40Ar/39Ar age of material returned from asteroid 25143 Itokawa

The Hayabusa mission to asteroid 25143, Itokawa, brought back 2000 small particles, which most closely resemble material found in LL4‐6 chondrites. We report an ⁴⁰Ar/³⁹Ar age of 1.3 ± 0.3 Ga for a sample of Itokawa consisting of three grains with a total mass of ~2 μg. This age is lower than the >4.0 Ga ages measured for 75% of LL chondrites but close to one for Y‐790964 and its pairs. The flat ⁴⁰Ar/³⁹Ar release spectrum of the sample suggests complete degassing 1.3 Ga ago. Recent solar heating in Itokawa's current orbit does not appear likely to have reset that age. Solar or impact heating 1.3 Ga ago could have done so. If impact heating was responsible, then the 1.3 Ga age sets an upper bound on the time at which the Itokawa rubble pile was assembled and suggests that rubble pile creation was an ongoing process in the inner solar system for at least the first 3 billion years of solar system history.     

Middle Permian cephalopods from central Peninsular Malaysia: implications for faunal migration through the southern Tethys

A Wordian (Middle Permian) cephalopod fauna consisting of four ammonoid species, Tauroceras aff. scrobiculatum (Gemmellaro), Agathiceras sp., Bamyaniceras orientale n. sp. and Pronoritidae gen. and sp. indet., and two nautiloid species, Tainoceras sp. and Orthocerida fam. indet., were recovered from the Bera South area, southern Pahang, Peninsular Malaysia. The outcrop represents the southernmost extent of the Bera Formation. Bamyaniceras and Tainoceras are recorded in Malaysia for the first time. The presence of T. aff. scrobiculatum suggests a regional correlation with an ammonoid-bearing bed of Sungai Cheroh, western Pahang, and permits global correlations with strata of northeastern Iraq, northern Oman and Sicily (Italy). A possible eastwards faunal migration through the southern Tethys is suggested.     

Diversity of Pliocene mysticetes from eastern Japan

Abstract Assemblages of Early Pliocene Mysticeti (Cetacea) from the Sendai-Iwate and Choshi areas in eastern Japan were examined. The early Early Pliocene Tatsunokuchi and Yushima formations of the Sendai-Iwate area have yielded many cetotheres assigned to Herpetocetus (Cetotheriidae) and some extinct rorquals assigned to Burtinopsis (Balaenopteridae) and other genera. The late Early Pliocene strata of the Na-arai Formation of the Choshi area has yielded more than 300 mysticete ear bones which fall into seven morphotypes. Assemblages from the two areas differ greatly in taxonomic composition. Archaic mysticetes are dominant in the Sendai-Iwate area, while modern mysticetes are dominant and diverse in the Choshi area. Based on the results of this study we conclude that the diversity of the Early Pliocene mysticetes in the western North Pacific is comparable to that of the Recent.     

A list of fossil cetaceans in Japan

Abstract Fossil cetacea of Japan are abundant and diverse. Despite several summary articles, all the known taxa have not previously been compiled in one place. Here we present a list of the published fossil cetacean records from the Japanese archipelago. The record extends from Middle or Late Oligocene to the Holocene, and includes representatives of both the suborders Odontoceti and Mysticeti. No Eocene Cetacea or Archaeoceti are recorded from Japan. As is typical of the eastern North Pacific and the South Pacific, the Oligocene and Early Miocene assemblages are comprised of archaic and usually extinct families, and the younger assemblages are represented by modern groups comprised of extant genera and families.     

Early Permian ammonoids from the Kaeng Krachan Group of the Phatthalung-Hat Yai area, southern peninsular Thailand

An Early Permian small ammonoid fauna consisting of Neocrimites sp., Agathiceras suessi Gemmellaro, A. girtyi Böse, Agathiceras? sp., and Miklukhoceras sp. was found in nodules of a fine sandstone bed exposed in the Phatthalung-Hat Yai area of southern peninsular Thailand. The ammonoid-bearing bed belongs stratigraphically to the uppermost part of the Kaeng Krachan Group, which is essentially a clastic-dominant, Late Carboniferous (?) to Early Permian stratigraphic unit, widely distributed in western and peninsular Thailand. This ammonoid fauna is considered to be of Bolorian (Kungurian) age and includes Agathiceras girtyi Böse, which is described for the first time from Thailand. The present discovery of Bolorian ammonoids suggests that the uppermost part of the Kaeng Krachan Group is slightly younger than previously considered and around the latest Early Permian. This further implies that the continental margin environment of the Sibumasu Block drastically changed at around Bolorian time from a cool, clastic-dominant shelf condition to a temperate to subtropical, carbonate platform due to rapid northward drift after middle Artinskian rifting.     

Gradients and phase velocities of ULF geomagnetic disturbances used to determine the source of an impending strong earthquake

Results of studying the behavior of the vectors of gradients and phase velocities of ULF geomagnetic disturbances (F < 1 Hz) in the Japan seismic zone are presented. The gradient and phase velocity vectors along the Earth’s surface were determined using data of the group of three high-sensitivity three-component magnetovariation stations (MVC-3DS) located at triangle vertices at a small (～5 km) distance from one another (magnetic gradiometer). Two such groups of stations were installed in 1999 southwest and southeast of Tokyo at a distance of ～150 km from each other. It has been indicated that, several months before strong earthquakes (M > 5), the values of gradients and phase velocities start anomalously changing, and directions toward sources of impending strong earthquakes appear in the distribution of gradient vector directions. Directions from sources of impending earthquakes appear in the distribution of phase velocity vector directions. It is proposed to use gradients and phase velocities of ULF and ELF geomagnetic disturbances as one of the factors in a short-term prediction of strong earthquakes.     

Body waveform inversion for the source process of the February 3, 1996 Lijiang, Yunnan earthquake

The source process of February 3, 1996 Lijiang earthquake in Yunnan was studied by body waveform inversion using teleseismic data from IRIS. Two normal double-couple subevents with different strikes were obtained. The difference of the onset time between these two subevents, which are 15 km apart in space, is 7 s. The total seismic moment is 3.81 × 10¹⁸ Nm (M _w=6.3). The total fault area S is about 720 km² from the aftershock data and the average dislocation is about ū=0.18 m. Considering both the result of inversion and tectonic environment around the source, the first rupture might result from the extension along the NNW directed Zhongdian-Yongsheng fault belt where an earthquake of M=6.4 occurred in 1966. Then, the second started along the NE directed the eastern foot of Snow Mountain fault where rupture seemed to be able to propagate more easily.     

Nonaqueous titration of functional groups in humic acid

Humic acid was titrated by sodium methoxide in dimethylsulfoxide using platinum-calomel electrode systems. Adding benzoic acid and phenol as internal standards to humic acid yielded two inflections. The titer at the first inflection point was equivalent to the carboxyl groups whose pK_a (H₂O) values were less than 7. The difference between the titers at the two inflection points was equivalent to the phenolic hydroxyl groups whose pK_a (H₂O) values were 7–10. Calculated results for the carboxyl and phenolic hydroxyl groups in humic acid obtained by the nonaqueous titration method agreed closely with those obtained by conventional methods.