Landscape influences on aluminium and dissolved organic carbon in streams draining the Hubbard Brook valley,New Hampshire,USA

Concentrations of both aluminium (Al) and dissolved organic carbon (DOC) in stream waters are likely to be regulated by factors that influence water flowpaths and residence times, and by the nature of the soil horizons through which waters flow. In order to investigate landscape‐scale spatial patterns in streamwater Al and DOC, we sampled seven streams draining the Hubbard Brook valley in central New Hampshire. We observed considerable variation in stream chemistry both within and between headwater watersheds. Across the valley, concentrations of total monomeric aluminium (Al_m) ranged from below detection limits (<0·7 µmol l⁻¹) to 22·3 µmol l⁻¹. In general, concentrations of Al_m decreased as pH increased downslope. There was a strong relationship between organic monomeric aluminium (Al_o) and DOC concentrations (R² = 0·92). We observed the highest Al_m concentrations in: (i) a watershed characterized by a steep narrow drainage basin and shallow soils and (ii) a watershed characterized by exceptionally deep forest floor soils and high concentrations of DOC. Forest floor depth and drainage area together explained much of the variation in ln Al_m (R² = 0·79; N = 45) and ln DOC (R² = 0·87; N = 45). Linear regression models were moderately successful in predicting ln Al_m and ln DOC in streams that were not included in model building. However, when back‐transformed, predicted DOC concentrations were as much as 72% adrift from observed DOC concentrations and Al_m concentrations were up to 51% off. This geographic approach to modelling Al and DOC is useful for general prediction, but for more detailed predictions, process‐level biogeochemical models are required. Copyright © 2005 John Wiley & Sons, Ltd.     

Device for finely resolved sampling of littoral lake regions: Design and operation

Although littoral regions in northern lakes may sustain fish spawning grounds, little is known of the temporal or spatial aspects of their thermal and chemical regimes. This shortcoming is due in part to the difficulty in properly sampling these regions throughout the year with adequate spatial resolution. This problem is especially critical in lakes affected by episodic acidification during the spring snowmelt, a period of substantial importance to fisheries recruitment. A device was constructed to alleviate the problems associated with conventional water quality sampling of littoral regions. Constructed of thick walled polyvinyl chloride and permanently installed in the nearshore regions of an Adirondack lake, the episodic event sampler (EES) provided finely resolved (0.25 m) temperature and water chemistry data during the spring snowmelt period (February to May) of 1989. Although the construction and installation of the sampler represented a significant investment in labour and materials, this was offset by the high quality of the data collected. As the samplers were relatively undamaged by freeze-thaw activity, it is expected that they will continue to provide excellent information for several years.     

Iceberg discharge to the Chukchi shelf during the Younger Dryas

The extent of glaciation in northwestern Alaska, the source of sediment supply to the Chukchi shelf and slope, and the movement of sea ice and icebergs across the shelf during the last glacial maximum (LGM) remain poorly constrained. Here we present geophysical and geological data from the outer Chukchi margin that reveal a regionally extensive, heavily ice-scoured surface ∼ 5-8 m below the modern seafloor. Radiocarbon dating of this discrete event yields age estimates between 10,600 and 11,900 ¹⁴C yr BP, indicating the discharge event occurred during the Younger Dryas. Based on mineralogy of the ice-rafted debris, the icebergs appear to be sourced from the northwestern Alaskan margin, which places important constraints on the ice extent in northern Alaska during the LGM as well as existing circulation models for the region.     

New evidence for high discharge to the Chukchi shelf since the Last Glacial Maximum

Using CHIRP subbottom profiling across the Chukchi shelf, offshore NW Alaska, we observed a large incised valley that measures tens of kilometers in width. The valley appears to have been repeatedly excavated during sea level lowering; however, the two most recent incisions appear to have been downcut during the last sea level rise, suggesting an increase in the volume of discharge. Modern drainage from the northwestern Alaskan margin is dominated by small, low-discharge rivers that do not appear to be large enough to have carved the offshore drainage. The renewed downcutting and incision during the deglaciation and consequent base level rise implies there must have been an additional source of discharge. Paleoprecipitation during deglaciation is predicted to be at least 10% less than modern precipitation and thus cannot account for the higher discharge to the shelf. Glacial meltwater is the most likely source for the increased discharge.     

