Thermal alteration experiments on organic matter in recent marine sediment—III. Aliphatic and steroidal alcohols

Recent sediments from Tanner Basin (off southern California) and Bandaras Bay (in Gulf of California) have been analyzed for normal, isoprenoid and steroidal alcohols using chromatographic (column, GLC, TLC), and spectroscopic (u.v., i.r., MS) methods, prior to and after heat-treatment (from 65 to 150°C). Normal saturated alcohols (C₁₄-C₂₄) and monounsaturated alcohols (C₂₂-C₂₄) were identified, as well as the isoprenoid alcohols, phytol and dihydrophytol.Two series of sterols (Δ⁵ and Δ⁷) were found in Tanner Basin, and Δ⁵-sterols and triterpenes, in Bandaras Bay sediment. Sterols from both sediments contained the corresponding stanols.     

Differential effects of salinity changes on two estuarine fishes,Leiostomus xanthurus andMicropogonias undulatus

Salinity fluctuation has been proposed as an important determinant of estuarine fish distribution. To test this idea, we compared distribution, behavioral preference and physiological sensitivity of two juvenile estuarine fishes, spot (Leiostomus xanthurus) and croaker (Micropogonias undulatus), with respect to salinity change. In field collections, spot: croaker ratios were positively correlated with salinity variation. Subsequent behavioral observations revealed that croaker tend to cross a 10‰ salinity gradient less often than spot. We proposed that energetic costs of salinity adaptation may be higher for croaker, resulting in the observed avoidance behavior. Oxygen consumption rates over rapid salinity fluctuations showed no significant differences in metabolic response between species, although there was some indication that sensitivity changes with fish size. Apparently, juvenile spot and croaker are well-equipped to withstand extreme changes in salinity. We conclude that environmental factors correlated with salinity change may be responsible for distribution differences between these two abundant species.     

Fluxes and sources of suspended organic matter in an estuarine turbidity maximum region during low discharge conditions

Water column concentrations of total suspended solids (TSS), particulate organic carbon (POC) and particulate nitrogen (PN) were measured at three different depths in four different locations bracketing the estuarine turbidity maximum (ETM) along the main channel of a temperate riverine estuary (Winyah Bay, South Carolina, USA). Measurements were carried out over full tidal cycle (over 24 h). Salinity, temperature, current magnitude and direction were also monitored at the same time throughout the water column. Tidally averaged net fluxes of salt, TSS, POC and PN were calculated by combining the current measurements with the concentration data. Under the extreme low river discharge conditions that characterized the study period, net landward fluxes of salt were measured in the lower part of the study area, suggesting that the landward transport through the main channel of the estuary was probably balanced by export out through the sides. In contrast, the net fluxes of salt in the upper reaches of the study area were near zero, indicating a closed salt balance in this part of the estuary. In contrast to salt, the net fluxes of TSS, POC and PN in the deeper parts of the water column were consistently landward at all four sites in Winyah Bay indicating the non-conservative behavior of particulate components and their active transport up the estuary in the region around the ETM.The carbon contents (%POC), carbon:nitrogen ratios (org[C:N]a) and stable carbon isotopic compositions (δ¹³C_POC) of the suspended particles varied significantly with depth, location and tidal stage. Tidally averaged compositions showed a significant increase up the estuary in the %POC and org[C:N]a values of suspended particles consistent with the preferential landward transport of carbon-rich particles with higher vascular plant debris content. The combination of tidal resuspension and flood-dominated flow appeared to be responsible for the hydrodynamic sorting of particles along the estuary that resulted in denser, organic-poor particles being transported landward less efficiently. The elemental and isotopic compositions indicated that vascular C₃ plants and estuarine algae were the major sources of the particulate organic matter of all the samples, without any significant contributions from salt marsh C₄ vegetation (Spartina alterniflora) and/or marine phytoplankton.     

