Analytical computation of arc menisci configuration under primary drainage in convex capillary cross sections

We analyze the geometric set-up of Lindquist’s “The Geometry of Primary Drainage” (J Colloid Interface Sci 296(2):655–668, 2006) and show that his main equation, which models the arc menisci configuration under primary drainage in capillary tube cross sections, can be solved analytically for the special case of a convex cross section and the wetting angle being assumed 0. Our approach relies on the Voronoi diagram of the cross section and runs in O(n logn) time for an n-segment cross section. It requires only the solution of n − 2 second-degree polynomial equations.     

Adenine oxidation by pyrite-generated hydroxyl radicals

Cellular exposure to particulate matter with concomitant formation of reactive oxygen species (ROS) and oxidization of biomolecules may lead to negative health outcomes. Evaluating the particle-induced formation of ROS and the oxidation products from reaction of ROS with biomolecules is useful for gaining a mechanistic understanding of particle-induced oxidative stress. Aqueous suspensions of pyrite particles have been shown to form hydroxyl radicals and degrade nucleic acids. Reactions between pyrite-induced hydroxyl radicals and nucleic acid bases, however, remain to be determined. Here, we compared the oxidation of adenine by Fenton-generated (i.e., ferrous iron and hydrogen peroxide) hydroxyl radicals to adenine oxidation by hydroxyl radicals generated in pyrite aqueous suspensions. Results show that adenine oxidizes in the presence of pyrite (without the addition of hydrogen peroxide) and that the rate of oxidation is dependent on the pyrite loading. Adenine oxidation was prevented by addition of either catalase or ethanol to the pyrite/adenine suspensions, which implies that hydrogen peroxide and hydroxyl radicals are causing the adenine oxidation. The adenine oxidation products, 8-oxoadenine and 2-hydroxyadenine, were the same whether hydroxyl radicals were generated by Fenton or pyrite-initiated reactions. Although nucleic acid bases are unlikely to be directly exposed to pyrite particles, the formation of ROS in the vicinity of cells may lead to oxidative stress.     

From Tethys to Eastern Paratethys: Oligocene depositional environments, paleoecology and paleobiogeography of the Thrace Basin (NW Turkey)

The Oligocene depositional history of the Thrace Basin documents a unique paleogeographic position at a junction between the Western Tethys and the Eastern Paratethys. As part of the Tethys, shallow marine carbonate platforms prevailed during the Eocene. Subsequently, a three-staged process of isolation started with the Oligocene. During the Early Rupelian, the Thrace Basin was still part of the Western Tethys, indicated by typical Western Tethyan marine assemblages. The isolation from the Tethys during the Early Oligocene is reflected by oolite formation and endemic Eastern Paratethyan faunas of the Solenovian stage. The third phase reflects an increasing continentalisation of the Thrace Basin with widespread coastal swamps during the Late Solenovian. The mollusc assemblages are predominated by mangrove dwelling taxa and the mangrove plant Avicennia is recorded in the pollen spectra. The final continentalisation is indicated by the replacement of the coastal swamps by pure freshwater swamps and fluvial plains during the Late Oligocene (mammal zone MP 26). This paleogeographic affiliation of the Thrace Basin with the Eastern Paratethys after ~32 Ma contrasts all currently used reconstructions which treat the basin as embayment of the Eastern Mediterranean basin.     

U-Pb Zircon Geochronology with an Integrated LA-ICP-MS Microanalytical Workstation: Achievements in Precision and Accuracy

Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) is a microanalytical tool especially suitable for providing fast and precise U-Pb geochronological results on zircon grains. A new 193 nm excimer laser adapted to a micromachining workstation, equipped with a newly designed two-volume ablation cell and coupled with a quadrupole ICP-MS, is presented here. The system was tuned routinely to achieve sensitivities in the range of 3000 cps/μg g⁻¹ for ²³⁸U (< 2% RSD), with a 34 μm spot size, at 5 Hz and ∼ 8 J cm⁻², while ablating the NIST SRM 612 glass reference material. The system was capable of providing fast (< 1.5 minutes each analysis) and precise (generally < 1.5% 1s errors) ²⁰⁶Pb/²³⁸U zircon ages. The ages of widely used reference material zircons (Plesovice, 337 Ma; Temora, 416 Ma; R33, 418 Ma; Sri Lanka, 564 Ma; 91500, 1065 Ma) could be precisely matched, with an accuracy on isotopic ratios that ranged from ∼ 2 to ∼ 6%, depending on the homogeneity of the natural reference materials.     

