Vertikale und zeitliche Verteilung der Leitfähigkeit in einem eutrophen Gewässer während der Sommerstagnation

Summary Data are given of the vertical distribution of temperature, conductivity and alkalinity of an eutrophic lake (Rotsee near Lucerne) measured at short intervals during the summer stratification. We were able to prove in a limited measure only the expected day's periodicity from the conductivity of the CO₂-assimilation of the phytoplankton. We found pronounced internal ‘seiches’ in the hypolimnion; their mathematical interpretation is given only in the order of size.Rodhe's diagram andNümann's method make it possible to determine quantitative relations; from the chemical point of view the lake (depth 16,5 m) shows a four-layered type during the summer.      

临界转换的早期预警信号

从生态系统到金融市场和气候在内的很多复杂动力系统,都会有临界点,在这样的点上系统可能会发生突变,从而演变到一个对立的动力模式上。在这样的临界点到达之前对其进行预测极为困难,但是现在,不同科学领域的研究工作表明,普遍性的早期预警信号有迹可循。对一系列不同类型的系统来说,这些信号会指示是否正在趋近一个临界阈值。     

The composition of liquids coexisting with dense hydrous magnesium silicates at 11-13.5 GPa and the endpoints of the solidi in the MgO-SiO2-H2O system

High-pressure liquids in the MgO-SiO₂-H₂O (MSH) system have been investigated at 11 and 13.5 GPa and between 1000 and 1350 °C. A bulk composition more magnesian than the tie-line forsterite-H₂O was employed for the study. Rocking multi-anvil experiments were combined with a diamond trap set-up. After termination of the experiments, the liquid trapped in the diamond layer was analysed by laser ablation ICP-MS using the ‘freezing’ technique. At 11 GPa, liquids coexist with one or two of phase A, clinohumite, chondrodite, and forsterite. A marked discontinuity in the evolution of liquid compositions near 1100 °C is observed at 11 GPa. A step of ∼13 wt% H₂O and 13 wt% MgO is interpreted to result from overstepping the fluid-saturated solidus reaction mass balanced to 1.00(18) phase A + 1.07(4) fluid = 0.63(15) chondrodite + 1.44(2) melt. At 13.5 GPa liquids coexist with one or two of hydrous wadsleyite, clinohumite, superhydrous B, phase B, and forsterite. The discontinuity in liquid composition is no longer present, indicating that the second critical endpoint of the solidus has been overstepped. Thus, hydrous melts in the Mg-rich part of the MSH system (molar bulk Mg/Si > 2) are chemically distinct from aqueous fluids at pressure up to 11 GPa. Convergence of fluid and melt compositions along the solidus resulting in a supercritical liquid occurs between 11 and 13.5 GPa, at which pressure the entire MSH system becomes supercritical.     

Climate Change as a Predictable Surprise

In this article, I analyze climate change as a “predictable surprise,” an event that leads an organization or nation to react with surprise, despite the fact that the information necessary to anticipate the event and its consequences was available (Bazerman and Watkins, 2004). I then assess the cognitive, organizational, and political reasons why society fails to implement wise strategies to prevent predictable surprises generally and climate change specifically. Finally, I conclude with an outline of a set of response strategies to overcome barriers to change.This paper has benefitted from the excellent input from Alex Todorov, Michael Oppenheimer, and three anonymous reviewers.     

Digital mapping of coastal boulders – high-resolution data acquisition to infer past and recent transport dynamics

