Europium anomaly variation under low-temperature water-rock interaction: A new thermometer

The positive europium (Eu) anomaly, enrichment of Eu abundance relative to the neighboring elements, is often observed for water interacted with the rocks. Not only high temperature (~400°C) water-rock interaction such as seafloor hydrothermal fluids, but also relatively lower temperature interaction, less than 100°C, cause positive Eu anomaly. However, relationship between the degree of Eu anomaly and interaction temperature has not been investigated. Water-rock interaction experiments at three different reaction temperatures were performed in this study to reveal the cause of positive Eu anomaly. Comparison of the results under different solution chemistry and temperature conditions showed that the basalt containing plagioclase released larger abundances of REEs than the basaltic glass. The degree of Eu anomaly assessed by Eu/Eu* value was smaller when 0.7 M NaCl solution was used for liquid phase for both solid phases. On the other hand, the Eu/Eu* became larger with increasing reaction temperature for basalts interacted with ultra-pure water. Therefore, it is suggested that the Eu anomaly is potentially used as a fluid-rock interaction thermometer under low salinity condition.     

Implications of a non-adiabatic density gradient for the Earth's viscoelastic response to surface loading

The response of a viscoelastic Earth to the melting of the Late Pleistocene ice sheets has been the subject of a number of investigations employing PREM. In PREM, a non-adiabatic density gradient (NADG) exists in the upper mantle, and to understand the implications of this model it is thus important to examine the effects of this NADG on the Earth's response to surface loads. This paper is based on the assumption that the contribution to the depth dependence of the density that is not due to self-compression is due to compositional change. This contribution is referred to as 'non-adiabatic'. We evaluate the effects of a non-adiabatic density jump (NADJ) for the 670  km discontinuity and the NADG in the upper mantle by adopting a compressible earth model with both a compositional density gradient and a density jump. Numerical calculations based on these models indicate that the magnitude of the Earth's response associated with the NADG is much smaller than that associated with the NADJ at 670  km depth. It is also confirmed that the higher modes associated with the NADJ and the NADG are much more sensitive to the existence of an elastic lithosphere than the fundamental modes associated with the density jumps at the surface and core–mantle boundary.     

Boron isotopic composition of fumarolic condensates from some volcanoes in Japanese island arcs

Boron samples from 40 fumarolic condensates from volcanoes in the Ryukyu arc (Satsuma Iwo-jima and Shiratori Iwo-yama) and the North-east Japan arc (Usu-shinzan, Showa-shinzan, Esan and Issaikyo-yama) all have ${}^{11}\text{B}{}^{10}\text{B}$ ratios close to 4.07. Higher values, from 4.09 to 4.13, were only observed in condensates from volcanoes in the southernmost end of the North-east Japan arc (Nasu-dake), the northern part of the Izu-Bonin arc (Hakone), and the North Mariana arc (Ogasawara Iwo-jima). These higher values suggest geological interaction of the magmas with sea-water enriched in ¹¹B.     

A 27-kyr record of environmental change in central Asia inferred from the sediment record of Lake Hovsgol,northwest Mongolia

Geochemistry of a sediment core from Lake Hovsgol, northwest Mongolia provides a continuous, 27-kyr history of the response of the lake and the surrounding catchment to climate change. Principle component (PC) analysis of 19 major and trace elements, total inorganic carbon (TIC), and total organic carbon (TOC) in the bulk sediment samples revealed that the 21 chemical components can be grouped into four assemblages—group-1: Na, Mg, Ca, Sr, and TIC, hosted in carbonate minerals (calcite, dolomite, and magnesian calcite); group-2: Ni, Cu, and Zn, recognized as biophilic trace metals, and TOC; group-3: Al, K, Ti, V, Fe, Rb, Cs, Ba, and Pb, composed of rock-forming minerals; and group-4: Cr, Mn, and As, sensitive to the redox condition of the sediment. The four element assemblages originated from three relevant processes. Group-1 and group-2 components are authigenic products and comprise the end member on the PC-1 score, whose variation reflects changes in the water volume, i.e. the balance between precipitation and evaporation (P/E). Group-3 components from detrital materials of the catchment contribute to the PC-2 score, whose variability indicates erosion/weathering intensity in the drainage basin, which might be controlled by the amount of vegetation cover associated with moisture change. The group-4 components of redox-sensitive elements contribute to the PC-3 score and are not an end member because of their small amount. The first two PC scores suggest a sequential record of paleo-moisture evolution in central Asia. The P/E balance in the Lake Hovsgol region, inferred from the PC-1 score, gradually increased during the glacial/interglacial transition. This resembles climate change of the North Atlantic region on the glacial–interglacial scale, but does not reflect the abrupt climate shifts such as the warm Bølling-Allerød and the cold Younger Dryas of the North Atlantic on the millennial scale. A periodic variation of ~8.7 kyr was observed in the PC-2 score profile of detrital input to Lake Hovsgol over the last glacial and Holocene. The decrease in detrital input coincided with the copious supply of moisture from the Asian monsoon regime and the North Atlantic westerly winds to the Baikal drainage basin, which includes Lake Hovsgol. Our geochemical records from Lake Hovsgol demonstrate that the climate system of interior continental Asia was strongly influenced by change on both Milankovitch and sub-Milankovitch scales.     