Effects of benzene and dimethylnaphthalene on homeostatic processes in two species of crabs

Long-term exposure of animals to sub-lethal doses of toxicants such as benzene (B) and dimethylnaphthalene (DMN) may result in subtle changes in their physiology and biochemistry. In crustaceans such changes include decreased rate of limb regeneration, extended time to molt and decreased growth increment at molt.^1,2 These processes depend upon an adequate supply of stored nutrients in the tissues and appropriate release of neuroendocrine substances from the central nervous system.^3,4 We are examining the effects of sub-lethal doses of B and DMN on osmotic and ionic regulation and on nutrient storage in the blue crab, Callinectes sapidus, and the green crab, Carcinus maenas. Disturbances in these physiological processes may reflect alterations in neuroendocrine functions brought about by the presence of toxicants. We find that exposure of C. maenas to B or DMN, followed by transfer to a dilute medium, results in impaired osmoregulatory capacity, while addition of these compounds to a dilute medium to which the animal is already acclimated does not affect their regulatory ability. Storage of carbohydrate in the midgut gland (hepatopancreas) is decreased by B or DMN, while the accessory storage tissues (gill, muscle) are not significantly affected.     

Tectono‐sedimentary evolution of the western Corinth rift (Central Greece)

The Corinth rift (Greece) is one of the world's most active rifts. The early Plio‐Pleistocene rift is preserved in the northern Peloponnese peninsula, south of the active Corinth rift. Although chronostratigraphic resolution is limited, new structural, stratigraphic and sedimentological data for an area >400 km² record early rift evolution in three phases separated by distinct episodes of extension rate acceleration and northward fault migration associated with major erosion. Minimum total N–S extension is estimated at 6.4–7.7 km. The earliest asymmetrical, broad rift accommodated slow extension (0.6–1 mm a^?1) over >3 Myrs and closed to the west. North‐dipping faults with throws of 1000–2200 m defined narrow blocks (4–7 km) with little footwall relief. A N‐NE flowing antecedent river system infilled significant inherited relief (Lower group). In the earliest Pleistocene, significant fluvial incision coincided with a 15 km northward rift margin migration. Extension rates increased to 2–2.5 mm a^?1. The antecedent rivers then built giant Gilbert‐type fan deltas (Middle group) north into a deepening lacustrine/marine basin. N‐dipping, basin margin faults accommodated throws <1500 m. Delta architecture records initiation, growth and death of this fault system over ca. 800 ka. In the Middle Pleistocene, the rift margin again migrated 5 km north. Extension rate increased to 3.4–4.8 mm a^?1. This transition may correspond to an unconformity in offshore lithostratigraphy. Middle group deltas were uplifted and incised as new hangingwall deltas built into the Gulf (Upper group). A final increase to present‐day extension rates (11–16 mm a^?1) probably occurred in the Holocene. Fault and fault block dimensions did not change significantly with time suggesting control by crustal rheological layering. Extension rate acceleration may be due to strain softening or to regional tectonic factors.     

Post‐orogenic sediment drape in the Northern Pyrenees explained using a box model

The transition to a post‐orogenic state in mountain ranges has been identified by a change from active subsidence to isostatic rebound of the foreland basin. However, the nature of the interplay between isostatic rebound and sediment supply, and their impact on the topographic evolution of a range and foreland basin during this transition, has not been fully investigated. Here, we use a box model to explore the syn‐ to post‐orogenic evolution of foreland basin/thrust wedge systems. Using a set of parameter values that approximate the northern Pyrenees and the neighbouring Aquitaine foreland basin, we evaluate the controls on sediment drape over the frontal parts of the retro‐wedge following cessation of crustal thickening. Conglomerates preserved at approximately 600‐m elevation, which is ~ 300 m above the present mountain front in the northern Pyrenees are ca. 12 Ma, approximately 10 Myrs younger than the last evidence of crustal thickening in the wedge. Using the model, this post‐orogenic sediment drape is explained by the combination of a sustained, high sediment influx from the range into the basin relative to the efflux out of the basin, combined with cessation of the generation of accommodation space through basin subsidence. Post‐orogenic sediment drape is considered a generic process that is likely to be responsible for elevated low‐gradient surfaces and preserved remnants of continental sedimentation draping the outer margins of the northern Pyrenean thrust wedge.     

