Reliability of Relative Paleointensity Recorded in Chinese Loess–Paleosol Sediments

A detailed paleomagnetic and rock-magnetic investigation spanning loess L7 to paleosol S8 has been carried out at the Baoji and Xifeng sections. Results of anisotropy of magnetic susceptibility confirm that the studied loess–paleosol sediments retain primary sedimentary fabrics. Stepwise thermal demagnetization shows that two well-defined magnetization components can be isolated from both loess and paleosol specimens. A low-temperature component, isolated between 100°C and 200°C, is consistent with the present geomagnetic field direction, and a high-temperature component, isolated between 200–300°C and 620–680°C, includes clearly normal and reversed polarities. Isothermal remanent magnetization and thermomagnetic analyses indicate that characteristic remanent magnetization is mainly carried by magnetite and hematite. The Day plot, together with the stratigraphic variations of rock-magnetic parameters, shows that the uniformity of magnetic mineralogy and grain size fulfills the criteria for relative paleointensity (RPI) studies. RPI records have been constructed using natural remanent magnetization (NRM) intensity after thermal demagnetization at 300°C normalized by low-frequency magnetic susceptibility (NRM300/χ). The results show that the RPI record from the Baoji section, where pedogenesis is quite weak, is compatible with the stacked PISO-1500 paleointensity record, suggesting that it might reflect the paleointensity variation of the geomagnetic field. The RPI record from the Xifeng section, where pedogenesis is rather strong, indicates a clear dissimilarity with the stacked PISO-1500 paleointensity record, implying that it does not reflect the paleointensity variation of the geomagnetic field. Our new results show that the NRM300/χ from the strongly pedogenetic paleosols does not completely eliminate the pedogenetic (climatic) influence, so it might be unsuitable for a reliable paleointensity study.     

Structural changes of synthetic opal by heat treatment

The structural changes of synthetic opal by heat treatment up to 1,400 °C were investigated using scanning electron microscopy, X-ray diffraction, and Fourier transform infrared and Raman spectroscopies. The results indicate that the dehydration and condensation of silanol in opal are very important factors in the structural evolution of heat-treated synthetic opal. Synthetic opal releases water molecules and silanols by heat treatment up to 400 °C, where the dehydration of silanol may lead to the condensation of a new Si–O–Si network comprising a four-membered ring structure of SiO₄ tetrahedra, even at 400 °C. Above 600 °C, water molecules are lost and the opal surface and internal silanol molecules are completely dehydrated by heat effect, and the medium-temperature range structure of opal may begin to thermally reconstruct to six-membered rings of SiO₄ tetrahedra. Above 1,000 °C, the opal structure almost approaches that of silica glass with an average structure of six-membered rings. Above 1,200 °C, the opal changes to low-cristobalite; however, minor evidence of low-tridymite stacking was evident after heat treatment at 1,400 °C.     

Impacts of elevated CO2 on particulate and dissolved organic matter production: microcosm experiments using iron-deficient plankton communities in open subarctic waters

Response of phytoplankton to increasing CO₂ in seawater in terms of physiology and ecology is key to predicting changes in marine ecosystems. However, responses of natural plankton communities especially in the open ocean to higher CO₂ levels have not been fully examined. We conducted CO₂ manipulation experiments in the Bering Sea and the central subarctic Pacific, known as high nutrient and low chlorophyll regions, in summer 2007 to investigate the response of organic matter production in iron-deficient plankton communities to CO₂ increases. During the 14-day incubations of surface waters with natural plankton assemblages in microcosms under multiple pCO₂ levels, the dynamics of particulate organic carbon (POC) and nitrogen (PN), and dissolved organic carbon (DOC) and phosphorus (DOP) were examined with the plankton community compositions. In the Bering site, net production of POC, PN, and DOP relative to net chlorophyll-a production decreased with increasing pCO₂. While net produced POC:PN did not show any CO₂-related variations, net produced DOC:DOP increased with increasing pCO₂. On the other hand, no apparent trends for these parameters were observed in the Pacific site. The contrasting results observed were probably due to the different plankton community compositions between the two sites, with plankton biomass dominated by large-sized diatoms in the Bering Sea versus ultra-eukaryotes in the Pacific Ocean. We conclude that the quantity and quality of the production of particulate and dissolved organic matter may be altered under future elevated CO₂ environments in some iron-deficient ecosystems, while the impacts may be negligible in some systems.     

