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111.
The enantiomeric and carbon-isotopic composition of the amino acid isovaline have been analyzed in several samples of the Murchison meteorite and one sample of the Murray meteorite. l-Enantiomeric excesses of the amino acid were found to range from 0 to 15.2%, varying significantly both between meteorite stones and at short distances within a single stone. The upper limit of this range is the largest enantiomeric excess measured to date for a biologically rare meteoritic amino acid and raises doubts that circularly polarized light irradiation could have been the sole cause of amino acids chiral asymmetry in meteorites. Individual d- and l-isovaline δ13C values ware found to be about +18‰, with no significant differences between the two enantiomers to suggest terrestrial contamination. The amino acid relative abundance also varied between samples, with isovaline/alanine ratios of 0.5 to 6.5. X-ray diffraction analyses of contiguous meteorite fragments suggest a possible correlation between isovaline and hydrous silicates abundances. 相似文献
112.
113.
Mapping block-and-ash flow hazards based on Titan 2D simulations: a case study from Mt. Taranaki,NZ 总被引:1,自引:0,他引:1
Jonathan N. Procter Shane J. Cronin Thomas Platz Abani Patra Keith Dalbey Michael Sheridan Vince Neall 《Natural Hazards》2010,53(3):483-501
Numerical models for simulation of mass flows are typically focussed upon accurately predicting the paths, travel times and
inundation from a single flow or collapse event. When considering catchment-based hazards from a volcano, this is complicated
by often being faced with several possible scenarios. Over the last 800 years at Mt. Taranaki/Egmont, a number of dome growth
and collapse events have resulted in the genesis and emplacement of block-and-ash flows (BAFs). Each BAF was directed northwestward
by a breach in the crater rim. The latest dome collapse events in the AD 1880s and AD 1755 inundated the northwestern flank
and had run-out lengths 10 km from source. Future activity of this type could have a devastating effect on the Taranaki region’s
communities, infrastructure and economy. Hazard planning has involved constructing volcanic hazard maps based upon the areas
inundated by past volcanic flows, with little consideration of present-day topography. Here, a numerical geophysical mass
flow modelling approach is used to forecast the hazards of future comparable BAF events on NW Mt. Taranaki. The Titan2D programme
encompasses a “shallow water”, continuum solution-based, granular flow model. Flow mechanical properties needed for this approach
include estimates of internal and basal friction as well as the physical dimensions of the initial collapse. Before this model
can be applied to Taranaki BAFs, the input parameters must be calibrated by simulating a range of past collapse events. By
using AD 1860 and AD 1755 scenarios, initial collapse volumes can be well constrained and internal and basal friction angles
can be evaluated through an iterative approach from previous run-out lengths. A range of possible input parameters was, therefore,
determined to produce a suite of potentially inundated areas under present-day terrain. A suite of 10 forecasts from a uniformly
distributed range were combined to create a map of relative probabilities of inundation by future BAF events. These results
were combined in a GIS package to produce hazard zones related to user-specified hazard thresholds. Using these input parameter
constraints, future hazard forecasts for this scale and type of event can also take into account changing summit and topographic
configurations following future eruptive or collapse events. 相似文献
114.
Pece V. Gorsevski M. Kenneth Brown Kurt Panter Charles M. Onasch Anita Simic Jeffrey Snyder 《Landslides》2016,13(3):467-484
The purpose of this study was to detect shallow landslides using hillshade maps derived from light detection and ranging (LiDAR)-based digital elevation model (DEM) derivatives. The landslide susceptibility mapping used an artificial neural network (ANN) approach and backpropagation method that was tested in the northern portion of the Cuyahoga Valley National Park (CVNP) located in northeast Ohio. The relationship between landslides and predictor attributes, which describe landform classes using slope, profile and plan curvatures, upslope drainage area, annual solar radiation, and wetness index, was extracted from LiDAR-based DEM using geographic information system (GIS). The approach presented in this paper required a training study area for the development of the susceptibility model and a validation study area to test the model. The results from the validation showed that within the very high susceptibility class, a total of 42.6 % of known landslides that were associated with 1.56 % of total area were correctly predicted. In contrast, the very low susceptibility class that represented 82.68 % of the total area was associated with 1.20 % of known landslides. The results suggest that the majority of the known landslides occur within a small portion of the study area, consistent with field investigation and other studies. Sample probabilistic maps of landslide susceptibility potential and other products from this approach are summarized and presented for visualization to help park officials in effective management and planning. 相似文献
115.
