Assessment of the interstellar processes leading to deuterium enrichment in meteoritic organics

Abstract— The presence of isotopic anomalies is the most unequivocal demonstration that meteoritic material contains circumstellar or interstellar components. In the case of organic compounds in meteorites and interplanetary dust particles (IDPs), the most useful isotopic tracer has been deuterium (D). We discuss four processes that are expected to lead to D enrichment in interstellar materials and describe how their unique characteristics can be used to assess their relative importance for the organics in meteorites. These enrichment processes are low‐temperature gas phase ion‐molecule reactions, low‐temperature gas‐grain reactions, gas phase unimolecular photodissociation, and ultraviolet photolysis in D‐enriched ice mantles. Each of these processes is expected to be associated with distinct regiochemical signatures (D placement on the product molecules, correlation with specific chemical functionalities, etc.), especially in the molecular population of polycyclic aromatic hydrocarbons (PAHs). We describe these differences and discuss how they may be used to delineate the various interstellar processes that may have contributed to meteoritic D enrichments. We also briefly discuss how these processes may affect the isotopic distributions in C, O, and N in the same compounds.     

Ultraviolet spectroscopy of Asteroid (4) Vesta

We report a comprehensive review of the UV–visible spectrum and rotational lightcurve of Vesta combining new observations by Hubble Space Telescope and Swift Gamma-ray Burst Observatory with archival International Ultraviolet Explorer observations. The geometric albedos of Vesta from 220 nm to 953 nm are derived by carefully comparing these observations from various instruments at different times and observing geometries. Vesta has a rotationally averaged geometric albedo of 0.09 at 250 nm, 0.14 at 300 nm, 0.26 at 373 nm, 0.38 at 673 nm, and 0.30 at 950 nm. The linear spectral slope as measured between 240 and 320 nm in the ultraviolet displays a sharp minimum near a sub-Earth longitude of 20°, and maximum in the eastern hemisphere. This is consistent with the longitudinal distribution of the spectral slope in the visible wavelength. The photometric uncertainty in the ultraviolet is ∼20%, and in the visible wavelengths it is better than 10%. The amplitude of Vesta’s rotational lightcurves is ∼10% throughout the range of wavelengths we observed, but is smaller at 950 nm (∼6%) near the 1-μm band center. Contrary to earlier reports, we found no evidence for any difference between the phasing of the ultraviolet and visible/near-infrared lightcurves with respect to sub-Earth longitude. Vesta’s average spectrum between 220 and 950 nm can well be described by measured reflectance spectra of fine particle howardite-like materials of basaltic achondrite meteorites. Combining this with the in-phase behavior of the ultraviolet, visible, and near-infrared lightcurves, and the spectral slopes with respect to the rotational phase, we conclude that there is no global ultraviolet/visible reversal on Vesta. Consequently, this implies a lack of global space weathering on Vesta, as previously inferred from visible–near-infrared data.     

Speckle imaging of Titan at 2 microns: surface albedo, haze optical depth, and tropospheric clouds 1996-1998

We present results from 14 nights of observations of Titan in 1996-1998 using near-infrared (centered at 2.1 microns) speckle imaging at the 10-meter W.M. Keck Telescope. The observations have a spatial resolution of 0.06 arcseconds. We detect bright clouds on three days in October 1998, with a brightness about 0.5% of the brightness of Titan. Using a 16-stream radiative transfer model (DISORT) to model the central equatorial longitude of each image, we construct a suite of surface albedo models parameterized by the optical depth of Titan's hydrocarbon haze layer. From this we conclude that Titan's equatorial surface albedo has plausible values in the range of 0-0.20. Titan's minimum haze optical depth cannot be constrained from this modeling, but an upper limit of 0.3 at this wavelength range is found. More accurate determination of Titan's surface albedo and haze optical depth, especially at higher latitudes, will require a model that fully considers the 3-dimensional nature of Titan's atmosphere.     

