Cathodoluminescence of high-pressure feldspar minerals as a shock barometer

Cathodoluminescence (CL) analyses were carried out on maskelynite and lingunite in L6 chondrites of Tenham and Yamato-790729. Under CL microscopy, bright blue emission was observed in Na-lingunite in the shock veins. Dull blue-emitting maskelynite is adjacent to the shock veins, and aqua blue luminescent plagioclase lies farther away. CL spectroscopy of the Na-lingunite showed emission bands centered at ~330, 360–380, and ~590 nm. CL spectra of maskelynite consisted of emission bands at ~330 and ~380 nm. Only an emission band at 420 nm was recognized in crystalline plagioclase. Deconvolution of CL spectra from maskelynite successfully separated the UV–blue emission bands into Gaussian components at 3.88, 3.26, and 2.95 eV. For comparison, we prepared K-lingunite and experimentally shock-recovered feldspars at the known shock pressures of 11.1–41.2 GPa to measure CL spectra. Synthetic K-lingunite has similar UV–blue and characteristic yellow bands at ~550, ~660, ~720, ~750, and ~770 nm. The UV–blue emissions of shock-recovered feldspars and the diaplectic feldspar glasses show a good correlation between intensity and shock pressure after deconvolution. They may be assigned to pressure-induced defects in Si and Al octahedra and tetrahedra. The components at 3.88 and 3.26 eV were detectable in the lingunite, both of which may be caused by the defects in Si and Al octahedra, the same as maskelynite. CL of maskelynite and lingunite may be applicable to estimate shock pressure for feldspar-bearing meteorites, impactites, and samples returned by spacecraft mission, although we need to develop more as a reliable shock barometer.     

Factors controlling dissolved silica in coral reef surface water of Urasoko Bay, Ishigaki Island, Japan

From August 2006 to August 2007, the concentrations of dissolved silica (Si(OH)₄) were monitored in the surface water of Urasoko Bay and the mouth of the stream that runs into the bay. Urasoko Bay is located on the northern coast of Ishigaki Island, Okinawa, Japan, which is in a subtropical area of the North Pacific Ocean and is surrounded by a relatively poorly developed fringing reef. Added to these samples were freshwater from the upstream area and brackish water that exudes at the beach site, which were collected from April to June 2007. Rainwater samples were also collected during the study period. The concentration of Si(OH)₄ generally decreased from upstream to the bay site, and, on clear days, Si(OH)₄ data from all study sites (the bay, beach, stream mouth, and upstream) plotted against salinity fell on a single straight line. When the influence of rainwater was, the results were scattered below the straight line, which suggests dilution by rainwater with a much lower Si(OH)₄ concentration. These findings show that offshore seawater, rainwater, and upstream freshwater regulate the concentration of Si(OH)₄ in the surface water of Urasoko Bay.     

Climate control on Venus: Comparison of the carbonate and pyrite models

We review two models describing the Venus climate system: the carbonate and pyrite models. It has been argued carbonate and pyrite are potentially important minerals controlling the climate of Venus, though existence of either minerals has not been confirmed. Although it used to be proposed that carbonation reaction might explain the Venus’ atmospheric CO₂ abundance, it is unlikely Venus’ surface is reactive enough to control the Venus’ massive CO₂ atmosphere. Venus’ surface carbonate is also able to affect the climate through the reaction with atmospheric SO₂ to form anhydrite. Under the carbonate model the climate state is not in equilibrium and would be unstable due to the reaction between carbonate and SO₂. On the other hand, pyrite-magnetite reaction is proposed to explain the Venus’ atmospheric SO₂ abundance. Under pyrite-magnetite reaction, however, the climate would be stabilized such that the existing climate state is maintained over a geological timescale, while some observational facts such as atmospheric abundance of SO₂ and surface temperature could also be reasonably explained.     

Collapse and fragmentation of rotating magnetized clouds – I. Magnetic flux–spin relation

We discuss the evolution of the magnetic flux density and angular velocity in a molecular cloud core, on the basis of three-dimensional numerical simulations, in which a rotating magnetized cloud fragments and collapses to form a very dense optically thick core of  >5 × 10¹⁰ cm⁻³  . As the density increases towards the formation of the optically thick core, the magnetic flux density and angular velocity converge towards a single relationship between the two quantities. If the core is magnetically dominated its magnetic flux density approaches  1.5( n /5 × 10¹⁰ cm⁻³)^1/2 mG  , while if the core is rotationally dominated the angular velocity approaches  2.57 × 10⁻³ ( n /5 × 10¹⁰ cm⁻³)^1/2 yr⁻¹  , where n is the density of the gas. We also find that the ratio of the angular velocity to the magnetic flux density remains nearly constant until the density exceeds  5 × 10¹⁰ cm⁻³  . Fragmentation of the very dense core and emergence of outflows from fragments will be shown in the subsequent paper.     

