Tertiary Tsondab Sandstone Formation: preliminary bedform reconstruction and comparison to modern Namib Sand Sea dunes

The Tertiary Tsondab Sandstone Formation, which underlies much of the present Namib Sand Sea, is a key element in understanding the Cenozoic evolution of the Namib Desert. Outcrops of the aeolian facies of the Tsondab Sandstone at Elim and Diep Rivier consist of two sequences of bioturbated cross-strata separated by likely formation-scale surfaces of stabilisation. Cross-strata consist of scalloped sets about 200 m in width and separated by southeast dipping bounding surfaces. Internally, sets contain reactivation surfaces of probable seasonal origin. The north to south-southeast dipping foresets define crescent shapes with a trough axis trending northeast. Although additional data are needed to define the Tsondab bedform, the outcrop data is best satisfied in computer simulations by north trending, east migrating main bedforms, which had relatively large and slow-moving dunes superimposed upon their eastern flanks and migrated to the north. Foresets dipping to the south to south-southwest at Elim suggest that superimposed dunes also occurred on the western flanks of the main bedform and migrated to the south, but that their record was largely lost with net eastward migration of the main bedform. This preliminary Tsondab model shares attributes such as trend, scale of cross-strata, and presence of scalloped sets with reactivation surfaces with computer models of the modern linear dunes in which large-scale sinuosity migrates alongcrest to the north. Differences emerge in the overall set architecture and the orientation of cross-strata and bounding surfaces, as well as the degree of vegetation that must have characterised Tsondab dunes.     

The Sensitivity of Four Monitoring Well Sampling Systems to Low Concentrations of Three Volatile Organics

Four state-of-the-art ground water sampling systems were analyzed to determine their reliability in providing representative samples of the volatile chlorinated hydrocarbons trichloroethylene (TCE), perchloroethylene (PCE), and 1,1,1-trichloroethane (TCA) from a simulated monitoring well. The sampling systems studied represent four commonly used devices, including a stainless steel and Teflon® piston pump, a Teflon bailer, a Teflon bladder pump, and a PVC air-lift pump.
Controlled laboratory sampling experiments were conducted in a tank and well test chamber designed to approximate field conditions. A well purging and sampling procedure was used in the test apparatus to determine the accuracy and precision of each device for detecting low concentrations of the compounds in ground water. The compounds selected are some of the most ubiquitous hazardous contaminants found in shallow aquifers near hazardous waste sites throughout the United States.
No significant statistical difference was found among the four sampling systems in detecting the compounds.     

Heat capacity, entropy, and magnetic properties of jarosite-group compounds

Jarosite phases are common minerals in acidic, sulfate-rich environments. Here, we report heat capacities (C _p) and standard entropies (S°) for a number of jarosite samples. Most samples are close to the nominal composition AFe₃(SO₄)₂(OH)₆, where A = K, Na, Rb, and NH₄. One of the samples has a significant number of defects on the Fe sites and is called the defect jarosite; others are referred to as A-jarosite. The samples, their compositions, and the entropies at T = 298.15 K are:

A surge response function approach to coastal hazard assessment. Part 2: Quantification of spatial attributes of response functions

In response to the 2004 and 2005 hurricane seasons, surge risk assessment approaches have been re-evaluated to develop more rapid, reliable methods for predicting the risk associated with extreme hurricanes. Here, the development of dimensionless surge response functions relating surge to hurricane meteorological parameters is presented. Such response functions present an opportunity to maximize surge data usage and to improve statistical estimates of surge probability by providing a means for defining continuous probability density functions. A numerical modeling investigation was carried out for the Texas, USA coastline to develop physical scaling laws relating storm surge response with hurricane parameters including storm size, intensity, and track. It will be shown that these scaling laws successfully estimate the surge response at any arbitrary location for any arbitrary storm track within the study region. Such a prediction methodology has the potential to decrease numerical computation requirements by 75% for hurricane risk assessment studies.     

Selection and quality assessment of Landsat data for the North American forest dynamics forest history maps of the US

Using the NASA Earth Exchange platform, the North American Forest Dynamics (NAFD) project mapped forest history wall-to-wall, annually for the contiguous US (1986–2010) using the Vegetation Change Tracker algorithm. As with any effort to identify real changes in remotely sensed time-series, data gaps, shifts in seasonality, misregistration, inconsistent radiometry and cloud contamination can be sources of error. We discuss the NAFD image selection and processing stream (NISPS) that was designed to minimize these sources of error. The NISPS image quality assessments highlighted issues with the Landsat archive and metadata including inadequate georegistration, unreliability of the pre-2009 L5 cloud cover assessments algorithm, missing growing-season imagery and paucity of clear views. Assessment maps of Landsat 5–7 image quantities and qualities are presented that offer novel perspectives on the growing-season archive considered for this study. Over 150,000+ Landsat images were considered for the NAFD project. Optimally, one high quality cloud-free image in each year or a total of 12,152 images would be used. However, to accommodate data gaps and cloud/shadow contamination 23,338 images were needed. In 220 specific path-row image years no acceptable images were found resulting in data gaps in the annual national map products.     