Near-infrared laboratory spectra of solid H2O/CO2 and CH3OH/CO2 ice mixtures

We present near-IR spectra of solid CO₂ in H₂O and CH₃OH, and find they are significantly different from that of pure solid CO₂. Peaks not present in either pure H₂O or pure CO₂ spectra become evident when the two are mixed. First, the putative theoretically forbidden CO₂ (2ν₃) overtone near 2.134 μm (4685 cm⁻¹), that is absent from our spectrum of pure solid CO₂, is prominent in the spectra of H₂O/CO₂=5 and 25 mixtures. Second, a 2.74-μm (3650 cm⁻¹) dangling OH feature of H₂O (and a potentially related peak at 1.89 μm) appear in the spectra of CO₂-H₂O ice mixtures, but are probably not diagnostic of the presence of CO₂. Other CO₂ peaks display shifts in position and increased width because of intermolecular interactions with H₂O. Warming causes some peak positions and profiles in the spectrum of a H₂O/CO₂=5 mixture to take on the appearance of pure CO₂. Absolute strengths for absorptions of CO₂ in solid H₂O are estimated. Similar results are observed for CO₂ in solid CH₃OH. Since the CO₂ (2ν₃) overtone near 2.134 μm (4685 cm⁻¹) is not present in pure CO₂ but prominent in mixtures, it may be a good observational (spectral) indicator of whether solid CO₂ is a pure material or intimately mixed with other molecules. These observations may be applicable to Mars polar caps as well as outer Solar System bodies.     

The double inverse polarity paradigm

A model is presented for the origin of inverse polarity magnetic fields in the perpendicular as well as in the axial direction of quiescent prominences. The model is based on the presence of a discrete coronal arcade structure where magnetic separating surfaces can be identified. On the crossing of these separating surfaces magnetic reconnection driven by photospheric shear and converging motions can create the observed field direction in quiescent prominences.Dedicated to Cornelis de Jager     

Physics of solar prominences

Summary Conclusion This colloquium on solar prominences - the first ever held - has shown that a major part of activity in prominence research in recent years concentrated on both observation and computation of the magnetic conditions which were found to play a crucial role for the development and the maintainance of prominences. Remarkable progress was made in fine-scale measurements of photospheric magnetic fields around filaments and in internal field measurements in prominences. In addition, important information on the structure of the magnetic fields in the chromosphere adjacent to the filaments may be derived from high resolution photographs of the H fine structure around filaments which have become available recently; unfortunately, an unambiguous determination of the vector field in the chromosphere is not yet possible.It is quite clear, now, that stable filaments extend along neutral lines which divide regions of opposite longitudinal magnetic fields. Different types of neutral lines are possible, depending on the history and relationship of the opposite field regions. There is convincing evidence that the magnetic field in the neighbouring chromosphere may run nearly parallel to the filament axis and that there are two field components in stable prominences: an axial field dominant in the lower parts and a transverse field dominant in the higher parts.Methods for the computation of possible prominence field configurations from measured longitudinal photospheric fields were developed in recent years. In a number of cases (e.g. for loop prominences) the observed configuration could be perfectly represented by a force-free or even a potential field; poor agreement was found between computed and measured field strengths in quiescent prominences. In order to reconcile both of them it is necessary to assume electric currents. Unambiguous solutions will not be found until measurements of the vector field in the photosphere and in the prominences are available.The two-dimensional Kippenhahn-Schlüter model is still considered a useful tool for the study of prominence support and stability. However, a more refined model taking into account both field components and considering also thermal stability conditions is available now. It was proposed that quiescent prominences may form in magnetically neutral sheets in the corona where fields of opposite directions meet.As for the problem of the origin of the dense prominence material there are still two opposite processes under discussion. The injection of material from below, which was mainly applied to loop prominences, has recently been considered also a possible mechanism for the formation of quiescent prominences. On the other hand, the main objections against the condensation mechanism could be removed: it was shown that (1) sufficient material is available in the surrounding corona, and that (2) coronal matter can be condensed to prominence densities and cooled to prominence temperatures in a sufficiently short time.The energy balance in prominences is largely dependent on their fine structure. It seems that a much better radiative loss function for optically thin matter is now available. The problem of the heat conduction can only be treated properly if the field configuration is known. Very little is known on the heating of the corona and the prominence in a complicated field configuration. For the optically thick prominences the energy balance becomes a complicated radiative transfer problem.Still little is known on the first days of prominence development and on the mechanism of first formation which, both, are crucial for the unterstanding of the prominence phenomenon. As a first important step, it was shown in high resolution H photographs that the chromospheric fine structure becomes aligned along the direction of the neutral line already before first filament appearance. More H studies and magnetic field measurements are badly needed.Recent studies have shown that even in stable prominences strong small-scale internal rotational or helical motions exist; they are not yet understood. On the other hand, no generally agreed interpretation of large-scale motions of prominences seems to exist. A first attempt to explain the ascendance of prominences, the Disparitions Brusques, as the result of a kink instability was made recently.New opportunities in prominence research are offered by the study of invisible radiations: X-rays and meterwaves provide important information, not available otherwise, on physical conditions in the coronal surroundings of prominences; EUV observations will provide data on the thin transition layer between the cool prominence and the hot coronal plasma.Mitt. aus dem Fraunhofer Institut No. 111.     

