Pyroclastic flows in Japan

Bulletin of Volcanology -     

On Structure and Temporal Variation of the Bifurcation Current off the Kii Peninsula

The Kii Bifurcation Current is often found along the southwest coast of the Kii Peninsula, and its frequency of occurrence reaches about 70% in the period from 1988 to 1996 (Takeuchi et al., 1998a). In order to clarify the structure and short-period variability of the Kii Bifurcation Current, detailed observations were made four times on board the R/V Seisui-maru of Mie University on October 29–31, 1996, on June 24–26, 1997, October 14–16, 1997, and December 3–4, 1997. The measured horizontal structure of the Kii Bifurcation Current indicates that the eastern portion of the Current (eastward flow near Cape Shionomisaki) consists of a part of the current zone of the Kuroshio. It is shown that the current structure, including the Kii Bifurcation Current in the vicinity of Cape Shionomisaki, is stable when the Kuroshio is flowing in a stationary straight path, but that the current structure is considerably changed when small-scale eddies pass by the cape. Such short-period variation can be monitored by using the daily variation of the sea level difference between Kushimoto and Uragami. In particular, in the case of October 29–31, 1996, when an eminent small-scale eddy passed by Cape Shionomisaki, and when the Kuroshio axis tentatively moved southwards about 50 km apart from the coast, the Kii Bifurcation Current seems to have disappeared.     

The international at-sea intercomparison of fCO2 systems during the R/V Meteor Cruise 36/1 in the North Atlantic Ocean

The ‘International Intercomparison Exercise of fCO₂ Systems’ was carried out in 1996 during the R/V Meteor Cruise 36/1 from Bermuda/UK to Gran Canaria/Spain. Nine groups from six countries (Australia, Denmark, France, Germany, Japan, USA) participated in this exercise, bringing together 15 participants with seven underway fugacity of carbon dioxide (fCO₂) systems, one discrete fCO₂ system, and two underway pH systems, as well as systems for discrete measurement of total alkalinity and total dissolved inorganic carbon. Here, we compare surface seawater fCO₂ measured synchronously by all participating instruments. A common infrastructure (seawater and calibration gas supply), different quality checks (performance of calibration procedures for CO₂, temperature measurements) and a common procedure for calculation of final fCO₂ were provided to reduce the largest possible amount of controllable sources of error. The results show that under such conditions underway measurements of the fCO₂ in surface seawater and overlying air can be made to a high degree of agreement (±1 μatm) with a variety of possible equilibrator and system designs. Also, discrete fCO₂ measurements can be made in good agreement (±3 μatm) with underway fCO₂ data sets. However, even well-designed systems, which are operated without any obvious sign of malfunction, can show significant differences of the order of 10 μatm. Based on our results, no “best choice” for the type of the equilibrator nor specifics on its dimensions and flow rates of seawater and air can be made in regard to the achievable accuracy of the fCO₂ system. Measurements of equilibrator temperature do not seem to be made with the required accuracy resulting in significant errors in fCO₂ results. Calculation of fCO₂ from high-quality total dissolved inorganic carbon (C_T) and total alkalinity (A_T) measurements does not yield results comparable in accuracy and precision to fCO₂ measurements.     

Microplastics in the Southern Ocean

A field survey to collect microplastics with sizes < 5 mm was conducted in the Southern Ocean in 2016. We performed five net-tows and collected 44 pieces of plastic. Total particle counts of the entire water column, which is free of vertical mixing, were computed using the surface concentration (particle count per unit seawater volume) of microplastics, wind speed, and significant wave height during the observation period. Total particle counts at two stations near Antarctica were estimated to be in the order of 100,000 pieces km^? 2.     