Effect of temperature on the methyl chloride production rate in a marine phytoplankton, <Emphasis Type="Italic">Phaeodactylum tricornutum</Emphasis>

Methyl halides such as methyl chloride (CH₃Cl) are known to be important carriers of halogen from the ocean to the atmosphere, and the halogens they release into the stratosphere by photolysis catalyze ozone depletion. Marine phytoplankton have been reported as a source of CH₃Cl, but the effects of environmental temperature on the CH₃Cl production by phytoplankton have not been investigated. In this study, we investigated the effects of temperature on the production of CH₃Cl in the culture of a marine diatom, Phaeodactylum tricornutum CCMP 630, incubated at 10, 15, 20, 25, and 30 °C. CH₃Cl concentrations in cultured samples were determined using purge and trap gas chromatograph–mass spectrometry. Phytoplankton growth was monitored by measuring the chlorophyll a concentrations. CH₃Cl production was observed for several weeks at four different temperatures ranging from 10 to 25 °C. The CH₃Cl production from P. tricornutum was increased with increasing temperature from 10 to 25 °C, and the maximum production rate for CH₃Cl was 0.21~0.26 μmol (g chlorophyll a)^?1 d^?1 at 25 °C, which was several times higher than that at 10 °C (~0.03 μmol (g chlorophyll a)^?1 d^?1). The Arrhenius equation was successfully used to characterize the effects of temperature on the production rates of CH₃Cl in the culture of P. tricornutum. Our results suggest that water temperature directly affects CH₃Cl production derived from P. tricornutum and that water temperature would be a significant factor for estimating the emissions of CH₃Cl from marine environments.     

Control of Phosphate Concentration through Adsorption and Desorption Processes in Groundwater and Seawater Mixing at Sandy Beaches in Tokyo Bay, Japan

Field observation was conducted to monitor phosphate concentrations in groundwater and seawater mixing at two sandy beaches in Futtsu and Miura in Tokyo Bay, Japan. Dissolved phosphate concentrations were measured along transects from fresh groundwater aquifer to seawater adjacent the beaches. The concentrations were often high (up to 46 µM) in fresh groundwater samples (Cl^– < 0.2). Coastal seawater, on the other hand, exhibited low phosphate concentrations (1.5 µM or less). Along the transects, phosphate generally displayed non-conservative behavior during mixing of fresh and saline waters in the aquifer; concentrations as high as 100 µM were found around the upper limit of seawater intrusion (Cl^– = 2). Laboratory experiments were executed to identify the processes that control the phosphate behavior in the mixing processes. The results revealed that adsorption-desorption processes by the aquifer sand particles could significantly control the phosphate concentrations in the groundwater. Furthermore, the adsorption and/or desorption was found to be a function of salinity; the equilibrium concentration of dissolved phosphate in slurry of sand and water was the highest in freshwater and decreased considerably in saline water. The extreme concentration of phosphate may be caused by release from sand particles coinciding with the rapid change in salinity with tide.     

Current structure and volume transport of the Soya Warm Current in summer

ADCP, CTD and XBT observations were conducted to investigate the current structure and temperature, salinity and density distributions in the Soya Warm Current (SWC) in August, 1998 and July, 2000. The ADCP observations clearly revealed the SWC along the Hokkaido coast, with a width of 30–35 km and an axis of maximum speed of 1.0 to 1.3 ms⁻¹, located at 20–25 km from the coast. The current speed gradually increased from the coast to a maximum and steeply decreased in the offshore direction. The SWC consisted of both barotropic and baroclinic components, and the existence of the baroclinic component was confirmed by both the density front near the current axis and vertical shear of the alongshore current. The baroclinic component strengthened the barotropic component in the upper layer near the axis of the SWC. The volume transport of the SWC was 1.2–1.3 SV in August, 1998 and about 1.5 SV and July, 2000, respectively. Of the total transport, 13 to 15% was taken up by the baroclinic component. A weak southeastward current was found off the SWC. It had barotropic characteristics, and is surmised to be a part of the East Sakhalin Current.     

Formation of thermohaline front by cooling of the sea surface and inflow of the fresh water

A numerical study of characteristics of the front formed by cooling of the sea surface and inflow of the fresh water is made within a vertical two-dimensional plane without the rotation of the earth. The convective adjustment technique is employed to parameterize the small scale convective overturning process.A sharply edged shelf causing the marked difference of the heat capacity of the water columns between over the shelf (50 m depth) and in the deeper region (150 m depth), is responsible for the formation of a thermal front over the shelf edge and two cell circulations of the same sense with each other adjoining at the frontal region.Inflow of the fresh water at the upper region of the coast (which is equivalently replaced by the outflow of the salt from the same region) adds a circulation of the opposite sense to the above ones, which transports the water of low salinity and low temperature offshore and forms a sharp front both of temperature and salinity with the offshore water of high salinity and high temperature. This thermohaline front or Oceanic front has a remarkable character that the horizontal density gradient is minimal at the front due to the counteracting contributions of temperature and salinity to density. Response of this front to the sudden ceases of the surface cooling and the fresh water supply, is also studied in order to understand its transient behaviors.     

A numerical investigation of western boundary currents in subtropical and subpolar gyres with a barotropic model

Dynamics of western boundary currents in the subtropical and subpolar gyres are studied as a source-sink flow of barotropic fluid by means of numerical integration of the time-dependent non-linear vorticity equation. The bottom topography consists of a continental shelf of uniform slope (120 km wide) parallel to the straight western coast and a flat bottom of uniform depth. The steady solution in the case of low Reynolds number (Re≦100) shows the vorticity balance of the western boundary current between theβ-, diffusion-, and bottom relief terms. The cuspidated flow of the western boundary current in the subpolar gyre is observed as a compensating flow for the subtropical western boundary current separating from the western coast. In the case of Re=350, the zonal current separating from the coast meanders with the wave length of the stationary Rossby waves. It is shown that in the present model the separation of the boundary current is controlled by the planetary vorticity (f) of the fluid particle in the boundary flow, with which the same particle flows out the eastern wall at the corresponding latitude. The decrease of the efflux width increases the intensity of the non-linear overshooting of the boundary current separating from the western coast.