3D shear-wave velocity structure of the Eifel plume, Germany

The Quaternary Eifel volcanic fields, situated on the Rhenish Massif in Germany, are the focus of a major interdisciplinary project. The aim is a detailed study of the crustal and mantle structure of the intraplate volcanic fields and their deep origin. Recent results from a teleseismic P-wave tomography study reveal a deep low-velocity structure which we infer to be a plume in the upper mantle underneath the volcanic area [J.R.R. Ritter et al., Earth Planet. Sci. Lett. 186 (2001) 7-14]. Here we present a travel-time investigation of 5038 teleseismic shear-wave arrivals in the same region. First, the transverse (T) and radial (R) component travel-time residuals are treated separately to identify possible effects of seismic anisotropy. A comparison of 2044 T- and 2994 R-component residuals demonstrates that anisotropy does not cause any first-order travel-time effects. The data sets reveal a deep-seated low-velocity anomaly beneath the volcanic region, causing a delay for teleseismic shear waves of about 3 s. Using 3773 combined R- and T-component residuals, an isotropic non-linear inversion is calculated. The tomographic images reveal a prominent S-wave velocity reduction in the upper mantle underneath the Eifel region. The anomaly extends down to at least 400 km depth. The velocity contrast to the surrounding mantle is depth-dependent (from −5% at 31-100 km depth to at least −1% at 400 km depth). At about 170-240 km depth the anomaly is nearly absent. The resolution of the data is sufficient to recover the described features, however the anomaly in the lower asthenosphere is underestimated due to smearing and damping. The main anomaly is similar to the P-wave model except the latter lacks the ‘hole’ near 200 km depth, and both are consistent with an upper mantle plume structure. For plausible anhydrous plume material in the uppermost 100 km of the mantle, an excess temperature as great as 200-300 K is estimated from the seismic anomaly. However, 1% partial melt reduces the required temperature anomaly to about 100 K. The temperature anomaly associated with the deeper part of the plume (250 to about 450 km depth) is at least 70 K. However, this estimate is quite uncertain, because the amplitude of the shear-wave anomaly may be larger than the modelled one. Another possibility is water in the upwelling material. The gap at 170-240 km depth could arise from an increase of the shear modulus caused by dehydration processes which would not affect P-wave velocities as much. An interaction of temperature and compositional variations, including melt and possibly water, makes it difficult to differentiate quantitatively between the causes of the deep-seated low-velocity anomaly.     

The BEAM-project: prediction and assessment of mixture toxicities in the aquatic environment

Freshwater and marine ecosystems are exposed to various multi-component mixtures of pollutants. Nevertheless, most ecotoxicological research and chemicals regulation focus on hazard and exposure assessment of individual substances only, the problem of chemical mixtures in the environment is ignored to a large extent. In contrast, the assessment of combination effects has a long tradition in pharmacology, where mixtures of chemicals are specifically designed to develop new products, e.g. human and veterinary drugs or agricultural and non-agricultural pesticides. In this area, two concepts are frequently used and are thought to describe fundamental relationships between single substance and mixture effects: Independent Action (Response Addition) and Concentration Addition. The question, to what extent these concepts may also be applied in an ecotoxicological and regulatory context may be considered a research topic of major importance, as the concepts would allow to make use of already existing single substance toxicity data for the predictive assessment of mixture toxicities. Two critical knowledge gaps are identified: (a) There is a lack of environmental realism, as a huge part of our current knowledge about the applicability of the concepts is restricted to artificial situations with respect to mixture composition or biological effect assessment. (b) The knowledge on what exactly is needed for using the concepts as tools for the predictive mixture toxicity assessment is insufficient. Both gaps seriously hamper the necessary, scientifically sound consideration of mixture toxicities in a regulatory context.In this paper, the two concepts will be briefly introduced, the necessity of considering the toxicities of chemical mixtures in the environment will be demonstrated and the applicability of Independent Action and Concentration Addition as tools for the prediction and assessment of mixture toxicities will be discussed. An overview of the specific aims and approaches of the BEAM project to fill in the identified knowledge gaps is given and first results are outlined.     

