Ra-partitioning between phlogopite and silicate melt and 226Ra/Ba–230Th/Ba isochrons

In this study we experimentally determine phlogopite/melt partition coefficients of Ra and other trace elements in a lamproitic system. This work was achieved using an analytical technique (LA-ICP-MS) with low detection limits (~ 0.01 fg) permitting the measurement of the very low Ra concentrations feasible in experiments (~ 1 ppb). D_Ra^{phlogopite/melt} was determined to 2.28 ± 0.44 and 2.84 ± 0.47 in two experiments, the ratio D_Ra/D_Ba is around 1.6. The compatibility of Ra in phlogopite results from an ionic radius being close to the apex of the lattice strain parabola for earth alkalis in the large XII-coordinated interlayer site of phlogopite. A re-evaluation of D_Ra and D_Ra/D_Ba for magmatic minerals containing appreciable Ra, yields D_Ra^mineral/melt ranging from ~ 2.6 for phlogopite down to 2–3 ? 10^? 5 for pyroxenes, and D_Ra/D_Ba^mineral/melt from ~ 4 for leucite to 2 ? 10^? 2 for orthopyroxene. The influence of melt composition on D_Ra/D_Ba is less than 10%. All investigated minerals have different D_Ra/D_Ba, strongly fractionating Ra from Ba. Thus, for magmatic systems, (²²⁶Ra)/Ba in the various minerals is not constant, these minerals do not form a straight line in the (²²⁶Ra)/Ba–(²³⁰Th)/Ba system at the time of crystallization and thus, there is no (²²⁶Ra)/Ba–(²³⁰Th)/Ba isochron at t₀. ²²⁶Ra–²³⁰Th–Ba mineral dating is thus applicable only to model ages calculated from mineral–glass pairs with known D_Ra.     

Highway Roadway Stability Influenced by Warm Permafrost and Seasonal Frost Action: A Case Study from Glennallen, Alaska, USA

Ground temperatures from four of the seven extensively studied highway cross-sections near Gulkana/Glennallen,Alaska during 1954~1962,were chosen to better understand the impacts of highway construction on warm permafrost.Both the thawing of permafrost and seasonal frost action impacted on road surface stability for about 6 years until the maximum summer thaw reached about 3 m in depth.Seasonal frost action caused most of the ensuing stability problems.Unusually warm summers and the lengths of time required to re-freeze the active layer were far more important than the average annual air temperatures in determining the temperatures of the underlying shallow permafrost,or the development of taliks.The hypothesized climate warming would slightly and gradually deepen the active layer and the developed under-lying talik,but its effect would be obscured by unusually warm summers,by warmer than usual winters,and by the vari-able lengths of time of the zero curtains.At least one period of climate mini-cooling in the deeper permafrost during the early 20th century was noted.     

Magnetic crustal character in Central Ireland

The simplest magnetic model for the upper 20 km of crust in central Ireland is of two layers. A thin, weakly magnetic upper layer carrying a number of magnetic bodies that can be related to surface geology overlies a magnetic crustal zone whose gross magnetization increases towards the north. The deeper trace of the lapetus Suture in central Ireland forms the boundary between a more magnetic northern crustal area and a less magnetic southern area. A pre-Carboniferous major dextral offset of this suture boundary occurs in the Limerick area. The suture is traced beneath the Dingle peninsula in the far south-west of Ireland. In east-central Ireland, between the Iapetus Suture and Southern Upland Line, the crust contains a large, south-dipping magnetic body with no surface expression, which produces the Virginia magnetic anomaly. The development of magnetic bodies — in particular, volcanic rocks of Carboniferous age — has been controlled by regional stress patterns. The major volcanic centre at Limerick lies at the intersection of two major Caledonian block fault systems just to the north of the surface trace of the Hercynian Front.