TiO2 activity in metamorphosed pelitic and basic rocks: principles and applications to metamorphism in southeastern Canadian Cordillera

The activity of TiO₂ can be precisely defined as a function of pressure, temperature and activities of other components for common mineral assemblages in metapelites (ilmenite-quartz-garnet-plagioclase-Al₂SiO₅) and in metabasites (plagioclase-sphene-ilmenite-quartzgarnet). These mineral assemblages can be modelled by the equilibria: 1) 3ilmenite+Al₂SiO₅+2quartz=almandine+3TiO₂ 2) anorthite + 2sphene = grossular + 2TiO₂ + quartz 3) 3anorthite+3quartz+6ilmenite = grossular+ 6TiO₂+2almandine. These mineral assemblages can be used at (rutile saturation) and a given T to get maximum pressure limits of some metapelites and metabasites. When electron microprobe analyses of mineral grains adjacent to Ti-bearing phases are made, these data give maximum pressure estimates in reasonable agreement with other geobarometers. The activity of TiO₂ in many metapelites is very near rutile saturation, but for metabasites the activity of TiO₂ in some sillimanite zone rocks is as low as 0.6. The solubility of TiO₂ in biotite, hornblende and garnet is a complex function of T, P, the activities of components in coexisting minerals and crystal chemical constraints in these minerals. At a given P and T the solubility of TiO₂ in biotite and hornblende does not appear to be strongly dependent upon for sphene and ilmenite versus rutile-bearing assemblages.     

Abyssal current influence on the southwest Bermuda Rise and surrounding region

Echograms (3.5 kHz) and bottom photographs reveal that the northward flowing Antarctic Bottom Water (AABW) has strongly influenced the modern depositional regime on the southwest Bermuda Rise. The spatial distribution of echo character types, the orientation and nature of current-controlled structures, and limited current meter data show that AABW flows with varying intensities along three primary pathways around and over the southwest Bermuda Rise. The main core of AABW flows clockwise around the eastern and western flanks of the southern Bermuda Rise, roughly parallel to the 5400 m isobath. This current bifurcates at 28°30′N, 69°W where a portion flows northeast over the southwest Bermuda Rise and the remainder continues north along the physiographic boundary between the southwest Bermuda Rise and the Hatteras Abyssal Plain. Secondary ribbons of AABW branch off the main core of AABW during its southerly journey along the southeastern Bermuda Rise, and flow west through fracture zones. Finally, a diffuse, northward flowing AABW sweeps the entire southwest Bermuda Rise.

A progression of current-controlled bedforms occurs beneath the main path of the AABW reflecting the spatially varying current velocities and sediment supply. The main core of AABW flows west through the narrow Vema Gap creating erosional furrows along the border between the southwest Bermuda Rise and the Vema Gap. Current velocities greater than 20 cm s⁻¹ are inferred from the bedforms in this region. Farther north along the southwestern edge of the Bermuda Rise, sediment waves become more prevalent. This transition from erosional to more depositional bedforms results from diminished current velocities (5–15 cm s⁻¹) and increased sediment supply. Although some of these bedforms on the southwest Bermuda Rise appear to be relict, their orientation is consistent with current meter data and abyssal current direction inferred from bottom photographs.     

Origin of continental margin morphology: Submarine-slide or downslope current-controlled bedforms, a rock magnetic approach

Morphological features observed in both swath bathymetry and seismic reflection data are not unique, which introduces uncertainty as to their origin. The origin of features observed in the Humboldt Slide has generated much controversy because the same features have been interpreted as a submarine failure deposit versus current-controlled sediment waves. It is important to resolve this controversy because similar structures are observed on many continental margins and the origin of these features needs to be understood. Anisotropy of magnetic susceptibility (AMS) measurements on sediment samples acquired from the Humboldt Slide reveal that the top  8 m have not experienced post-depositional deformation. This suggests that these features are formed by primary deposition associated with downslope currents. Using the same AMS technique on a core acquired north of the Humboldt Slide in a region with no geophysical evidence for post-depositional deformation, we were able to identify a  1 m thick deposit that appears to be a small slump.     

Prey versus substrate as determinants of habitat choice in a feeding shorebird

Many shorebirds on their non-breeding grounds feed on macrobenthic fauna which become available at low tide in coastal intertidal flats. The Eastern Curlew Numenius madagascariensis in Moreton Bay Australia, varies greatly in density among different tidal flats. This study asks: how important is the abundance of intertidal prey as a predictor of this variation? We quantified feeding curlews’ diet across 12 sites (different tidal flats, each re-visited at least eight times), through 970 focal observations. We also estimated the abundance of total macrobenthic fauna, potential prey taxa and crustacean prey on each tidal flat; measured as the number of individuals and a relative biomass index per unit substrate surface area obtained from substrate core samples. We estimated curlew density at each site using low-tide surveys from every site visit.