Evaluation of the structural damage of high‐rise reinforced concrete buildings using ambient vibrations recorded before and after damage

Evaluation of the degrees of structural damage suffered by high‐rise residential buildings after being subjected to strong ground motions is extremely important to the development of life continuity planning for building residents. However, these evaluations cannot be based on strong‐motion records alone, because earthquake observation equipment is not installed in most such buildings in Japan. In this study, we propose simple equations for estimating the stiffness degradation rate and the peak inter‐story drift ratio (PIDR) by using ambient vibration records instead of strong‐motion records when high‐rise RC buildings are subjected to a severe earthquake. More specifically, we propose one equation that relates the square root of the stiffness degradation rate, which is the ratio of natural frequencies at the maximum response to the preliminary tremor response (elastic state), in strong‐motion records with the ratio of natural frequencies identified from ambient vibrations before and after damage was suffered. We also propose an equation that relates the PIDR with the stiffness degradation rate on the basis of the stiffness‐degrading bilinear restoring force characteristic derived from the strong‐motion records of 13 high‐rise buildings for the 1995 Hyogoken‐Nanbu Earthquake (Mw 6.9) and the 2011 Tohoku‐Oki Earthquake (Mw 9.0). Copyright © 2015 John Wiley & Sons, Ltd.     

Impact of land uses on heavy metal distribution in the Selenga River system in Mongolia

The Selenga River contributes to 50% of the total inflow to Lake Baikal. Large tracts of the Selenga River Basin have been developed for industry, urbanization, mining, and agriculture, resulting in the release of suspended solids (SS) that affect downstream water quality and primary productivity. This study addressed SS as the main factor controlling pollutant transport and the primary indicator of land degradation in the Selenga River system. Tributaries with larger areas dedicated to agricultural use had higher SS concentrations, reaching 862 mg L^?1, especially during the high runoff and intensive cultivation season. Although the large SS flux was detected in the main river, the small tributaries were distinguished by high SS concentrations. The high SS concentration corresponded to widespread development in the watershed. Watersheds with high potential of SS release are sensitive to intensive land uses. SS in the river system had a constant elemental composition consisting mainly of Fe and Al oxides, indicating that surface soils were major constituents of the tributary SS. Three minor heavy metals (Zn, Cu, and Cr) appeared in high concentrations downstream of urban and mining areas (two- to sixfold increases), indicating that these contaminants are carried by SS. At two tributary junctions, the concentration of contaminants on the SS decreased due to a large influx of SS with low heavy metal contents. Changes in electric conductivity and pH at downstream of tributary junctions enhanced the sedimentation of SS and the removal of contaminants from the water phase after aggregation of the SS. Land use changes in the tributary watersheds are major controlling factors for the fate of contaminants in the river system.     

The ultra-low-frequency magnetic disturbances associated with earthquakes

The ultra-low-frequency (ULF) electromagnetic emission is recently recognized as one of the most promising candidates for short-term earthquake (EQ) prediction. This paper reviews previous convincing evidence on the presence of ULF emissions before three major EQs. Then, we present further statistical study on the ULF occurrence, our networks of ULF monitoring in different spatial scales in Japan and finally we present several signal processings to identify the seismogenic emissions by showing latest results for recent large EQs.     

Aluminum in the East China Sea and Okinawa Trough, marginal sea areas of the Western North Pacific

The distribution of aluminum (Al) in seawater has been investigated in the continental slope and the Okinawa Trough areas of the East China Sea, which is one of the marginal seas in the western North Pacific Ocean. Aluminum concentration in waters over the slope and the Trough ranged from 5.6 to 25 nmol/kg in the surface layer (0–100 m), and had a minima of 1.1 nmol/kg between 400 and 500 m depth and ranged from 1.3 to 9.7 nmol/kg in the deep or bottom waters. Aluminum values were higher than in the surface waters of the central North Pacific, while minimum values were similar to levels in the intermediate or deep waters of the central North Pacific, except for the bottom water over the slope. This suggests that the high Al concentration in the surface reflects the large atmospheric input of Asian dust around the western side of the North Pacific region. On the continental slope, Al concentrations in the upper 500 m depth decreased slopeward. This horizontal gradient of Al can be explained from the combination of dilution by upwelling of Al-poor water originated from the North Pacific Intermediate Water (NPIW) which intrudes into the mid-depth of the Okinawa Trough and the scavenging of Al by biogenic particles in the continental slope zone.     