Processes controlling cobalt distribution in two temperate estuaries,Sagami Bay and Wakasa Bay,Japan

Concentrations of cobalt (Co) in surface waters from the Sagami River to northern Sagami Bay and from the Yura River to southwestern Wakasa Bay in Japan were determined in order to investigate the factors governing the distribution of this metal during estuarine mixing. Dissolved (<0.2 μm) and particulate (>0.2 μm) Co showed non-conservative mixing behavior with low or mid-salinity maxima within those two estuarine regions, indicating benthic remobilization and/or sewage input apart from riverine input during the estuarine mixing. These results are supported by a suite of complementary measurements of other parameters, such as manganese, phosphate, and suspended particulate matter concentrations. In addition, the concentration ratio of dissolved Co to total Co (dissolved plus particulate) increased along the salinity gradient, implying the potential for desorption of this metal from suspended particulate matter on estuarine mixing.     

High organic carbon deposition in the northern margin of the Aleutian Basin (Bering Sea) before the last deglaciation

High-resolution geochemical, isotope and elemental data from core PC23A in the northern margin of the Aleutian Basin (Bering Sea) were used to reconstruct distinct paleoceanographic features of the last deglaciation (pre-Boreal[PB], Bølling-Allerød[BA], Younger Dryas[YD]). The PB and BA intervals are characterized by increased siliceous (diatom) and calcareous (coccolithophores and foraminifers) productivity represented by high biogenic opal and CaCO₃ contents, respectively. The enhanced productivity can plausibly be attributed to an elevated sea-surface nutrient supply from increased melt-water input and enhanced Alaskan Stream injection under warm, restricted sea-ice conditions. High C_org/N ratios and low δ¹³C values of sediment organic matter during the PB and BA intervals reflect the contribution of terrestrial organic matters. The PB and BA intervals were also identified by laminated sediment layers of core PC23A, characterized by high Mo/Al and Cd/Al ratios, indicating that the bottom water condition remained anoxic. High δ¹⁵N values during the same period were attributed mainly to the increased nutrient utilization and subsequent denitrification of seawater nitrate. Part of high δ¹⁵N values may also be due to incorporation of inorganic nitrogen in the clay minerals. It is worthy of note that high total organic carbon (TOC) deposition occurred approximately 3,000 years before onset of the last deglaciation. Simultaneous high C_org/N ratios and low δ¹³C values clearly suggest that the high TOC content should be related to terrestrial organic carbon input. Low δ¹⁵N values during the high TOC interval also confirm the contribution of terrigenous organic matter. Although abundant calcareous phytoplankton production under cold, nutrient-poor conditions represented by Baex data was reported for high TOC deposition preceding the last deglaciation in an earlier study of the Okhotsk Sea, the main reason for the enhanced TOC deposition in the Bering Sea is an increased terrigenous input from the submerged continental shelves (Beringia) with a sea-level rise; this is further supported by Al enrichment of bulk sediments during the high TOC deposition.     

Stable Carbon and Nitrogen Isotopic Characterization of Organic Matter in a Mangrove Ecosystem on the Southwestern Coast of Thailand

Organic matter in a tropical mangrove ecosystem was characterized by stable carbon and nitrogen isotopic analyze, conducted on various organic samples, including land and mangrove plants, soils, particulate organic matter (POM), and sea and river sediments along the southwestern coast of Thailand. The δ¹³C values of land plants and POM in river water can be explained in terms of a greater influence of C₃ plants than C₄ plants in this area. The POM and sediments from the Trang River and Ko Talibong area showed systematically higher δ¹⁵N values than those from Ko Muk and other coastal areas. Organic matter in the Trang River might be influenced by nitrogen released from agricultural or human waste, which could affect the isotopic composition of POM and sediments in the Trang River estuary and along the coast near the river mouth. We used a stochastic method to estimate the contributions of four organic end-members, identifiable by their δ¹³C and δ¹⁵N values. The results implied that seagrasses were a major source of sedimentary organic matter, contributing 42 ± 5% in the Ko Muk area and 36 ± 5% in the Ko Talibong area. The contribution of coastal POM to sediments was estimated to be only 13% in Ko Muk and 19% in Ko Talibong. Mangrove plants contributed approximately 23% in both areas. It was concluded that seagrasses are an important source of sedimentary organic matter in this coastal region of southwestern Thailand. This revised version was published online in August 2006 with corrections to the Cover Date.     