A coupling of mixed and continuous Galerkin finite element methods for poroelasticity II: the discrete-in-time case

In this paper, we formulate a finite element procedure for approximating the coupled fluid and mechanics in Biot’s consolidation model of poroelasticity. Here, we approximate the pressure by a mixed finite element method and the displacements by a Galerkin method. Theoretical convergence error estimates are derived in a discrete-in-time setting. Of particular interest is the case when the lowest-order Raviart–Thomas approximating space or cell-centered finite differences are used in the mixed formulation and continuous piecewise linear approximations are used for displacements. This approach appears to be the one most frequently applied to existing reservoir engineering simulators.     

Tertiary Tsondab Sandstone Formation: preliminary bedform reconstruction and comparison to modern Namib Sand Sea dunes

The Tertiary Tsondab Sandstone Formation, which underlies much of the present Namib Sand Sea, is a key element in understanding the Cenozoic evolution of the Namib Desert. Outcrops of the aeolian facies of the Tsondab Sandstone at Elim and Diep Rivier consist of two sequences of bioturbated cross-strata separated by likely formation-scale surfaces of stabilisation. Cross-strata consist of scalloped sets about 200 m in width and separated by southeast dipping bounding surfaces. Internally, sets contain reactivation surfaces of probable seasonal origin. The north to south-southeast dipping foresets define crescent shapes with a trough axis trending northeast. Although additional data are needed to define the Tsondab bedform, the outcrop data is best satisfied in computer simulations by north trending, east migrating main bedforms, which had relatively large and slow-moving dunes superimposed upon their eastern flanks and migrated to the north. Foresets dipping to the south to south-southwest at Elim suggest that superimposed dunes also occurred on the western flanks of the main bedform and migrated to the south, but that their record was largely lost with net eastward migration of the main bedform. This preliminary Tsondab model shares attributes such as trend, scale of cross-strata, and presence of scalloped sets with reactivation surfaces with computer models of the modern linear dunes in which large-scale sinuosity migrates alongcrest to the north. Differences emerge in the overall set architecture and the orientation of cross-strata and bounding surfaces, as well as the degree of vegetation that must have characterised Tsondab dunes.     

The Sensitivity of Four Monitoring Well Sampling Systems to Low Concentrations of Three Volatile Organics

Four state-of-the-art ground water sampling systems were analyzed to determine their reliability in providing representative samples of the volatile chlorinated hydrocarbons trichloroethylene (TCE), perchloroethylene (PCE), and 1,1,1-trichloroethane (TCA) from a simulated monitoring well. The sampling systems studied represent four commonly used devices, including a stainless steel and Teflon® piston pump, a Teflon bailer, a Teflon bladder pump, and a PVC air-lift pump.
Controlled laboratory sampling experiments were conducted in a tank and well test chamber designed to approximate field conditions. A well purging and sampling procedure was used in the test apparatus to determine the accuracy and precision of each device for detecting low concentrations of the compounds in ground water. The compounds selected are some of the most ubiquitous hazardous contaminants found in shallow aquifers near hazardous waste sites throughout the United States.
No significant statistical difference was found among the four sampling systems in detecting the compounds.     

Heat capacity, entropy, and magnetic properties of jarosite-group compounds

Jarosite phases are common minerals in acidic, sulfate-rich environments. Here, we report heat capacities (C _p) and standard entropies (S°) for a number of jarosite samples. Most samples are close to the nominal composition AFe₃(SO₄)₂(OH)₆, where A = K, Na, Rb, and NH₄. One of the samples has a significant number of defects on the Fe sites and is called the defect jarosite; others are referred to as A-jarosite. The samples, their compositions, and the entropies at T = 298.15 K are: