Heavy metal biosorption potential of a Malaysian Rhodophyte (<Emphasis Type="Italic">Eucheuma denticulatum</Emphasis>) from aqueous solutions

Biosorption is a promising technology for the removal of heavy metals from industrial wastes and effluents. In the present study, biosorption of Pb²⁺, Cu²⁺, Fe²⁺ and Zn²⁺ onto the dried biomass of Eucheuma denticulatum (Rhodophyte) was investigated as a function of solution pH, contact time, temperature and initial metal ion concentration. The experimental data were evaluated by Langmuir, Freundlich, Temkin and Dubinin–Radushkevich isotherm models. The sorption isotherm data followed Langmuir and Freundlich models, and the maximum Langmuir monolayer biosorption capacity was found as 81.97, 66.23, 51.02 and 43.48 mg g^?1 for Pb²⁺, Cu²⁺, Fe²⁺ and Zn²⁺, respectively. The sorption kinetic data followed pseudo-second-order and intraparticle diffusion models. Thermodynamic study revealed feasible, spontaneous and endothermic nature of the sorption process. Fourier transform infrared analysis showed the presence of amine, aliphatic, carboxylate, carboxyl, sulfonate and ether groups in the cell wall matrix involved in metal biosorption process. A total of nine error functions were applied in order to evaluate the best-fitting models. We strongly suggest the analysis of error functions for evaluating the fitness of the isotherm and kinetic models. The present work shows that E. denticulatum can be a promising low-cost biosorbent for removal of the experimental heavy metals from aqueous solutions. Further study is warranted to evaluate its potential for the removal of heavy metals from the real environment.     

Multiple step ahead river flow modelling for south east tasmanian aquaculture

We develop multiple step ahead prediction models of river flow for locations in Tasmania (Australia) for decision support in aquaculture. In predicting river flows for multiple days ahead, we first statistically determine the maximum input lags of rainfall and river flow. We then use machine learning techniques in building models. In multiple step ahead prediction, we consider both static and dynamic approaches. In dynamic approach, one day prediction is served as input to two days ahead prediction. The experimental results demonstrate that, in general, a dynamic approach provides better accuracy in multiple day’s ahead prediction. For Duck Bay location using dynamic approach, support vector regression performs best over linear regression, M5P and multilayer perceptron. However, at Montagu Bay location, we find that M5P performs best over methods. We find that multiple step ahead prediction of river flow for each location requires modelling of lags with associated machine learning techniques.     

Mineral chemistry of banded migmatites from Hafafit and Feiran areas, Egypt

The migmatitic rocks exposed in Hafafit and Feiran areas exhibit some migmatitic structures as the banded, agmatic, boudinage and schlieren structures. The dominant type of these structures is the stromatic migmatites. Electron microprobe analyses of plagioclases, biotites and amphiboles from Hafafit and Feiran areas, in the Eastern Desert and Sinai, Egypt, are carried out and the metamorphic conditions are discussed. The present study revealed marked differences in the composition of plagioclases, biotites and amphiboles from Hafafit and Feiran localities. The obtained data indicated that plagioclases of the Feiran migmatites are of andesine and oligoclase composition, and display anorthite content from An₂₀ to An₃₈; whereas the Hafafit migmatites show a wider range of plagioclases from An₁₀ to An₆₀, and therefore plagioclases have labradorite, andesine and oligoclase composition. This may be due to the slow rate of the crystallisation processes. The analyses indicated that biotites of the studied areas are of metamorphic origin showing significant variation in Fe–Mg. It is worth mentioning that biotites from Hafafit migmatites have Mg–biotite composition while that of Feiram migmatites have Fe–biotite composition. High Mg and low Fe contents in biotite suggest higher crystallisation temperature. The composition of amphiboles in Hafafit migmatites is ferro-tschermakitic hornblende, while amphiboles from Feiram migmatites are magnesio-hornblende. High Ti content in the hornblende of Feiran migmatites suggests that they were formed at slightly higher temperatures and lower pressure than the Hafafit migmatites (i.e. Feiram migmatites and Hafafit migmatites were formed at granulite and amphibolite facies, respectively). Discrimination diagrams show that the muscovite is of secondary origin. Moreover, the present study confirmed that these migmatites are mainly formed by metamorphic differentiation via partial melting.     