Microbial Degradation of Tar Oil Compounds under Different Redox Conditions

The microbial transformation of typical tar oil compounds such as acridine, benzo(b)thiophene, dibenzofuran, indane, and indene under different redox conditions was investigated in microcosm studies. Under aerobic conditions the inherent contamination in polluted soil as well as the added N‐, S‐, O‐ heterocyclic and homocyclic compounds were transformed predominantly apart from thiophene. 1‐Indanone was detected by RP‐HPLC‐DAD and GC‐MS as an intermediate metabolite from indane and indene. Under nitrate and sulfate reducing conditions indane, benzo(b)thiophene, and dibenzofuran were transformed in assays with the polluted soil samples from well B 65 and B 66 within 426 days, whereas they were persistent in assays with the highly polluted soil B 67. All heterocyclic and homocyclic compounds added to the non‐contaminated soil from well B 85 were not degraded under nitrate and sulfate reducing conditions, too. The results indicate that for the decision, wether natural attenuation can be implemented in the remediation of contaminated site, in addition to BTEX and PAHs especially the fate of further tar oil compounds in anoxic aquifers has to be considered.     

Pleistocene/Holocene climate change, re-establishment of fluvial drainage network and increase in relief in the Swiss Alps

ABSTRACT Data are presented about modern sediment discharge of the Swiss rivers and related to the size of catchments. The information reveals that the Central Alps have experienced denudation rates of ≈0.15 mm yr⁻¹ in the foreland, and ≈0.5 mm yr⁻¹ in the Alpine core. Mapping, however, indicates that modern erosion only affects 30–50% of the Alpine surface, and that fluvial and associated hillslope processes have focused erosion in 50–200-m-deep valleys. These valleys are incised into the glacial surface. If this limited spatial extent of erosion is considered, then effective erosion rates are significantly higher than average denudation rates. These effective rates equal or locally exceed modern rates of rock uplift. This implies that the modification of erosional processes related to the Pleistocene/Holocene climate change has resulted in an increase in the relief at a local scale. At a drainage basin scale, however, the relief appears not to change at present.     

Correlation of seismic activity and fumarole temperature at the Mt. Merapi volcano (Indonesia) in 2000

In this paper we present densely sampled fumarole temperature data, recorded continuously at a high-temperature fumarole of Mt. Merapi volcano (Indonesia). These temperature time series are correlated with continuous records of rainfall and seismic waveform data collected at the Indonesian–German multi-parameter monitoring network. The correlation analysis of fumarole temperature and precipitation data shows a clear influence of tropical rain events on fumarole temperature. In addition, there is some evidence that rainfall may influence seismicity rates, indicating interaction of meteoric water with the volcanic system. Knowledge about such interactions is important, as lava dome instabilities caused by heavy-precipitation events may result in pyroclastic flows. Apart from the strong external influences on fumarole temperature and seismicity rate, which may conceal smaller signals caused by volcanic degassing processes, the analysis of fumarole temperature and seismic data indicates a statistically significant correlation between a certain type of seismic activity and an increase in fumarole temperature. This certain type of seismic activity consists of a seismic cluster of several high-frequency transients and an ultra-long-period signal (<0.002 Hz), which are best observed using a broadband seismometer deployed at a distance of 600 m from the active lava dome. The corresponding change in fumarole temperature starts a few minutes after the ultra-long-period signal and simultaneously with the high-frequency seismic cluster. The change in fumarole temperature, an increase of 5 °C on average, resembles a smoothed step. Fifty-four occurrences of simultaneous high-frequency seismic cluster, ultra-long period signal and increase of fumarole temperature have been identified in the data set from August 2000 to January 2001. The observed signals appear to correspond to degassing processes in the summit region of Mt. Merapi.     

Effects of spatially structured vegetation patterns on hillslope erosion in a semiarid Mediterranean environment: a simulation study

A general trend of decreasing soil loss rates with increasing vegetation cover fraction is widely accepted. Field observations and experimental work, however, show that the form of the cover‐erosion function can vary considerably, in particular for low cover conditions that prevail on arid and semiarid hillslopes. In this paper the structured spatial distribution of the vegetation cover and associated soil attributes is proposed as one of the possible causes of variation in cover–erosion relationships, in particular in dryland environments where patchy vegetation covers are common. A simulation approach was used to test the hypothesis that hillslope discharge and soil loss could be affected by variation in the spatial correlation structure of coupled vegetation cover and soil patterns alone. The Limburg Soil Erosion Model (LISEM) was parameterized and verified for a small catchment with discontinuous vegetation cover at Rambla Honda, SE Spain. Using the same parameter sets LISEM was subsequently used to simulate water and sediment fluxes on 1 ha hypothetical hillslopes with simulated spatial distributions of vegetation and soil parameters. Storms of constant rainfall intensity in the range of 30–70 mm h^?1 and 10–30 min duration were applied. To quantify the effect of the spatial correlation structure of the vegetation and soil patterns, predicted discharge and soil loss rates from hillslopes with spatially structured distributions of vegetation and soil parameters were compared with those from hillslopes with spatially uniform distributions. The results showed that the spatial organization of bare and vegetated surfaces alone can have a substantial impact on predicted storm discharge and erosion. In general, water and sediment yields from hillslopes with spatially structured distributions of vegetation and soil parameters were greater than from identical hillslopes with spatially uniform distributions. Within a storm the effect of spatially structured vegetation and soil patterns was observed to be highly dynamic, and to depend on rainfall intensity and slope gradient. Copyright © 2005 John Wiley & Sons, Ltd.     