Pedo-geochemical baseline content levels and soil quality reference values of trace elements in soils from the Mediterranean (Castilla La Mancha, Spain)

To evaluate trace element soil contamination, geochemical baseline contents and reference values need to be established. Pedo-geochemical baseline levels of trace elements in 72 soil samples of 24 soil profiles from the Mediterranean, Castilla La Mancha, are assessed and soil quality reference values are calculated. Reference value contents (in mg kg^?1) were: Sc 50.8; V 123.2; Cr 113.4; Co 20.8; Ni 42.6; Cu 27.0; Zn 86.5; Ga 26.7; Ge 1.3; As 16.7; Se 1.4; Br 20.1; Rb 234.7; Sr 1868.4; Y 38.3; Zr 413.1; Nb 18.7; Mo 2.0; Ag 7.8; Cd 4.4; Sn 8.7; Sb 5.7; I 25.4; Cs 14.2; Ba 1049.3; La 348.4; Ce 97.9; Nd 40.1; Sm 10.7; Yb 4.2; Hf 10.0; Ta 4.0; W 5.5; Tl 2.3; Pb 44.2; Bi 2.2; Th 21.6; U 10.3. The contents obtained for some elements are below or close to the detection limit: Co, Ge, Se, Mo, Ag, Cd, Sb, Yb, Hf, Ta, W, Tl and Bi. The element content ranges (the maximum value minus the minimum value) are: Sc 55.0, V 196.0, Cr 346.0, Co 64.4, Ni 188.7, Cu 49.5, Zn 102.3, Ga 28.7, Ge 1.5, As 26.4, Se 0.9, Br 33.0 Rb 432.7, Sr 3372.6, Y 39.8, Zr 523.2, Nb 59.7, Mo 3.9, Ag 10.1, Cd 1.8, Sn 75.2, Sb 9.9, I 68.0, Cs 17.6, Ba 1394.9, La 51.3, Ce 93.5, Nd 52.5, Sm 11.2, Yb 4.2, Hf 11.3, Ta 6.3, W 5.2, Tl 2.1, Pb 96.4, Bi 3.0, Th 24.4, U 16.4 (in mg kg^?1). The spatial distribution of the elements was affected mainly by the nature of the bedrock and by pedological processes. The upper limit of expected background variation for each trace element in the soil is documented, as is its range as a criterion for evaluating which sites may require decontamination.     

Winter synoptic-scale variability over the Mediterranean Basin under future climate conditions as simulated by the ECHAM5

Changes of the winter climate in the Mediterranean Basin (MB) for future A2 conditions are investigated for the period 2071–2100 and compared with the control period 1961–1990. The analysis is based on time-slice simulations of the latest version of the ECHAM model. First, the control simulation is evaluated with reanalysis data. The emphasis is given to synoptic and large-scale features and their variability in the MB. The model is found to be capable of reproducing the main features of the MB and southern Europe in the winter season. Second, the A2 simulation is compared with the control simulation, revealing considerable changes of the synoptic variability. Focusing on the synoptic spatio-temporal scale aims to unfold the dynamic background of the climatic changes. The Mediterranean cyclones, which are individually detected and tracked, decrease by 10% in the Western Mediterranean (WM) whereas no significant change is found in the Eastern Mediterranean. The cyclone intensity is slightly reduced in the entire region. To understand these changes, the underlying dynamical background is analyzed. It is found that changes in baroclinicity, static stability, transformation from eddy kinetic energy to kinetic energy of the mean flow and stationary wave activity are significant in particular in the WM and the coastline of North Africa. The reduction of cyclonic activity severely impacts the precipitation mainly in the southern part of the WM.     

Towards integrated governance for water, health and social–ecological systems: The watershed governance prism

This article proposes a shift toward the integrated governance of watersheds as a basis for fostering health, sustainability and social–ecological resilience. The authors suggest that integrated watershed governance is more likely when different perspectives, including health and well-being, are explicitly understood, communicated, and sought as co-benefits of watershed management. A new conceptual device – the watershed governance prism – is introduced in relation to the multiple facets of governance that characterize contemporary water resources management and examined as an integrative framework to link social and environmental concerns with the determinants of health in the watershed context. The authors assess the diagnostic and communicative potential of such a framework, discussing its utility as a concise depiction of multiple, interacting policy priorities and as a guide to integrate different research and policy domains into the governance of water, health and social–ecological systems.     