Jordan A. Rosencranz Lauren N. Brown James R. Holmquist Yareli Sanchez Glen M. MacDonald Richard F. Ambrose 《Estuaries and Coasts》2017,40(5):1371-1384
Salt marsh resilience to sea-level rise depends on marsh plain elevation, tidal range, subsurface processes, as well as surface accretion, of which suspended-sediment concentration (SSC) is a critical component. However, spatial and temporal patterns of inorganic sedimentation are poorly quantified within and across Salicornia pacifica (pickleweed)-dominated marshes. We compared vertical accretion rates and re-examined previously published suspended-sediment patterns during dry-weather periods at Seal Beach Wetlands, which is characterized by a mix of Spartina foliosa (cordgrass) and pickleweed, and for Mugu Lagoon, where cordgrass is rare. Mugu Lagoon occurs higher in the tidal frame and receives terrigenous sediment from an adjacent creek. Feldspar marker horizons were established in winter 2013–2014 to measure accretion. Accretion rates at Seal Beach Wetlands and Mugu Lagoon were 6 ± 0.5 mm/year (mean ± SE) and 2 ± 0.3 mm/year. Also, the estimated sediment flux (g/year) across the random feldspar plots was 3.5 times higher at Seal Beach Wetlands. At Mugu Lagoon, accretion was higher near creeks, although not statistically significant. Dry-weather SSC showed similar concentrations at transect locations across sites. During wet weather, however, SSC at Mugu Lagoon increased at all locations, with concentrations decaying farther than 8 m from tidal creek edge. Based on these results from Mugu Lagoon, we conclude accretion patterns are set by infrequent large flooding events in systems where there is a watershed sediment source. Higher accretion rates at Seal Beach Wetlands may be linked to lower-marsh elevations, and thus more frequent inundation, compared with Mugu Lagoon. 相似文献
116.
Eman Al-Awadi Michael Quinn Amitabha Mukhopadhyay Andre Hauser Adnan Akber Adel Al-Haddad Majed Al-Rashedi 《Environmental Geology》2009,56(5):877-889
A study, aimed at characterizing the nature of anthropogenic and biogenic hydrocarbon contamination in the groundwater of
Kuwait, was carried out using fluorescence spectroscopy and other analytical techniques. The results of these analyses have
demonstrated that the groundwater in certain areas of northern Kuwait has been significantly impacted by contamination originating
from the oil-contaminated surface soils. The study revealed that a water-soluble fraction (WSF) of the crude oil surface contamination
appeared to be slowly leaching into the freshwater lenses located in the area. The study also showed that hydrocarbon pollutants
were practically absent in the brackish water areas of central and southern Kuwait, except for a few isolated sites. However,
nonpetroleum hydrocarbons, with ultraviolet-visible absorption characteristics and fluorescence characteristics typically
associated with humic substances, were observed at a few sites in the brackish water fields. 相似文献
117.
