A study of the composition of the lower solar corona

Some trends in the composition of the lower solar corona due to mixing and diffusion have been examined. Mixing has been treated through plausible inference from the thermal gradient and through analogy with the neutral atmosphere of the earth. These indicate that diffusion may be important in the lower corona. Changes in composition due to pressure and thermal gradients have been calculated with multi-component diffusion equations. Results indicate that (i) large enhancements of heavy elements are possible and (ii) the composition of the corona can show large variations with values of the thermal gradient in the lower corona.     

Exsolved garnet-bearing pyroxene megacrysts from some South African kimberlites

Clinopyroxene and orthopyroxene megacrysts containing garnet lamellae up to 1.2 mm thick as an exsolved phase are found rarely in kimberlites from Frank Smith and Bellsbank. Chemically the clinopyroxenes are characteristically subcalcic, being within the range of 100 Ca/Ca + Mg + Fe = 27 to 36, and the orthopyroxenes are characterized by high Al₂O₃ and Cr₂O₃. Immediately after crystallization during very slow cooling, clinopyroxene and orthopyroxene exsolve wide-spaced orthopyroxene and clinopyroxene phases parallel to (100) of the host phases, respectively, then both host and exsolved phases exsolve garnet lamellae. Topotactic relations between pyroxenes and garnet are determined by X-ray for the first time. Partitioning of major and minor elements among the coexisting clinopyroxene, orthopyroxene and garnet in pyroxene megacrysts is the same as that of the granular-type garnet peridotite xenoliths in Lesotho and South African kimberlies. Mineralogy and chemistry indicate that subcalcic clinopyroxene and orthopyroxene megacrysts contain respectively about 10 and 3 mole % of the garnet molecule in solid solution.     

Variations in seawater osmium isotope composition since the last glacial maximum: A case study from the Japan Sea

Concentrations of Re and Os, and the isotopic composition of Os have been measured in the Japan Sea sediments to assess the response of the Japan Sea to glacial–interglacial climate change and associated weathering fluxes. The osmium concentrations in the sediment samples analyzed vary from 59 to 371 pg/g, and ¹⁸⁷Os/¹⁸⁸Os from 0.935 to 1.042. Only ¹⁸⁷Os/¹⁸⁸Os of sediment samples from dark laminations deposited under suboxic to anoxic conditions and having elevated concentrations of Re and Os, and with ≥ 80% hydrogenous Os are explained in terms of seawater composition. Lower ¹⁸⁷Os/¹⁸⁸Os were observed for sediments deposited during the last glacial maximum (LGM) when planktonic foraminifera from the Japan Sea recorded lighter oxygen isotopic composition. Decrease in dissolved Os fluxes from continents and/or change in the composition of the dissolved load to the Japan Sea are suggested as the driving mechanisms for the observed lower LGM ¹⁸⁷Os/¹⁸⁸Os. The results of this study, coupled with lower ¹⁸⁷Os/¹⁸⁸Os during the last glacial observed at other sites from ocean basins with different lithology and contrasting sediment accumulation rates, suggest that this trend is characteristic of the global oceans.

Data from this study show that the Japan Sea recorded higher ¹⁸⁷Os/¹⁸⁸Os during the current interglacial coinciding with excursions of oxygen isotopic compositions of planktonic foraminifera to heavier values. This is explained in terms of preferential release of ¹⁸⁷Os during deglacial weathering and/or higher continental Os flux driven by warm and wet climate. This study demonstrates that Os isotopic composition of reducing margin sediments has immense potential to track variations in the seawater composition. In addition, ¹⁸⁷Os/¹⁸⁸Os of reducing sediments may be used to draw inferences about local paleoceanographic processes in semi-enclosed basins such as the Japan Sea.     

On coronal Fe abundances and temperatures from XUV emission lines

Data obtained by the OSO-7 spectroheliograph on strong XUV lines of five, different Fe ions from the outer equatorial corona are presented. Interpretation of the data with a spherically symmetric model atmosphere gives average ion abundances for lines of sight at 0.3R from the limb. Fe xvi is usually more abundant than Fe xv, xiv, xii and ix, but there are times when Fe xii is more abundant than the other ions. The deviation of measured relative abundances of Fe xii, xiv, and xvi from predictions of ionization equilibrium at one temperature seems to indicate that there are appreciable temperature variations along lines of sight. Element abundances are very uncertain since they appear to depend so heavily on likely but unknown density irregularities along lines of sight.     

Trapping of rare gases during the condensation of solids

Rare gas trapping during crystallization from vapor phases of (1) CdTe, (2) Zn, (3) Mg and (4) Fe₃O₄ has been studied. Samples were deposited as very fine crystals (about several hundred angströms) in ambient Ar atmospheres of various pressures. It was found that the amount of Ar trapped in the samples was proportional to the ambient Ar pressure. Stepheating degassing of the crystals showed that Ar was rather loosely trapped and released at relatively low temperatures. However, on a simple mechanical compaction of the crystal powder the retentivity of Ar was considerably enhanced.     

