Solar Eclipses and the Surface Properties of Water

Earth, Moon, and Planets - During four solar eclipse events (two annular, one total and one partial) a correlation was observed between a change in water surface tension and the magnitude of the...     

Hafnium isotopes in Arctic Ocean water

The first isotopic compositions of dissolved hafnium in seawater from across the Arctic Ocean are reported. Most samples from the four sub-basins of the Arctic Ocean have values within error of an average of ε_Hf = +0.8. Combined Hf-Nd isotope compositions do not fall on the well-established positive correlation for mantle and crustal rocks. Instead, Arctic waters have Hf that is more radiogenic than that typically found in rocks with similar Nd isotope compositions, a feature previously found in ferromanganese crusts and waters from the Pacific Ocean. Arctic seawater samples generally fall on the lower part of the ferromanganese crust array, reflecting influences of inputs from Arctic rivers and interactions of shelf waters with underlying sediments. Arctic rivers have much higher Hf concentrations (7-30 pM) than Arctic seawater (0.36-4.2 pM). Water from the Mackenzie River has the least radiogenic Hf, with ε_Hf = −7.1 ± 1.7, and plots furthest away from the ferromanganese crust array, while waters from the Ob, Yenisey, and Lena Rivers have values that are indistinguishable from most Arctic waters. In the Amundsen, Makarov, and Canada basins, Hf concentrations are highest at the surface and lowest in the deeper waters, reflecting the influences of riverine inputs and of waters that have flowed over the extensive Siberian continental shelves and have Nd and Hf characteristics that reflect water-sediment interactions. This is in contrast to the relatively low near surface Hf concentrations reported for locations elsewhere. The Pacific water layer in the Canada Basin exhibits the highest value of ε_Hf = +6.8 ± 1.8, reflecting the Hf isotopic composition of waters entering the Arctic from the Pacific Ocean. Mixing relationships indicate that a substantial fraction of the Hf in the Mackenzie River is lost during estuarine mixing; the behaviour of Hf from other rivers is less constrained.     

The Neoproterozoic Fiq glaciation and its aftermath, Huqf supergroup of Oman

The <1.5‐km thick Fiq Member of the Ghadir Manqil Formation, Huqf Supergroup, Oman, contains a succession of Marinoan‐age glacially and non‐glacially influenced deposits overlain by a transgressive, ¹³C‐depleted, deep‐water dolostone (Hadash Formation) that deepens up into the marine shales and siltstones of the Masirah Bay Formation. The Fiq Member and Hadash–Masirah Bay Formations are well exposed in the core of the Jebel Akhdar of northern Oman and provide a valuable insight into the processes operating during a Neoproterozoic glacial epoch and its aftermath. The Fiq Member comprises seven stratigraphic units (F1–F7) of proximal and distal glacimarine, non‐glacial sediment gravity flow, and non‐glacial shallow marine facies associations. These units can be correlated over almost the entire Neoproterozoic outcrop belt (ca. 80 km) of the Jebel Akhdar. Four units contain glacimarine rainout diamictites, commonly at the top of cycles beneath strong lithofacies dislocations suggesting flooding. The units are thought to have been generated by combined glacio‐isostatic and glacio‐eustatic forcing caused by changing volumes of terrestrial glacier ice. The lateral persistence and thickness of massive diamictite units increase upwards in the stratigraphy, the youngest (F7) diamictite being abruptly overlain by the Hadash Formation. Correlation of lithofacies associations across the rift basin and palaeocurrents indicate that siliciclastic sediment and glacially entrained debris were derived from both basin margins. Open‐water conditions existed during interglacials, attested to by the presence of wave‐rippled sandstones in the western part of the basin. The Hadash carbonate also exhibits variations between east and west, showing that despite an overall deep‐water depositional setting, rift margin and intrabasinal structure continued to exert a control on facies development during the post‐glacial aftermath. Onlap of basin margins continued through the deposition of the Masirah Bay Formation. The sedimentology and stratigraphy of the Fiq Member and Hadash–Masirah Bay Formations have a number of implications for the Snowball Earth hypothesis. The overall stratigraphic evolution of the Fiq Member suggests a dynamic, temperate/polythermal style of glaciation, perhaps nucleated on uplifted continental or rift margin topography, with marine‐terminating glaciers. Some transgressions coupled to deglaciations within the Fiq glacial epoch were accompanied by minor deposition of carbonate. However, final deglaciation triggered the deposition of a <8‐m thick, deep‐water dolomite contaminated with siliciclastics, with a lithofacies assemblage still reflecting the underlying bathymetric template, followed by relatively deep marine shales and siltstones. The preservation of relatively deep marine Masirah Bay sediments above the Fiq basin margin suggests either tectonic collapse of the rift shoulder or, more likely, rapid eustatic rise accompanying deglaciation.     

The Winchcombe meteorite—A regolith breccia from a rubble pile CM chondrite asteroid

The Winchcombe meteorite is a CM chondrite breccia composed of eight distinct lithological units plus a cataclastic matrix. The degree of aqueous alteration varies between intensely altered CM2.0 and moderately altered CM2.6. Although no lithology dominates, three heavily altered rock types (CM2.1–2.3) represent >70 area%. Tochilinite–cronstedtite intergrowths (TCIs) are common in several lithologies. Their compositions can vary significantly, even within a single lithology, which can prevent a clear assessment of alteration extent if only TCI composition is considered. We suggest that this is due to early alteration under localized geochemical microenvironments creating a diversity of compositions and because later reprocessing was incomplete, leaving a record of the parent body's fluid history. In Winchcombe, the fragments of primary accretionary rock are held within a cataclastic matrix (~15 area%). This material is impact-derived fallback debris. Its grain size and texture suggest that the disruption of the original parent asteroid responded by intergranular fracture at grain sizes <100 μm, while larger phases, such as whole chondrules, splintered apart. Re-accretion formed a poorly lithified body. During atmospheric entry, the Winchcombe meteoroid broke apart with new fractures preferentially cutting through the weaker cataclastic matrix and separating the breccia into its component clasts. The strength of the cataclastic matrix imparts a control on the survival of CM chondrite meteoroids. Winchcombe's unweathered state and diversity of lithologies make it an ideal sample for exploring the geological history of the CM chondrite group.     

Origin of organic matter in early solar system—V. Further studies of meteoritic hydrocarbons and a discussion of their origin

The Murchison meteorite contains aliphatic and aromatic hydrocarbons similar to those made in static Fischer-Tropsch-type syntheses. Principal compound classes above C₈ are n-alkanes, mono- and dimethylalkanes, alkenes, alkylbenzenes and -naphthalenes. Below C₈, n-alkanes are virtually absent; instead, benzene, toluene, branched alkanes dominate. The CH₄/C₂H₆ ratio is greater than 30, possibly greater than 700. Isoprenoids from C₁₇ to C₂₀ occur in a surface rinse but not in subsequent extracts and appear to be terrestrial contaminants. Thiophenes, porphyrin-like pigments and chlorobenzenes were also found; the latter appear to be contaminants. In the Allende meteorite, only methane, benzene, toluene and an aromatic polymer seem to be indigenous.