Market intermediaries and rural people in Bolivia's forest products sector: Are trusting partnerships possible?

Decentralization in access to and control of Bolivia's forest resources, coupled with a rising global demand for tropical hardwoods, raises important questions about whether increased trade and community forest management (CFM) initiatives can enable forms of market integration that have more favourable outcomes for rural communities. This paper assesses the prospects for such a transition through an examination of the relationships linking wood product market intermediaries (brokers and buyers) to rural suppliers and forest communities in Bolivia. The analysis centres on whether trust – conceptualized as a power‐laden sociospatial process driven by multiscalar factors – can evolve between buyers and suppliers such that more progressive (sustainable and mutually beneficial) partnerships devolop. Focusing on three types of buyer–supplier relationships in Bolivia – direct ties between wood brokers/buyers and suppliers, nongovernmental organization (NGO) mediated exchange relationships and Forest Stewardship Council (FSC) certification of suppliers – our findings show how trust building initiatives that focus on one scale may fail if factors at other scales create obstacles to collaboration, Given these relational constraints, CFM strategies in Bolivia currently face limitation on their viability as economic development strategies.     

Diagenesis of vascular plant organic matter components during burial in lake sediments

Diagenetic changes are difficult to distinguish from variations in sources of organic matter to sediments. Organic geochemical comparisons of samples of wood, bark, and needles from a white spruce (Picea glauca) living today and one buried for 10,000 years in lake sediments have been used to identify the effects of diagenesis on vascular plant matter. Important biogeochemical changes are evident in the aged spruce components, even though the cellular structures of the samples are well preserved. Concentrations of total fatty acids dramatically diminish; unsaturated and shorter chainlength components are preferentially lost from the molecular distributions. Concentrations of total alcohols are similar in the modern and 10,000-year-old wood and bark but markedly lowered in the aged needles. Hydrocarbon concentrations and distributions show little diagenetic change in the 10,000-year-old plant materials. Cellulose components in the wood decrease relative to lignin components, although both types of materials remain in high concentration in comparison to other organic components. Aromatization of abietic acid proceeds more rapidly in buried spruce wood than in bark; retene is the dominant polyaromatic hydrocarbon in the aged wood. In contrast to the variety of changes evident in molecular compositions, neither ¹³C values nor C/N ratios differ significantly in the bulk organic matter of modern and aged spruce components.     

Laser Ablation (U-Th-Sm)/He Dating of Zircons: Analytical Age Bias and its Consequence for Studying Detrital Zircon Populations

The in situ (U-Th-Sm)/He and U/Pb laser-ablation double-dating procedure is a valuable method that can provide a large dataset relatively efficiently in contrast with conventional bulk helium thermochronometry. In this study, we evaluate the potential age error associated with the double ablation procedure and report the in situ (U-Th-Sm)/He double-ablation dating of 249 zircons from the Fish Canyon Tuff locality. With LA-ICP-MS pseudo-depth profiling and 3D numerical modelling, we show that the concentric double-ablation procedure in minerals with U-Th-Sm zoning can generate a significant (U-Th-Sm)/He age error (positive or negative), resulting in over-scattering and/or an offset of the mean age. Pseudo-depth profiling is insufficient to predict the individual age error, partly because of the superimposed ablations. To evaluate the consequence of this inherent bias, we confront a synthetic age distribution to the error expected for U-Th-Sm zoned zircons analysed with double-ablation (U-Th-Sm)/He thermochronometry. As expected, a strong age bias causes the spreading of peak ages, downgrading the original signal. Yet, the throughput of the ablation-based method can allow intra- and inter-sample peak age identification and comparison, and the coupling of (U-Th-Sm)/He and U/Pb ages extends our ability to deconvolute a multimodal age spectrum.     

The respiratory environment of the Namib Desert Golden Mole

We measured the partial pressure of oxygen (PO₂) in the interstitial gas surrounding the sand-swimming Namib moleEremitalpa granti namibensis. At a sand temperature of 26 °C, which produced a nearly maximal rate of oxygen consumption, thePO₂near the noses of the animals averaged only 0·9 kPa (6·7 Torr) below the level in the free atmosphere. High oxygen availability was a result of the notably low metabolic rate in the 20 g mammals and the dry, porous and metabolically inactive nature of dune sand. A mathematical model indicated that normal mammals weighing 200 g or more could comfortably exist completely encased in dune sand. We concluded that the moles' small size and low metabolic rate are not adaptations to hypoxia or hypercapnia underground but are probably related to low food availability and the energetic cost of foraging in their desert environment.