A 27-kyr record of environmental change in central Asia inferred from the sediment record of Lake Hovsgol,northwest Mongolia

Geochemistry of a sediment core from Lake Hovsgol, northwest Mongolia provides a continuous, 27-kyr history of the response of the lake and the surrounding catchment to climate change. Principle component (PC) analysis of 19 major and trace elements, total inorganic carbon (TIC), and total organic carbon (TOC) in the bulk sediment samples revealed that the 21 chemical components can be grouped into four assemblages—group-1: Na, Mg, Ca, Sr, and TIC, hosted in carbonate minerals (calcite, dolomite, and magnesian calcite); group-2: Ni, Cu, and Zn, recognized as biophilic trace metals, and TOC; group-3: Al, K, Ti, V, Fe, Rb, Cs, Ba, and Pb, composed of rock-forming minerals; and group-4: Cr, Mn, and As, sensitive to the redox condition of the sediment. The four element assemblages originated from three relevant processes. Group-1 and group-2 components are authigenic products and comprise the end member on the PC-1 score, whose variation reflects changes in the water volume, i.e. the balance between precipitation and evaporation (P/E). Group-3 components from detrital materials of the catchment contribute to the PC-2 score, whose variability indicates erosion/weathering intensity in the drainage basin, which might be controlled by the amount of vegetation cover associated with moisture change. The group-4 components of redox-sensitive elements contribute to the PC-3 score and are not an end member because of their small amount. The first two PC scores suggest a sequential record of paleo-moisture evolution in central Asia. The P/E balance in the Lake Hovsgol region, inferred from the PC-1 score, gradually increased during the glacial/interglacial transition. This resembles climate change of the North Atlantic region on the glacial–interglacial scale, but does not reflect the abrupt climate shifts such as the warm Bølling-Allerød and the cold Younger Dryas of the North Atlantic on the millennial scale. A periodic variation of ~8.7 kyr was observed in the PC-2 score profile of detrital input to Lake Hovsgol over the last glacial and Holocene. The decrease in detrital input coincided with the copious supply of moisture from the Asian monsoon regime and the North Atlantic westerly winds to the Baikal drainage basin, which includes Lake Hovsgol. Our geochemical records from Lake Hovsgol demonstrate that the climate system of interior continental Asia was strongly influenced by change on both Milankovitch and sub-Milankovitch scales.     

Implications of a non-adiabatic density gradient for the Earth's viscoelastic response to surface loading

The response of a viscoelastic Earth to the melting of the Late Pleistocene ice sheets has been the subject of a number of investigations employing PREM. In PREM, a non-adiabatic density gradient (NADG) exists in the upper mantle, and to understand the implications of this model it is thus important to examine the effects of this NADG on the Earth's response to surface loads. This paper is based on the assumption that the contribution to the depth dependence of the density that is not due to self-compression is due to compositional change. This contribution is referred to as 'non-adiabatic'. We evaluate the effects of a non-adiabatic density jump (NADJ) for the 670  km discontinuity and the NADG in the upper mantle by adopting a compressible earth model with both a compositional density gradient and a density jump. Numerical calculations based on these models indicate that the magnitude of the Earth's response associated with the NADG is much smaller than that associated with the NADJ at 670  km depth. It is also confirmed that the higher modes associated with the NADJ and the NADG are much more sensitive to the existence of an elastic lithosphere than the fundamental modes associated with the density jumps at the surface and core–mantle boundary.     

The sea surface temperature product algorithm of the Ocean Color and Temperature Scanner (OCTS) and its accuracy

The Ocean Color and Temperature Scanner (OCTS) aboard the Advanced Earth Observing Satellite (ADEOS) can observe ocean color and sea surface temperature (SST) simultaneously. This paper explains the algorithm for the OCTS SST product in the NASDA OCTS mission. In the development of the latest, third version (V3) algorithm, the OCTS match-up dataset plays an important role, especially when the coefficients required in the MCSST equation are derived and the equation form is adjusted. As a result of the validation using the OCTS match-up dataset, the algorithm has improved the root mean square (rms) error of the OCTS SST up to 0.698°C although some problems remain in the match-up dataset used in the present study.