Simulation of eutrophication and associated occurrence of hypoxic and anoxic condition in a coastal bay in Japan

A probabilistic method of calculating the occurrence of oxygen-depleted water within a combined hydrothermal and water quality model was presented in this paper to investigate the environmental impact of eutrophication on the living resources. The method was applied to an eutrophicated shallow coastal bay in western Japan, where the occurrence of red tides at the water surface and the onset of bottom hypoxic waters are observed every summer. Both meteorology and freshwater inflow contribute to the development of stratification of the bay, thus limiting the dissolved oxygen supply to bottom waters. The resulting hydrodynamics enhances the development of oxygen-depleted bottom waters by transporting organic matter produced by algal blooms to the inner bay, where it decomposes and exerts high SOD. During August, about 60% of the inner bay is hypoxic for prolonged durations and as a result most of the benthic biota and fish die. The method used here is a very useful and informative way to evaluate the spatial and temporal damage and severity caused by hypoxia on living resources. Moreover, the model results agreed very well with the observed hydrodynamics, thermal structure and water quality data of the stratified bay. The model can be used for other lakes and bays where knowledge of temperature and density stratification is important for assessing water quality.     

Anthropogenic Pb in settling particulate matter in the Northwestern Pacific examined using stable isotopes of Pb

We have investigated Pb concentrations and isotopic compositions in settling particles collected by sediment traps experiments over a period of two years, from May 2005 to April 2007, at two depths, 770 and 5100 m, at station KNOT in the Northwestern Pacific Ocean (44°N, 155°E). To the identify provenances of Pb, the samples were separated into two fractions by chemical leaching techniques, with the leachate expected to contain Pb of anthropogenic origin. Isotopic compositions of Pb and concentrations of Pb, Sc, Mn, La, Yb, and Th were measured by quadrupole ICP-MS. The isotope ratios of leachable Pb in settling particles were ²⁰⁷Pb/²⁰⁶Pb = 0.860 ± 0.001; ²⁰⁸Pb/²⁰⁶Pb = 2.116 ± 0.002 (mean ± 95% confidence intervals), which are similar to those of aerosols in China that are greatly affected by pollution from coal combustion. We estimated the mean contribution from anthropogenic Pb sources to the Pb in settling particles, using the conventional binary (anthropogenic and natural Pb) mixing equation for Pb isotopes, as 90% in the upper trap and 78% in the lower trap. Furthermore, we found a significant negative correlation between the isotope ratios of Pb and concentrations of leachable Mn, normalized to those of leachable Pb, suggesting that manganese oxides play an important role in transporting Pb from the upper layers of the ocean to the deeper layers. Our results support the speculation published in a previous study that Pb might be scavenged by Mn oxides in the Northwestern Pacific Ocean.     

A determination of the Dalton and Stanton numbers over a saturated barley field

In order to determine the values of the Dalton and the Stanton numbers, an observational study was made over a saturated barley field in the Hachirogata. flat reclaimed land located in the northern part of Japan. The mean height of the barley was about 11 cm; the roughness height for momentum was determined from the mean wind profiles as 4.24 ± 0.18 cm and the zero-plane displacement height as 0 cm. Under neutral stratification and a saturated surface, the reciprocals of the Dalton and Stanton numbers, Da^-1 and St^-1, were estimated. The results show that the mean value of St^-1 is 12.1, and the ratio of the bulk transfer coefficient for heat to that for momentum. C _H/C_M, is 0.53, which are not entirely incompatible with the few results available from past observations. The mean value of Da^- is 38.2. This value is larger than St^-1, and fits reasonably well with the semi-empirical equation proposed by Brutsaert (1975a,b).     

Dynamical downscaling: Fundamental issues from an NWP point of view and recommendations

Dynamical downscaling has been recognized as a useful tool not only for the climate community, but also for associated application communities such as the environmental and hydrological societies. Although climate projection data are available in lower-resolution general circulation models (GCMs), higher-resolution climate projections using regional climate models (RCMs) have been obtained over various regions of the globe. Various model outputs from RCMs with a high resolution of even as high as a few km have become available with heavy weight on applications. However, from a scientific point of view in numerical atmospheric modeling, it is not clear how to objectively judge the degree of added value in the RCM output against the corresponding GCM results. A key factor responsible for skepticism is based on the fundamental limitations in the nesting approach between GCMs and RCMs. In this article, we review the current status of the dynamical downscaling for climate prediction, focusing on basic assumptions that are scrutinized from a numerical weather prediction (NWP) point of view. Uncertainties in downscaling due to the inconsistencies in the physics packages between GCMs and RCMs were revealed. Recommendations on how to tackle the ultimate goal of dynamical downscaling were also described.