Axial and equatorial rotations of the Earth's cores associated with the Quaternary ice age

The differential axial and equatorial rotations of both cores associated with the Quaternary glacial cycles were evaluated based on a realistic earth model in density and elastic structures. The rheological model is composed of compressible Maxwell viscoelastic mantle, inviscid outer core and incompressible Maxwell viscoelastic inner core. The present study is, however, preliminary because I assume a rigid rotation for the fluid outer core. In models with no frictional torques at the boundaries of the outer core, the maximum magnitude of the predicted axial rotations of the outer and inner cores amounts to ∼2° year⁻¹ and ∼1° year⁻¹, respectively, but that for the secular equatorial rotations of both cores is ∼0.0001° at most. However, oscillating parts with a period of ∼225 years are predicted in the equatorial rotations for both cores. Then, I evaluated the differential rotations by adopting a time-dependent electromagnetic (EM) torque as a possible coupling mechanism at the core-mantle boundary (CMB) and inner core boundary (ICB). In a realistic radial magnetic field at the CMB estimated from surface magnetic field, the axial and equatorial rotations couple through frictional torques at the CMB, although these rotations decouple for dipole magnetic field model. The differential rotations were evaluated for conductivity models with a conductance of 10⁸ S of the lowermost mantle inferred from studies of nutation and precession of the Earth and decadal variations of length of day (LOD). The secular parts of equatorial rotations are less sensitive to these parameters, but the magnitude for the axial rotations is much smaller than for frictionless model. These models, however, produce oscillating parts in the equatorial rotations of both cores and also in the axial rotations of the whole Earth and outer and inner cores. These oscillations are sensitive to both the magnitude of radial magnetic field at the CMB and the conductivity structure. No sharp isolated spectral peaks are predicted for models with a thin conductive layer (∼200 m) at the bottom of the mantle. In models with a conductive layer of ∼100 km thickness, however, sharp spectral peaks are predicted at periods of ∼225 and ∼25 years for equatorial and axial rotations, respectively, although these depend on the strength of radial magnetic field at the CMB. While the present study is preliminary in modelling the fluid outer core and coupling mechanism at the CMB, the predicted axial rotations of the whole Earth may be important in explaining the observed LOD through interaction between the equatorial and axial rotations.     

Detailed paleoseismic history of the Hinagu fault zone revealed by the high-density radiocarbon dating and trenching survey across a surface rupture of the 2016 Kumamoto earthquake,Kyushu, Japan

The NE-trending Hinagu fault zone, length 81 km, is one of the major active faults in Kyushu, Japan. From north to south, it is divided into three segments based on geomorphic features and paleoseismic behavior: the Takano-Shirahata, Hinagu, and Yatsushiro Sea segments. The 2016 Kumamoto earthquake produced a 6-km-long surface rupture with a dextral strike-slip displacement on the northern part of the Takano-Shirahata segment. Surface rupture, a faint east-side-up flexure with a vertical offset of less than 8 cm, was observed near the middle of the Takano-Shirahata segment. To examine past surface-rupturing earthquakes on the Takano-Shirahata segment, including rupture frequency and timing, we conducted a paleoseismic study with boring and trenching at Yamaide. A trench across the surface rupture exposed multiple fault strands associated with multiple surface-rupturing events that deformed several strata of fine-grained sediments. By structural and stratigraphic interpretation, high-density radiocarbon dating and tephra analysis, and Bayesian modeling, we constrained the timing of seven events, Events 1–7, to 0.84–1.25, 1.31–7.06, 9.99–11.0, 10.8–12.1, 12.0–13.0, 14.2–15.1, and before 14.8 kcal BP. Slip during Events 1–6 was obviously larger than the 2016 slip. The estimated average recurrence interval was about 2596–2860 years, but the interval between Events 2 and 3 was much longer than other intervals. Moreover, the vertical throw associated with Event 2 was larger than that of other events. This implies that the Takano-Shirahata segment has a period with rare larger earthquakes and a period with frequent smaller earthquakes. Some events might have produced ruptures on both the Takano-Shirahata and the northern part of the Hinagu segments simultaneously or in a short time. The variety of recurrence intervals suggests that the seismic activity has been affected by one or both activities of the Futagawa fault zone and the Hinagu segment.     

Numerical simulation of organic chemicals in a marine environment using a coupled 3D hydrodynamic and ecotoxicological model

For ecotoxicological risk assessment in a marine ecosystem, we constructed a coupled three-dimensional hydrodynamic and ecotoxicological model (EMT-3D), and applied it to Tokyo Bay. The model was calibrated with field data obtained in 2002. The results of sensitivity analysis for dissolved Bisphenol A showed that biodegradation rate was the most important factor for concentration change. Bioconcentration coefficient was the most important factor for Bisphenol A in phytoplankton. Therefore, the parameters must be carefully considered in the modeling. The mass balance results showed that standing stocks of Bisphenol A in water, in particulate organic carbon and in phytoplankton are 7.85 x 10(4), 1.78 x 10(2) and 3.44 x 10(-1) g, respectively. With respect to flux, biodegradation in the water column had the highest value of 1.06 x 10(3) g/day, and next were effluent to the open sea, partition to particulate organic carbon, and bioconcentration in phytoplankton.