Derivation of short-duration design rainfalls using daily rainfall statistics

Design rainfall intensity–frequency–duration data are a basic input to many water-related development projects. To derive design rainfalls, one needs long period of recorded rainfall data. Although daily rainfall data are generally widely available, short-duration rainfall data are scarce. For many urban applications, design rainfalls for much shorter durations are needed, which cannot be obtained directly from daily read rainfall data. This paper presents a simple approach that can be adopted to derive design rainfalls of short durations using daily rainfall data and other physio-climatic characteristics using a novel ‘index frequency combined with parameter regression technique’. This uses L moments to reduce the impacts of sampling variability in the analysis. Furthermore, this adopts generalised least squares regression to account for the inter-station correlation of the rainfall data in the analysis. The proposed method is applied to a pilot data set consisting of 203 rainfall stations across Australia. An independent Monte Carlo cross-validation test shows that the proposed method is capable of generating consistent and accurate design rainfall estimates from 6-min to 12-h duration. The developed technique can be adapted to other countries where there is a scarcity of short-duration rainfall data, but daily rainfall data are abundant.     

Post-Cyclone Sidr illness patterns in coastal Bangladesh: an empirical study

After the landfall of Cyclone Sidr along the southwestern coast of Bangladesh on November 15, 2007, emergency and public health personnel within and beyond Bangladesh anticipated a massive outbreak of water-borne and other diseases in most affected areas. Fortunately, such an outbreak did not occur. The objectives of this paper are to examine the extent and pattern of illnesses experienced by Cyclone Sidr survivors in the aftermath of its landfall and to investigate household and individual-level factors associated with such illnesses. Based on face-to-face interviews conducted among 277 randomly selected Sidr survivors living in the four most severely impacted coastal districts, this study found that the post-cyclone incidence of water-borne, respiratory, and other diseases was not unusually high. Only 52 persons suffered Sidr-related illnesses, and their illnesses were significantly associated with household income, and gender and age of the Sidr survivors. A major outbreak of such diseases was largely avoided because of the proper distribution of food and safe drinking water, as well as the timely implementation of health care intervention measures. This important finding will aid relevant authorities in successfully responding to outbreaks of diseases following a future extreme event in Bangladesh and perhaps elsewhere.     

The radius spectrum of solid grains settling in gaseous giant protoplanets

Growth of grains having different initial sizes (10^?3 cm?≤?r ₀?≤?1 cm) has been investigated by coagulation processes inside gas giant protoplanets, formed by disk instability, in the mass range 0.3 to 10 Jovian masses. In doing so, we have determined distribution of thermodynamic variables inside the protoplanets and using the results we have determined growth of the grains having assumed initial sizes. Regarding the transference of heat inside the protoplanets, we have considered the possible two cases of interest, namely convection and conduction-radiation. The results of our calculation show that growth of the grains depends on protoplanetary masses and on initial states of the protoplanets and eventually all the grains having assumed different initial sizes acquire almost the same distribution in the central regions of respective protoplanets in the respective cases.     

The catastrophic cyclone of April 1991: Its Impact on the economy of Bangladesh

A very severe cyclonic storm with wind speeds of over 240 km/h struck the coastal areas of Bangladesh in the full moon night of 29 April 1991. The path of the eye, close to the shore, raised a storm surge of unusual height, reportedly more than 9 m above the mean sea level, which devastated the offshore islands and the mainland coast. The damage to the physical infrastructure of the port of Chittagong and adjoining industrial area has been colossal, and recovery will take years. Death tolls from the cyclone, storm surge and its aftermath exceeded 145 000 making it one of the world's major natural disasters of this century.This paper is concerned with examining the magnitude and intensity of the disaster. It analyses how the people of Bangladesh, and the environment in which they live, were affected by the cyclone. A brief account is presented of loss of life and of the damage suffered in various sectors, including agriculture, industry, and physical infrastructure.The paper lays emphasis on the need of building a sufficient number of multipurpose cyclone shelters in the disaster-prone coastal areas of Bangladesh. Adequate measures should be taken for evacuating people from vulnerable areas and putting them into these shelters in the event of a cyclonic storm. Simplification of the current cyclone warning system is recommended.The difficulties of providing relief to the survivors are discussed. And finally, the need for improvement of the communication infrastructure in the coastal areas is highlighted.     

