Phase diagrams describing solid-gas equilibria in the system Fe-Mg-Si-O-C-H,and its bearing on redox states of chondrites

Abstract— Phase diagrams describing solid-gas equilibria in the system Fe-Mg-Si-O-C-H under H-rich conditions (～700–2000 K and 10^?2–10^?20 atm of Ph ₂), including solar nebula conditions, were constructed based on thermochemical calculations. Boundaries of vaporous phases, which are the first phases to condense from a gas, can be obtained without calculating condensation temperatures of individual gas compositions because the numbers of major gaseous species are the same as those of components in the concerned systems. Fractionations by condensation and/or evaporation can be discussed easily in such phase diagrams. A thermal divide, which is a barrier that vapors cannot cross by a single cooling process, was recognized in the phase diagrams. This is present on the Fe-MgO-SiO₂-CO-H plane at high temperatures (≥500–700 K) and plays an important role in fractionations. Oxidizing states of ordinary chondrites and carbonaceous chondrites before aqueous alteration are located at the O-rich side of the thermal divide. Such oxidizing states can be formed from the solar gas by fractionation in the primordial solar nebula because the solar composition is located on the O-rich side. On the other hand, the reducing states of enstatite chondrites, located at the O-poor side, cannot be formed as long as the thermal divide is present. The reducing states can be obtained by CO to CH₄ molecular reaction at low temperatures (≤500–700 K), where the high-temperature thermal divide is absent. Addition of H₂O-rich and CH₄-rich ice can explain establishment of the redox states of ordinary and enstatite chondrites, respectively.     

The escape of ionizing photons from supernova-dominated primordial galaxies

In order to assess the contribution of Lyman break galaxies (LBGs) and Lyman α emitters (LAEs) at redshifts  3 < z < 7  to the ionization of intergalactic medium (IGM), we investigate the escape fractions of ionizing photons from supernova-dominated primordial galaxies by solving the three-dimensional (3D) radiative transfer. The model galaxy is employed from an ultra-high-resolution chemodynamic simulation of a primordial galaxy by Mori & Umemura, which well reproduces the observed properties of LAEs and LBGs. The total mass of model galaxy is  10¹¹ M_⊙  . We solve not only photoionization but also collisional ionization by shocks. In addition, according to the chemical enrichment, we incorporate the effect of dust extinction, taking the size distributions of dust into account. As a result, we find that dust extinction reduces the escape fractions by a factor of 1.5–8.5 in the LAE phase and by a factor of 2.5–11 in the LBG phase, while the collisional ionization by shocks increases the escape fractions by a factor of  ≈2  . The resultant escape fractions are 0.07–0.47 in the LAE phase and 0.06–0.17 in the LBG phase. These results are well concordant with the recent estimations derived from the flux density ratio at 1500 to 900 Å of LAEs and LBGs. Combining the resultant escape fractions with the luminosity functions of LAEs and LBGs, we find that high- z LAEs and LBGs can ionize the IGM at   z = 3–5  . However, ionizing radiation from LAEs as well as LBGs falls short of ionizing the IGM at   z > 6  . That implies that additional ionization sources may be required at   z > 6  .     

MicroRaman spectroscopy of anomalous planar microstructures in quartz from Mt. Oikeyama: Discovery of a probable impact crater in Japan

Abstract– Planar deformation features (PDFs) and planar fractures (PFs) have been found and confirmed by optical microscope observations and microRaman spectroscopy in quartz grains from Mt. Oikeyama (Akaishi Mountains, Central Japan), for which the semicircular topographic feature of the ridge suggests a crater formed by an impact event. According to the optical microscope observations, a low shock pressure (8–10 GPa) is estimated by the occurrence of basal or ω PDFs leading to lack of multiple sets of PDFs. In addition, a new type of planar microstructure was found in several quartz grains. The microRaman characteristics of PDFs in quartz from Mt. Oikeyama show the amorphous state indicating the presence of weak broad bands at 400 and 800 cm^?1 peak positions. These characteristics are indicative of PDFs that are limited to shocked quartz. This indicates an impact origin for distinct planar microstructures in quartz from Mt. Oikeyama.     

Experimental study on the bidirectional inelastic deformation capacity of U‐shaped steel dampers for seismic isolated buildings

Hysteretic dampers are used to dissipate earthquake‐induced energy in base‐isolated structures by acquiring inelastic deformations, rendering their hysteretic behavior of vital importance. The present paper focuses on investigating the behavior of U‐shaped steel dampers under bidirectional loading; this is significantly different from their corresponding uniaxial behavior. Two main sets of loading tests on full‐scale specimens are conducted in this regard: (i) quasi‐static tests with simple histories and (ii) dynamic tests with realistic loading histories. Based on the results obtained in the quasi‐static tests, an interaction curve that accounts for the reduction of the cyclic deformation capacity is proposed. However, the fidelity of this relation must be assessed under loading conditions similar to those of a seismically isolated structure subjected to an earthquake, which represents the goal of the second set of tests. The results of the dynamic tests validate the proposed interaction curve for estimating the deformation capacity of U‐shaped steel dampers under bidirectional loading. Copyright © 2015 John Wiley & Sons, Ltd.     

