A giant piston-corer

A new large piston-coring device utilizing well-casing pipe 14 cm (o.d.), 11 cm (i.d.) has obtained cores over 20 m in length in water depths of 100 to 5000 m. Recovery ratios range from 0·76 to 0·87. Penetration varies between 24 and 29 m with a total core weight of 3200–4000 kg and 2 to 3 m of free fall.     

Mercury transport in response to storm events from a northern forest landscape

Concentrations and fluxes of mercury (Hg) species in surface waters of forested watersheds are affected by hydrological events. The mechanisms of Hg transport during these events are poorly understood and yet may influence Hg bioavailability and exposure to aquatic biota. Three storm events with varying magnitude and intensity were investigated (June, September and November 2005) at a forested watershed in the Adirondack region of New York State, USA. Concentrations of Hg species increased during these events, both above and downstream of wetlands in the watershed. While Hg flux was higher from wetland drainage, the Hg flux from the upland site exhibited a greater relative increase to elevated runoff. Hg flux was controlled by discharge; however, Hg species concentrations were not well correlated with discharge, dissolved organic carbon (DOC), or total suspended solids (TSS) through the duration of events. A counter‐clockwise hysteresis response of DOC with increasing runoff contrasted with the clockwise response for total Hg, suggesting different contributions from source areas for these solutes. Correspondence with elevated total K and NO₃^? (α < 0·05) during the rising limb of the hydrograph suggests rapid delivery of throughfall Hg, potentially enhanced by hillslope hollows, to the stream channel. As the watershed saturated, stream Hg appears to be derived from the soil Hg pool. Results suggest that particulate Hg did not contribute substantially to total Hg flux during events (<25%). These results emphasize the role of watershed attributes and storm characteristics in Hg transport and bioavailability. Copyright © 2008 John Wiley & Sons, Ltd.     

Sources of nitrogen to estuaries in the United States

The purpose of this study was to quantify the nitrogen (N) inputs to 34 estuaries on the Atlantic and Gulf Coasts of the United States. Total nitrogen (TN) inputs ranged from 1 kg N ha⁻¹ yr⁻¹ for Upper Laguna Madre, Texas, to 49 kg N ha⁻¹ yr⁻¹ for Massachusetts Bay, Massachusetts. TN inputs to 11 of the 34 estuaries were dominated by urban N sources (point sources and septic systems) and nonpoint source N runoff (5% of total); point sources accounted for 36–86% of the TN inputs to these 11 urban-dominated estuaries. TN inputs to 20 of the 34 estuaries were dominated by agricultural N sources; N fertilization was the dominant source (46% of the total), followed by manure (32% of the total) and N fixation by crops (16% of the total). Atmospheric deposition (runoff from watershed plus direct deposition to the surface of the estuary) was the dominant N source for three estuaries (Barnegat Bay, New Jersey: 64%; St. Catherines-Sapelo, Georgia: 72%; and Barataria Bay, Louisiana: 53%). Six estuaries had atmospheric contributions ≥30% of the TN inputs (Casco Bay, Maine: 43%; Buzzards Bay, Massachusetts: 30%; Great Bay, New Jersey: 40%; Chesapeake Bay: 30%; Terrebonne-Timbalier Bay, Louisiana: 59%; and Upper Laguna Madre: 41%). Results from our study suggest that reductions in N loadings to estuaries should be accomplished by implementing watershed specific programs that target the dominant N sources.     

Formation of the Neoglacial surge moraines of the Klutlan Glacier,Yukon Territory,Canada

The Klutlan Glacier is a valley glacier 82-km long emerging from the Icefield Ranges of the St. Elias Mountains. It is one of at least 200 surging glaciers identified in western North America. During about the past 1200 yr, the glacier has deposited at its terminus a series of at least 7 surge-related Neoglacial ice-cored moraines. Lithologic characteristics of the Klutlan moraines suggest that they have resulted principally from the surging of the tributary Nesham Glacier, which periodically injects a lobe of medial and lateral moraines and the underlying ice into a more slowly moving Klutlan ice stream. Subsequent surges of the main ice carry the Nesham surge lobes to the Klutlan terminus as discrete geomorphic features. For the past 400 yr a Nesham lobe has reached the Klutlan terminus at approximately 80-yr intervals.     

Geological controls and effects of floodplain asymmetry on river–groundwater interactions in the southeastern Coastal Plain, USA

Channel sediment and alluvial aquifer hydraulic properties exert a major control on river–groundwater interactions. Channels and floodplains are often asymmetrical, resulting in differences in sediment hydraulic properties across the river. Floodplain asymmetry is common along Coastal Plain rivers in South Carolina and North Carolina, USA. The Tar River, North Carolina, has an asymmetrical valley. The study objective was to characterize the effects of floodplain asymmetry and geological controls on river–groundwater interactions. Floodplain and river channel sediments adjacent to the river were characterized with split spoon cores and hand auger samples along a 22-km reach. Hydrogeology was characterized with 38 piezometers and water level recorders in and adjacent to the river. Ground penetrating radar was used to define the shallow stratigraphy. Channel sediments were significantly different between the north and south sides of the river. Hydraulic conductivity and groundwater inputs were greater on the side of the river (north) that contained more permeable fluvial deposits. Groundwater chemistry (δ¹⁸O, specific conductance) data also suggested greater exchange between surface water and groundwater on the north side of the river channel. A conceptual hydrogeological model illustrates that groundwater movement and contaminant transport to the river differs across the channel due to asymmetrical geology.     

‘Acid rain’, dissolved aluminum and chemical weathering at the Hubbard Brook Experimental Forest,New Hampshire

Contemporary ‘acid rain’ in the Hubbard Brook ecosystem has induced a series of geochemical responses. Neutralization is accomplished in essentially a 2-step process. Initially, hydrogen ion acidity is neutralized by the dissolution of reactive alumina primarilly found in the soil zone. In the Hubbard Brook area this reactive alumina has solution properties much like natural gibbsite. Aluminum-rich surface waters with a pH of 4.7 5.2 are typical of this neutralization stage. In a second step, both hydrogen ion acidity and aluminum acidity are neutralized by the chemical weathering of primary silicate minerals, i.e. by the alkali and alkaline earths contained in the bedrock and glacial till of the watershed. The chemical weathering reaction is much slower than the alumina dissolution reaction, so that the aluminum acidity stage (pH 4.7 5.2) may persist for substantial periods. Typically, however, in the Hubbard Brook area the aluminum acidity has been neutralized and a pH > 5.2 is obtained before surface waters reach a third-over stream channel. Because of the relatively low pH's throughout the soil zone and in the streamwater, carbonic acid reactions are essentially absent at the present time in the Hubbard Brook system. Water pathlength (or residence time) in the soil zone is the crucial factor in the state of acid rain neutralization, aluminum chemistry and chemical weathering. As measured by the losses of alkali and alkaline earths from the ecosystem, chemical weathering rate in the Hubhard Brook area at the present time is not especially high relative to other areas.