A size classification for debris flows

A 10-fold classification for debris flow size is proposed based on total volume, peak discharge and area inundated by debris. Size classes can be used for regional overview studies where detailed site investigations are either unnecessary, too costly or where the highest hazard and risk creeks need to be identified for further study. They are also useful to compare the regional impact between affected areas and the effects of rainstorms, and they allow lay-people to obtain an understanding of debris flow magnitude and consequences. Finally, different size classes allow the estimation of travel times to points of interest based on empirically derived equations. It is proposed that agencies concerned with debris flows should establish a documentation of debris flow size according to this classification, which serves as a data base for hazard and risk planning.     

Eocene-Pliocene time scale and stratigraphy of the Upper Rhine Graben (URG) and the Swiss Molasse Basin (SMB)

We present a general stratigraphic synthesis for the Upper Rhine Graben (URG) and the Swiss Molasse Basin (SMB) from Eocene to Pliocene times. The stratigraphic data were compiled both from literature and from research carried out by the authors during the past 6 years ; an index of the stratigraphically most important localitites is provided. We distinguish 14 geographical areas from the Helvetic domain in the South to the Hanau Basin in the North. For each geographical area, we give a synthesis of the biostratigraphy, lithofacies, and chronostratigraphic ranges. The relationships between this stratigraphic record and the global sea-level changes are generally disturbed by the geodynamic (e.g., subsidence) evolution of the basins. However, global sea-level changes probably affected the dynamic of transgression–regression in the URG (e.g., Middle Pechelbronn Beds and Serie Grise corresponding with sea-level rise between Ru1/Ru2 and Ru2/Ru3 sequences, respectively) as well as in the Molasse basin (regression of the UMM corresponding with the sea-level drop at the Ch1 sequence). The URGENT-project (Upper Rhine Graben evolution and neotectonics) provided an unique opportunity to carry out and present this synthesis. Discussions with scientists addressing sedimentology, tectonics, geophysics and geochemistry permitted the comparison of the sedimentary history and stratigraphy of the basin with processes controlling its geodynamic evolution. Data presented here back up the palaeogeographic reconstructions presented in a companion paper by the same authors (see Berger et al. in Int J Earth Sci 2005).     

Molecular formulae of marine and terrigenous dissolved organic matter detected by electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry

The chemical structure of refractory marine dissolved organic matter (DOM) is still largely unknown. Electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR-MS) was used to resolve the complex mixtures of DOM and provide valuable information on elemental compositions on a molecular scale. We characterized and compared DOM from two sharply contrasting aquatic environments, algal-derived DOM from the Weddell Sea (Antarctica) and terrigenous DOM from pore water of a tropical mangrove area in northern Brazil. Several thousand molecular formulas in the mass range of 300-600 Da were identified and reproduced in element ratio plots. On the basis of molecular elemental composition and double-bond equivalents (DBE) we calculated an average composition for marine DOM. O/C ratios in the marine samples were lower (0.36 ± 0.01) than in the mangrove pore-water sample (0.42). A small proportion of chemical formulas with higher molecular mass in the marine samples were characterized by very low O/C and H/C ratios probably reflecting amphiphilic properties. The average number of unsaturations in the marine samples was surprisingly high (DBE = 9.9; mangrove pore water: DBE = 9.4) most likely due to a significant contribution of carbonyl carbon. There was no significant difference in elemental composition between surface and deep-water DOM in the Weddell Sea. Although there were some molecules with unique marine elemental composition, there was a conspicuous degree of similarity between the terrigenous and algal-derived end members. Approximately one third of the molecular formulas were present in all marine as well as in the mangrove samples. We infer that different forms of microbial degradation ultimately lead to similar structural features that are intrinsically refractory, independent of the source of the organic matter and the environmental conditions where degradation took place.