Biswajit Mukhopadhyay Michael J. Holdaway 《Contributions to Mineralogy and Petrology》1994,116(4):462-472
The equilibrium in which hydrous Fe-cordierite breaks down to almandine, sillimanite, quartz, and water was previously experimentally determined by Richardson (1968) and Holdaway and Lee (1977) using QMF buffer and by Weisbrod (1973) using QIF buffer. All these studies yielded similar results — a negative dP/dT slope for the equilibrium curve. However, based on theoretical arguments, Martignole and Sisi (1981), and based on Fe-Mg partitioning experiments on coexisting cordierite and garnet in equilibrium with sillimanite and quartz, Aranovich and Podlesskii (1983) suggested that this equilibrium curve has a positive dP/dT slope and its position depends on the water content of the equilibrium cordierite. We have redetermined this equilibrium using a much improved tecnique of detecting reaction direction, and cordierite starting material that contained virtually no hercynite. Hercynite was present as a contaminant in the cordierites of previous experimental studies and possibly reacted with quartz during the experimental runs to expand the apparent stability field of Fe-cordierite. We synthesized Fe-cordierite from reagent grade oxides at 710°C and 2 kbar (using QMF buffer) with two intermediate stages of grinding and mixing. The cordierite has a unit cell volume of 1574.60 Å3 (molar volume=23.706 J/bar) and no Fe3+ as indicated by X-ray diffraction and room temperature Mössbauer studies respectively. Reaction direction was concluded by noting20% change of the ratios of intensities of two key X-ray diffraction peaks of cordierite and almandine. Our results show that the four-phase equilibrium curve passes through the points 2.1 kbar, 650°C and 2.5 kbar, 750°C. This disagrees with all previous experimental studies. H2O in the Fe-cordierite, equilibrated at 2.2 kbar and 700°C and determined by H-extraction line in the stable isotope laboratory, is 1.13 wt% (n=0.41 moles). H2O content of pure Mg-cordierite equilibrated under identical conditions and determined by thermogravimentric conditions and determined by thermogravimetric analysis is 1.22 wt% (n=0.40). Similar determinations on Fe-cordierite and Mg-cordierite equilibrated at 2.0 kbar and 650°C show 1.27 wt% (n=0.46) and 1.47 wt% (n=0.48) of H2O respectively. Thus, H2O content appears to be independent of Fe/Mg ratio in cordierite, a conclusion which supports previous experimental determinations. The experimentally determined equilibrium curve represents conditions of PH2O=Ptotal. From this we calculated the anhydrous curve representing equilibrium under conditions of X
H2O
V
=0.0. A family of calculated equilibrium curves of constant n
H2O
Cord
cut the experimentally determined curve at a very small angle indicating a slight variation in n
H2O
Cord
in cordierite in equilibrium with almandine, sillimanite, and quartz under the conditions of constant X
H2O
V
. Ancther set of calculated equilibrium curves, each representing constant a
H2O
V
demonstrate that the slopes of the curves vary with X
H2O
V
, and are all positive in the full range of 0.0X
H2O
V
1.0. 相似文献
118.
Quantifying the Tetrad Effect,Shape Components,and Ce–Eu–Gd Anomalies in Rare Earth Element Patterns
Mathematical Geosciences - Plots of chondrite-normalised rare earth element (REE) patterns often appear as smooth curves. These curves can be decomposed into orthogonal polynomial functions (shape... 相似文献
119.
120.
J. Todd Hoeksema Yang Liu Keiji Hayashi Xudong Sun Jesper Schou Sebastien Couvidat Aimee Norton Monica Bobra Rebecca Centeno K. D. Leka Graham Barnes Michael Turmon 《Solar physics》2014,289(9):3483-3530
The Helioseismic and Magnetic Imager (HMI) began near-continuous full-disk solar measurements on 1 May 2010 from the Solar Dynamics Observatory (SDO). An automated processing pipeline keeps pace with observations to produce observable quantities, including the photospheric vector magnetic field, from sequences of filtergrams. The basic vector-field frame list cadence is 135 seconds, but to reduce noise the filtergrams are combined to derive data products every 720 seconds. The primary 720 s observables were released in mid-2010, including Stokes polarization parameters measured at six wavelengths, as well as intensity, Doppler velocity, and the line-of-sight magnetic field. More advanced products, including the full vector magnetic field, are now available. Automatically identified HMI Active Region Patches (HARPs) track the location and shape of magnetic regions throughout their lifetime. The vector field is computed using the Very Fast Inversion of the Stokes Vector (VFISV) code optimized for the HMI pipeline; the remaining 180° azimuth ambiguity is resolved with the Minimum Energy (ME0) code. The Milne–Eddington inversion is performed on all full-disk HMI observations. The disambiguation, until recently run only on HARP regions, is now implemented for the full disk. Vector and scalar quantities in the patches are used to derive active region indices potentially useful for forecasting; the data maps and indices are collected in the SHARP data series, hmi.sharp_720s. Definitive SHARP processing is completed only after the region rotates off the visible disk; quick-look products are produced in near real time. Patches are provided in both CCD and heliographic coordinates. HMI provides continuous coverage of the vector field, but has modest spatial, spectral, and temporal resolution. Coupled with limitations of the analysis and interpretation techniques, effects of the orbital velocity, and instrument performance, the resulting measurements have a certain dynamic range and sensitivity and are subject to systematic errors and uncertainties that are characterized in this report. 相似文献