Electron capture strength on odd-A nucleus 59Co in explosive astrophysical environment

The Gamow-Teller (GT) transitions within massive stars play sumptuous role in the dynamics of core collapse supernovae. GT strength distributions and electron capture rates have been calculated for odd-A nucleus ⁵⁹Co within the proton-neutron quasiparticles random phase approximation (pn-QRPA) formalism. The pn-QRPA results are compared with other model calculations and (n,p) reaction experiment carried out at TRIUMF charge-exchange facility. The pn-QRPA calculated a total B(GT ₊) strength of 3.3 for ⁵⁹Co to be compared with the shell model value of 2.5 and the 1.9±0.1 in the (n,p) charge-exchange reaction. Aufderheide et al. (1993) extracted total strength equaling 2.4±0.3. The placement of GT centroid at 5.6 MeV by the pn-QRPA model is in reasonable agreement with the shell model centroid at 5.1 MeV whereas the measured GT centroid was placed at 4.4±0.3 MeV in the (n,p) experiment. Fuller, Fowler and Newman (FFN) (1980, 1982a, 1982b), placed the GT centroid at too low excitation energy of 2.0 MeV in the daughter nucleus ⁵⁹Fe, and this misplacement led to the enhancement of FFN rates. The suppressed pn-QRPA and shell model electron capture rates are in good agreement with each other. The rates are suggestive of higher value of Y _e (electron-to-baryon ratio) and may contribute to a more massive homologously collapsing core resulting in a more energetic shock. It might be interesting for the simulators to check the effect of these suppressed rates on the fine-tuning of the time rate of Y _e , the concomitant heavy element nucleosynthesis, and, on the energetics of the subsequent shock wave.     

Water and sediment quality, partial mass budget and effluent N loading in coastal brackishwater shrimp farms in Bangladesh

The present study aimed to quantify the water and sediment quality and growth and production parameters and to establish nutrient budgets for an average of five selected semi-intensive shrimp ponds in Bangladesh over a growing cycle. Physico-chemical parameters of water and sediments were measured and analyzed by standard methods. Gross yield (kg ha-1) of shrimp was calculated from the stocking and harvesting data. Finally, a partial nutrient mass budget for N and P was calculated. Most of the parameters of water and sediments correlated significantly with each other suggesting a high degree of interactions between different parameters in the system. Significantly higher concentrations of all species of nitrogenous nutrients were recorded in the effluent waters than that entering into the ponds. Therefore, a high loading and net output of nitrogenous nutrients in effluent waters was documented. The study also indicated a net discharge of solids and minerals through effluent loading. However, significantly lower concentrations of phosphorus in the effluent water indicated a net retention and trapping of phosphatic nutrients in the environment. Total production ranged between 532.0 and 697.0 kg ha-1 cycle-1 and P. monodon production between 484.0 and 562.0 kg ha-1 cycle-1. Ponds gained nitrogen primarily from intake water (55%) and fertilizers (29%), and nitrogen was lost primarily from water exchange (78%) and harvested shrimp (12%). Phosphorus gain occurred mostly from intake water (52%) and fertilizers (25%), and phosphorus was lost primarily from water exchange (52%) and harvested shrimp (3.3%). About 10% of input nitrogen and 44% of phosphorus were not accounted for in measured losses, and presumably were fixed or metabolized in the system. On average, 78 g N was discharged to and 25 g P was removed from the surrounding water by the system for each kilogram of shrimp produced. Mean conversion of feed nitrogen and phosphorus to shrimp flesh averaged 74% and 40%, respectively. It was concluded that semi-intensive systems serve as net supplier of N to and net remover of P from the surrounding water.