Digital mapping of coastal boulders – high-resolution data acquisition to infer past and recent transport dynamics

Coastal boulder fields provide clues to long-term frequency-magnitude patterns of coastal flooding events and have the potential to play an important role in coastal hazard assessment. Mapping boulders in the field is time and labour-intensive, and work on intertidal reef platforms, as in the present study, is physically challenging. By addressing coastal scientists who are not specialists in remote sensing, this contribution reports on the possibilities and limitations of digital applications in boulder mapping in Eastern Samar, Philippines, where recent supertyphoons Haiyan and Hagupit induced high waves, coastal flooding and boulder transport. It is demonstrated how satellite imagery of sub-metre resolution (from Pléiades and WorldView-3 imagery) enables efficient analysis of transport vectors and distances of larger boulders, reflecting variation in latitudes of both typhoon tracks and approaching angles of typhoon-generated waves. During the investigated events, boulders with a-axes of up to 8 m were clearly identified to have been shifted for up to 32 m, mostly along the seaward margin of the boulder field. It is, however, hard to keep track of smaller boulders, and the length of a-axes and b-axes including their orientation is often impossible to map with sufficient accuracy. Orthophotographs and digital surface models created through the application of an unmanned aerial vehicle and the ‘Structure from Motion’ technique provide ultra-high-resolution data, and have the potential to not only improve the results of satellite image analysis, but also those from field mapping and may significantly reduce overall time in the field. Orthophotographs permit unequivocal mapping of a-axes and b-axes including their orientation, while precise values for c-axes can be derived from the respective digital surface models. Volume of boulders is best inferred from boulder-specific Structure from Motion-based three-dimensional models. Battery power, flight speed and altitude determine the limits of the area covered, while patches shielded by the boulders are difficult to resolve. For some tasks, field mapping remains mandatory and cannot be replaced by currently available remote sensing tools: for example, sampling for rock type, density and age dating, recording of lithological separation of boulders from the underlying geological unit and of geomorphic features on a millimetre to decimetre-scale, or documentation of fine-grained sediment transport in between the boulders in supratidal settings. In terms of future events, the digital products presented here will provide a valuable reference to track boulder transport on a centimetre to decimetre-scale and to better understand the hydrodynamics of extreme-wave events on a fringing reef coastline.     

Comet Halley's dust drag perturbing the Giotto spacecraft

Hypervelocity impact sputter causes impulses substantially greater than the initial momenta of micro-grains of comet Halley's dust coma, the effective factor being discontinuous at the dust mass (0.2 g) that just penetrates the spacecraft bumper shield. Marginally non-penetrating grains determine the net drag and torque, calculated here for the Giotto shield and exposed components. The torque due to asymmetries induces a precession of the spacecraft axis, whose amplitude is solved for passage through the model dust coma, to find slowly damped oscillations of significant (1°) amplitude.