Coastal boulder fields provide clues to long-term frequency-magnitude patterns of coastal flooding events and have the potential to play an important role in coastal hazard assessment. Mapping boulders in the field is time and labour-intensive, and work on intertidal reef platforms, as in the present study, is physically challenging. By addressing coastal scientists who are not specialists in remote sensing, this contribution reports on the possibilities and limitations of digital applications in boulder mapping in Eastern Samar, Philippines, where recent supertyphoons Haiyan and Hagupit induced high waves, coastal flooding and boulder transport. It is demonstrated how satellite imagery of sub-metre resolution (from Pléiades and WorldView-3 imagery) enables efficient analysis of transport vectors and distances of larger boulders, reflecting variation in latitudes of both typhoon tracks and approaching angles of typhoon-generated waves. During the investigated events, boulders with a-axes of up to 8 m were clearly identified to have been shifted for up to 32 m, mostly along the seaward margin of the boulder field. It is, however, hard to keep track of smaller boulders, and the length of a-axes and b-axes including their orientation is often impossible to map with sufficient accuracy. Orthophotographs and digital surface models created through the application of an unmanned aerial vehicle and the ‘Structure from Motion’ technique provide ultra-high-resolution data, and have the potential to not only improve the results of satellite image analysis, but also those from field mapping and may significantly reduce overall time in the field. Orthophotographs permit unequivocal mapping of a-axes and b-axes including their orientation, while precise values for c-axes can be derived from the respective digital surface models. Volume of boulders is best inferred from boulder-specific Structure from Motion-based three-dimensional models. Battery power, flight speed and altitude determine the limits of the area covered, while patches shielded by the boulders are difficult to resolve. For some tasks, field mapping remains mandatory and cannot be replaced by currently available remote sensing tools: for example, sampling for rock type, density and age dating, recording of lithological separation of boulders from the underlying geological unit and of geomorphic features on a millimetre to decimetre-scale, or documentation of fine-grained sediment transport in between the boulders in supratidal settings. In terms of future events, the digital products presented here will provide a valuable reference to track boulder transport on a centimetre to decimetre-scale and to better understand the hydrodynamics of extreme-wave events on a fringing reef coastline.     

Carbon and hydrogen isotopic compositions of the NBS 22 and NBS 21 stable isotope reference materials: An inter-laboratory comparison

Measurement of 17 laboratories on the stable isotope reference materials, NBS 22 lubricating oil and NBS 21 graphite, resulted in a revised calibration on the PDB scale. NBS 22 ¹³C/¹²C ratios of all laboratories did not demonstrate a gausssian distribution. Therefore, values which resulted from direct comparison with NBS 20 carbonate standards were selected the mean value of which is $\text{?29.81 ± 0.06?}$; this value is recommended as new value for NBS 22. The reported variations in δ¹³C for NBS 21 were consistent within the accuracies for single meaurements; the mean value is ?28.16 ± 0.01. The variations of D/H ratios of NBS 22 also were consistent with the accuracy quoted, with a mean value of ?119?.     

Numerical Homogenization of the Rigidity Tensor in Hooke's Law Using the Node-Based Finite Element Method

Combining a geological model with a geomechanical model, it generally turns out that the geomechanical model is built from units that are at least a 100 times larger in volume than the units of the geological model. To counter this mismatch in scales, the geological data model's heterogeneous fine-scale Young's moduli and Poisson's ratios have to be “upscaled” to one “equivalent homogeneous” coarse-scale rigidity. This coarse-scale rigidity relates the volume-averaged displacement, strain, stress, and energy to each other, in such a way that the equilibrium equation, Hooke's law, and the energy equation preserve their fine-scale form on the coarse scale. Under the simplifying assumption of spatial periodicity of the heterogeneous fine-scale rigidity, homogenization theory can be applied. However, even then the spatial variability is generally so complex that exact solutions cannot be found. Therefore, numerical approximation methods have to be applied. Here the node-based finite element method for the displacement as primary variable has been used. Three numerical examples showing the upper bound character of this finite element method are presented.     

Late pleistocene sedimentation history of the Shirshov Ridge, Bering Sea

The analysis of the lithology, grain-size distribution, clay minerals, and geochemistry of Upper Pleistocene sediments from the submarine Shirshov Ridge (Bering Sea) showed that the main source area was the Yukon-Tanana terrane of Central Alaska. The sedimentary materials were transported by the Yukon River through Beringia up to the shelf break, where they were entrained by a strong northwestward-flowing sea current. The lithological data revealed several pulses of ice-rafted debris deposition, roughly synchronous with Heinrich events, and periods of weaker bottom-current intensity. Based on the geochemical results, we distinguished intervals of an increase in paleoproductivity and extension of the oxygen minimum zone. The results suggest that there were three stages of deposition driven by glacioeustatic sea-level fluctuations and glacial cycles in Alaska.