Quantifying subglacial bed roughness in Antarctica: implications for ice-sheet dynamics and history

Glaciated landscapes consist of complex assemblages of landforms resulting from ice flow dynamic regimes and ice-sheet history, superimposed over, and in turn modifying, preglacial topography, lithology and geological structure. Insights into the formation of glaciated landscapes can, in principle, be obtained by analysing modern ice-sheet beds, but terrain analyses beneath modern ice sheets are restricted by the inaccessibility of the bed. It is, however, possible to quantify roughness, the vertical variation of the subglacial interface with horizontal distance, along two-dimensional images of the bed obtained from radio-echo sounding (RES). Here we collate several case studies from Antarctica, where roughness calculations have been used as a glaciological tool to infer basal processes and ice-sheet history over large (>500 km²) areas. We present two examples from West Antarctica, which demonstrate the utility of bed roughness in determining the presence and extent of subglacial sediments, glacial dynamics and former ice-sheet size. We also present two examples from East Antarctica, which illustrate how roughness provides knowledge of ice-sheet dynamics in the interior and pre-Quaternary ice-sheet histories. In modern ice-sheet settings, characterising bed roughness along RES tracks has the twin advantages of being relatively simple to calculate while producing informative subsurface data, and is especially powerful at furthering understanding when coupled with knowledge of ice flow from field, satellite and modelling investigations. The technique also offers significant potential for the comparison of modern and former ice-sheet terrains, contributing to an improved understanding of the formation and evolution of glaciated landscapes.     

Sediment sources of northern Québec and Labrador glacial deposits and the northeastern sector of the Laurentide Ice Sheet during ice-rafting events of the last glacial cycle

Provenance studies of anomalously high-flux layers of ice-rafted detritus (IRD) in North Atlantic sediments of the last glacial cycle show evidence for massive iceberg discharges coming from the Hudson Strait region of the Laurentide Ice Sheet (LIS). Although these so-called Heinrich events (H events) are commonly thought to be associated with abrupt drawdown of the LIS interior, uncertainties remain regarding the sector(s) of this multi-domed ice sheet that conveyed ice through Hudson Strait. In Northern Québec and Labrador (NQL), large-scale patterns of glacial lineations indicate massive ice flows towards Ungava Bay and Hudson Strait that could reflect the participation of the Labrador–Québec ice dome in H events. Here we evaluate this hypothesis by constraining the source of NQL glacial deposits, which provide an estimate of the provenance characteristics of IRD originating from this sector. Specifically, we use ⁴⁰Ar/³⁹Ar ages of detrital hornblende grains in 25 till samples distributed along a latitudinal transect (lat. 58°) extending east and west of Ungava Bay. The data show that tills located west and southwest of the Ungava Bay region are largely dominated by hornblende grains with Archean ages (>2.6 Ga), while tills located east of Ungava Bay are characterized by grains with early Paleoproterozoic ages (2.0–1.8 Ga), although most samples contain a few Archean-age grains. IRD derived from the NQL region should thus be characterized by a large proportion of Archean-age detrital grains, which contrasts significantly with the predominant Paleoproterozoic ⁴⁰Ar/³⁹Ar ages (1.8–1.6 Ga) typically reported for the dominant age population of hornblende grains in H layers. Comparisons with IRD through the last glacial cycle from a western North Atlantic core off Newfoundland do not show evidence for any prominent ice-rafted event with the provenance characteristics of NQL glacial deposits, thereby suggesting that significant ice-calving event(s) from the Labrador–Québec sector may have been limited throughout that interval. Although these results tend to point towards a relative stability of this ice dome during H events, our study also indicates that further provenance work is required on IRD proximal to the Hudson Strait mouth in order to constrain with a greater confidence the sector(s) of the LIS that fed ice into Hudson Strait during H events. Alternatively, these results and other paleogeographic considerations tend to support models suggesting that part of the Ungava Bay glacial lineations could be associated with a Late-Glacial ice flow across Hudson Strait.     

Rapid climate change in the Upper Palaeolithic: the record of charcoal conifer rings from the Gravettian site of Dolní Vĕstonice,Czech Republic

Precisely how Upper Palaeolithic human ecology was shaped by changing climate during the Pleniglacial remains a matter of debate, for while this generally cold period is now understood to include complex and often rapid flux in climate, there are still considerable difficulties in resolving climatic variations at particular times and places — derived from various lines of proxy evidence — with the high-resolution proxy record of temperature changes from oxygen isotope analysis of the Greenland ice-cores.In this paper we apply the methodology of large-scale flotation to newly excavated contexts from the Upper Palaeolithic (Gravettian) site of Dolní V?stonice II, Czech Republic, to explore the potential of charcoal — as a natural archive of environmental information — to offer information on environmental change towards the end of the middle pleniglacial during Oxygen Isotope Stage 3, between c. 32,500 and 31,200 Cal yr BP. The results of an analysis of ring widths and other anatomical features — interpreted alongside micromorphological data — indicate that this charcoal may capture a higher-resolution record of the changing climatic conditions during which humans were first expanding into these hitherto marginal ecologies and, consequently, shed new light upon the complexity of the lifeways that enabled them to do so.