宝鸡古土壤层S7和黄土层L8的天然剩磁锁定深度初探

详细的古地磁及岩石磁学研究表明磁铁矿和赤铁矿是宝鸡古土壤层S7和黄土层L8的特征剩磁的主要载磁矿物,在稳定的正反极性期间,这两种磁性矿物携带的剩磁方向完全一致.然而,在地磁漂移事件或者松山-布容(M-B)极性转换的过程中,这两种载磁矿物有时携带的剩磁方向不同.高分辨率的磁性地层结果证实宝鸡古土壤层S7和黄土层L8能记录300～500年的短期地球磁场极性倒转事件.经与日本大阪湾高分辨率的海洋沉积物中记录的同期短期极性倒转事件相比,估算宝鸡剖面土壤层S7和黄土层L8的天然剩磁锁定深度小于5～8 cm.     

Mid- and far-infrared extinction coefficients of hydrous silicate minerals

Extinction coefficients were measured for three kind of hydrous silicate minerals, montmorillonite, chlorite and serpentine, from 7 to 140 m. The infrared extinction coefficients of these minerals show (1) a few broad bands in the mid-infrared region and (2) a less steep wavelength-dependence in the far-infrared region, in contrast to those of high-temperature magnesium silicates. In the far-infrared region, montmorillonite shows a ^–0.8±0.1 dependence (, the wavelength) without any band structure, chlorite has a double maxima structure around 80 m, and serpentine shows a rather steep dependence with a small peak at 77 m.The changes of mid-infrared spectra by heating were measured. Change in chlorite spectrum is the most significant. Many fine features appear by heating and then they disappear. Above 900°C one broad feature remains around 10 m. Fine features of the montmorillonite spectrum disappear by heating. For serpentine, many new peaks appear and the spectrum resembles the spectrum of olivin. In near-infrared a band around 2.72 m disappears by heating.Extinction coefficients at very low temperatures were measured in the far-infrared region. For montmorillonite and serpentine, the spectrum is the same as that at room temperature. The double peaks of chlorite around 80 m become higher.     

The role of the grain boundary at chemical and isotopic fronts in marble during contact metamorphism

Carbon and oxygen isotopic profiles around a low pressure metasomatic wollastonite reaction front in a marble of the Hida metamorphic terrain, central Japan, display typical metamorphic fluid-enhanced isotopic zonations. Isotopic profiles obtained from detailed microscale analyses perpendicular to the chemical reaction front in calcite marble show that diffusion-enhanced isotopic exchange may control these profiles. Carbon and oxygen isotopic behaviour in grain boundaries is remarkably different. Oxygen isotopic troughs (¹⁸O depleted rims) around the calcite-grain boundaries are widely observed in this contact aureole, demonstrating that diffusion of oxygen in calcite grain boundary dominates over lattice diffusion in calcite. In contrast, no difference is observed in carbon isotopic profiles obtained from grain cores and rims. There is thus no specific role of the grain boundary for diffusion of carbonic species in the metamorphic fluid during transportation. Carbon chemical species such as CO₂ and CO₃ ions in metamorphic fluid migrate mainly through lattice diffusion. The carbon and oxygen isotope profiles may be modelled by diffusion into a semi-infinite medium. Empirically lattice diffusion of oxygen isotopes is almost six times faster than that of carbon isotopes, and oxygen grain-boundary diffusion is ten times faster than oxygen lattice diffusion. Oxygen isotopic results around the wollastonite vein indicate that migration of the metamorphic fluid into calcite marble was small and was parallel to the aquifer. From the stability of wollastonite and the attainment of oxygen isotopic equilibrium, we suggest that diffusion of oxygen occurred through an aqueous fluid phase. The timescale of formation of the oxygen isotopic profile around the wollastonite vein is calculated to be about 0.76 × 10⁶ years using the experimentally determined diffusion constant. Received: 14 January 1997 / Accepted: 23 April 1998