Effect of ocean acidification on coastal phytoplankton composition and accompanying organic nitrogen production

The effect of ocean acidification, caused by the increase in pCO₂ in seawater, on phytoplankton population and on related organic nitrogen production was experimentally examined by use of a natural coastal microbial population. pCO₂ and pH were controlled by aeration with air in which pCO₂ was at the current level (control), for which ambient air was used, and with air in which pCO₂ was ??800?? and ??1200?? ppm, in 500-L culture vessels. The experiment was continued for 15?days after addition of the inorganic nutrients such as nitrate, phosphate, and silicate. During most of the experimental period, a minor increase in phytoplankton biomass was noted, probably because of low irradiance, an increase in phytoplankton biomass was observed at the end of the experiment. Flow cytometric and microscopic observations revealed that this increase was because of Chrysochromulina sp. (Haptophyceae). The growth of Chrysochromulina sp. was most obvious in the control vessel, and tended to be obscured by increasing pCO₂ (decrease in pH), indicating the possibility that ocean acidification inhibits the growth of specific phytoplankton groups, for example Chrysochromulina sp. Production of particulate organic nitrogen (PON), determined by the ¹⁵N tracer method, also diminished under acidified conditions compared with that at the current level.     

Intermittent generation of mafic enclaves in the 1991–1995 dacite of Unzen Volcano recorded in mineral chemistry

Mafic enclaves in the 1991–1995 dacite of Unzen volcano show chemical and textural variability, such as bulk SiO₂ contents ranging from 52 to 62 wt% and fine- to coarse-grained microlite textures. In this paper, we investigated the mineral chemistry of plagioclase and hornblende microlites and distinguished three enclave types. Type-I mafic enclaves contain high-Mg plagioclase and low-Cl hornblende as microlites, whereas type-III enclaves include low-Mg plagioclase and high-Cl hornblende. Type-II enclaves have an intermediate mineral chemistry. Type-I mafic enclaves tend to show a finer-grained matrix, have slightly higher bulk rock SiO₂ contents (56–60 wt%) when compared with the type-III mafic enclaves (SiO₂?=?53–59 wt%), but the overall bulk enclave compositions are within the trend of the basalt–dacite eruptive products of Quaternary monogenetic volcanoes around Unzen volcano. The origin of the variation of mineral chemistry in mafic enclaves is interpreted to reflect different degree of diffusion-controlled re-equilibration of minerals in a low-temperature mushy dacitic magma reservoir. Mafic enclaves with a long residence time in the dacitic magma reservoir, whose constituent minerals were annealed at low-temperature to be in equililbrium with the rhyolitic melt, represent type-III enclaves. In contrast, type-I mafic enclaves result from recent mafic injections with a mineral assemblage that still retains the high-temperature mineral chemistry. Taking temperature, Ca/(Ca?+?Na) ratio of plagioclase, and water activity of the hydrous Unzen magma into account, the Mg contents of plagioclase indicate that plagioclase microlites in type-III enclaves initially crystallized at high temperature and were subsequently re-equilibrated at low-temperature conditions. Compositional profiles of Mg in plagioclase suggest that older mafic enclaves (Type-III) had a residence time of ~100 years at 800 °C in a stagnant magma reservoir before their incorporation into the mixed dacite of the 1991–1995 Unzen eruption. Presence of different types of mafic enclaves suggests that the 1991–1995 dacite of Unzen volcano tapped mushy magma reservoir intermittently replenished by high-temperature mafic magmas.     

Evolution of Mount Fuji,Japan: Inference from drilling into the subaerial oldest volcano,pre‐Komitake

A buried, old volcanic body (pre‐Komitake Volcano) was discovered during drilling into the northeastern flank of Mount Fuji. The pre‐Komitake Volcano is characterized by hornblende‐bearing andesite and dacite, in contrast to the porphyritic basaltic rocks of Komitake Volcano and to the olivine‐bearing basaltic rocks of Fuji Volcano. K‐Ar age determinations and geological analysis of drilling cores suggest that the pre‐Komitake Volcano began with effusion of basaltic lava flows around 260 ka and ended with explosive eruptions of basaltic andesite and dacite magma around 160 ka. After deposition of a thin soil layer on the pre‐Komitake volcanic rocks, successive effusions of lava flows occurred at Komitake Volcano until 100 ka. Explosive eruptions of Fuji Volcano followed shortly after the activity of Komitake. The long‐term eruption rate of about 3 km³/ka or more for Fuji Volcano is much higher than that estimated for pre‐Komitake and Komitake. The chemical variation within Fuji Volcano, represented by an increase in incompatible elements at nearly constant SiO₂, differs from that within pre‐Komitake and other volcanoes in the northern Izu‐Bonin arc, where incompatible elements increase with increasing SiO₂. These changes in the volcanism in Mount Fuji may have occurred due to a change in regional tectonics around 150 ka, although this remains unproven.     

A precise bathymetric map of the world’s deepest seafloor,Challenger Deep in the Mariana Trench

Data from three bathymetric surveys by R/V Kairei using a 12-kHz multibeam echosounder and differential GPS were used to create an improved topographic model of the Challenger Deep in the southwestern part of the Mariana Trench, which is known as the deepest seafloor in the world. The strike of most of the elongated structures related to plate bending accompanied by subduction of the Pacific plate is N70°E and is not parallel to the trench axis. The bending-related structures were formed by reactivation of seafloor spreading fabric. Challenger Deep consists of three en echelon depressions along the trench axis, each of which is 6–10 km long, about 2 km wide, and deeper than 10,850 m. The eastern depression is the deepest, with a depth of 10,920 ± 5 m.