterns and trends in glacier changes, and (2) in situ local scale studies that emphasise spatial heterogeneity and complexity in glacier responses to climate. This study of a small glacier in central Austria presents a spatiotemporally detailed analysis of changes in glacier geometry and changes in glaciological behaviour. It integrates geomorphological surveys, historical maps, aerial photographs, airborne LiDAR data, ground‐based differential global positioning surveys and Ground Penetrating Radar surveys to produce three‐dimensional glacier geometry at 13 time increments spanning from 1850 to 2013. Glacier length, area and volume parameters all generally showed reductions with time. The glacier equilibrium line altitude increased by 90 m between 1850 and 2008. Calculations of the mean bed shear stress rapidly approaching less than 100 kPA, of the volume–area ratio fast approaching 1.458, and comparison of the geometric reconstructions with a 1D theoretical model could together be interpreted to suggest evolution of the glacier geometry towards steady state. If the present linear trend in declining ice volume continues, then the Ödenwinkelkees will disappear by the year 2040, but we conceptualise that non‐linear effects of bed overdeepenings on ice dynamics, of supraglacial debris cover on the surface energy balance, and of local topographically driven controls, namely wind‐redistributed snow deposition, avalanching and solar shading, will become proportionally more important factors in the glacier net balance.     

Phytoplankton production and nutrient distributions in a subtropical estuary: Importance of freshwater flow

The relationships between phytoplankton productivity, nutrient distributions, and freshwater flow were examined in a seasonal study conducted in Escambia Bay, Florida, USA, located in the northeastern Gulf of Mexico. Five sites oriented along the salinity gradient were sampled 24 times over the 28-mo period from 1999 to 2001. Water column profiles of temperature and salinity were measured along with surface chlorophyll and surface inorganic nutrient concentrations. Primary productivity was measured at 2 sites on 11 dates, and estimated for the remaining dates and sites using an empirical regression model relating phytoplankton net production to the product of chlorophyll, euphotic zone depth, and daily solar insolation. Freshwater flow into the system varied markedly over the study period with record low flow during 2000, a flood event in March 2001, and subsequent resumption of normal flow. Flushing times ranged from 1 d during the flood to 20 d during the drought. Freshwater input strongly affected surface salinity distributions, nutrient flux, chlorophyll, and primary productivity. The flood caused high turbidity and rapid flushing, severely reducing phytoplankton production and biomass accumulation. Following the flood, phytoplankton biomass and productivity sharply increased. Analysis of nutrient distributions suggested Escambia Bay phytoplankton alternated between phosphorus limitation during normal flow and nitrogen limitation during low flow periods. This study found that Escambia Bay is a moderately productive estuary, with an average annual integrated phytoplankton production rate of 290 g C m⁻² yr⁻¹.     

A simple meteorological buoy with satellite telemetry

A small, inexpensive, and easily deployable meteorological buoy is described. Buoy motion is greatly reduced by appropriate ballast techniques; vector averaging further removes buoy motion effects from wind data. Data is transmitted to the GOES satellite and is retrieved by telephone. Measurements are vector-averaged wind components, wind speed, wind direction, water temperature, air temperature, and compass direction. Data from two field trials are discussed. Speed comparisons averaged 0.2 m sec⁻¹ with a standard deviation of 0.6 m sec⁻¹. Direction comparisons were different due to local topography, but they indicate a probable accuracy of ±5°.