δ53Cr values of catchment runoff exhibit seasonality regardless of bedrock Cr concentrations: Role of periodically changing chromium export fluxes

One pre-requisite for the construction of a global chromium isotope mass balance is detailed understanding of Cr isotope systematics in the critical zone where redox-processes can modify the isotope signature of geogenic Cr input into the hydrosphere. A Cr isotope inventory of bedrock, soil, and runoff was performed in a Central European headwater catchment underlain by amphibolite, situated in the vicinity of two previously studied catchments underlain by different bedrock types (serpentinite and leucogranite). Fresh bedrock in the amphibolite catchment NAZ contained ~300 mg/kg Cr, serpentinite at PLB contained ~800 mg/kg Cr, and leucogranite at LYS contained ~2 mg/kg Cr. Monthly hydrochemical monitoring at all three sites revealed higher Cr(VI) export fluxes in winter than in summer. NAZ was characterized by a distinct seasonality in the δ⁵³Cr values, with minima during winter/spring snowmelts (−0.35‰) and maxima during dry summers (0.40‰). Similar seasonality in δ⁵³Cr values had been reported from PLB and LYS. Bedrock at all three sites had similar Cr isotope composition close to −0.10‰, a value indistinguishable from the δ⁵³Cr value of bulk silicate Earth (BSE). Positive mean δ⁵³Cr value of NAZ runoff indicated Cr-isotope fractionations during weathering of geogenic Cr(III), combined with adsorption of the resulting Cr(VI) on soil particles during pedogenesis. However, the mass-weighted mean δ⁵³Cr of NAZ runoff was lower (−0.08‰), indistinguishable from the Cr isotope signature of bedrock. The same pattern of lower mass-weighted mean δ⁵³Cr values of runoff, compared to arithmetic mean δ⁵³Cr values of runoff, were observed also at PLB and LYS. We suggest that elevated Cr runoff fluxes in winter remove some of the residual isotopically light Cr that accumulated in the soil during summer. Seasonality in runoff δ⁵³Cr values appears to be a relatively widespread phenomenon, de-coupled from Cr availability for chemical weathering.     

Moisture characteristics and their point pedotransfer functions for coarse‐textured tropical soils differing in structural degradation status

The effect of soil structure on hydraulic pedotransfer functions (PTFs) in tropical soils with similar mineralogy and texture has not been well documented. Structurally contrasting soils from representative locations in southeastern Nigeria were analyzed for moisture retention at 0, 6, 10, 33, 100, 300 and 1500 kPa among other properties. They were grouped by depth (topsoils or subsoils) and also by their structural degradation status into low‐ and high‐stability soils, corresponding to organic matter (OM):[silt + clay] of <7.5 and >7.5%, respectively. Soil depth and structural stability influenced the soil moisture characteristic curves. The data were fitted to three tropical point PTFs, but none of them proved appropriate for predicting moisture retention in the soils. We therefore derived new ones using multiple linear stepwise regressions before and after the dataset grouping and compared their performances by means of cross‐validation. Moisture retention in the soils (sand content, 73.2–93.8%) could not be calibrated from texture and OM concentration alone, until when bulk density, total porosity and microporosity were included among the regressors. Microporosity's role was particularly outstanding at all matric potentials but the 1500 kPa. The ensuing PTFs represent a good fit for the soil moisture retention data. The two grouping strategies resulted in lower SE of the estimates in some cases, but this did not enhance the performances of the concerned PTFs. At the 1500 kPa, however, the PTF incorporating all datasets performed better than separate PTFs for topsoils/subsoils but worse than the one for high‐stability soils. Information on soil structure can therefore benefit PTF derivation for kaolinite‐dominated, coarse‐textured tropical soils at all the matric potentials considered. Copyright © 2012 John Wiley & Sons, Ltd.     

Geotechnical Behavior and Physico-Chemical Changes of Lime-Treated and Cement-Treated Silty Soil

Geotechnical and Geological Engineering - An investigation performed on the interactions of silty soil treated with cement or lime demonstrates the strong relationship between microstructural...     

Engineering Geological Properties of Building Stones from the North-Eastern Part of the Vienna Basin in the Western Carpathians

Geotechnical and Geological Engineering - This research focuses on assessing the most important physical and mechanical properties of rocks that were quarried from the north-eastern part of the...     

Sensitivity of tidal marshes as recorders of major megathrust earthquakes: constraints from the 25 December 2016 Mw 7.6 Chiloé earthquake,Chile

We present evidence of land-level change resulting from the 2016 M_w 7.6 Chiloé earthquake from tidal wetlands along the southern coastline of Isla de Chiloé, Chile, to test criteria for the detection of low-level, <0.1 m, coseismic land-level change. In order to record coseismic land-level change in tidal wetland sediments, both the creation and preservation thresholds must be exceeded. High-resolution diatom analyses of sediment blocks at two tidal marshes reveal that the 2016 earthquake exceeded the creation threshold and a statistically significant change in diatom assemblage is recorded. In contrast, the preservation threshold was not exceeded and the record of coseismic land-level motion is not preserved at any location visited. After nine months, interseismic and coseismic changes are statistically indistinguishable. The most sensitive part of the tidal wetland is not consistent between research locations, possibly as a result of changes in sedimentation after the earthquake. We compare records of change from great earthquakes in Alaska with the record from the Chiloé earthquake to explore the detection limit. We propose that coastal palaeoseismological records are highly likely to underestimate the frequency of major (M_w 7–8) earthquakes, with important implications for recurrence intervals and assessment of future seismic hazards.     

Lateglacial and Holocene environmental history of the central Kola region,northwestern Russia revealed by a sediment succession from Lake Imandra

Bolshaya Imandra, the northern sub-basin of Lake Imandra, was investigated by a hydro-acoustic survey followed by sediment coring down to the acoustic basement. The sediment record was analysed by a combined physical, biogeochemical, sedimentological, granulometrical and micropalaeontological approach to reconstruct the regional climatic and environmental history. Chronological control was obtained by ¹⁴C dating, ¹³⁷Cs, and Hg markers as well as pollen stratigraphy and revealed that the sediment succession offers the first continuous record spanning the Lateglacial and Holocene for this lake. Following the deglaciation prior to c. 13 200 cal. a BP, the lake's sub-basin initially was occupied by a glacifluvial river system, before a proglacial lake with glaciolacustrine sedimentation established. Rather mild climate, a sparse vegetation cover and successive retreat of the Scandinavian Ice Sheet (SIS) from the lake catchment characterized the Bølling/Allerød interstadial, lasting until 12 710 cal. a BP. During the subsequent Younger Dryas chronozone, until 11 550 cal. a BP, climate cooling led to a decrease in vegetation cover and a re-advance of the SIS. The SIS disappeared from the catchment at the Holocene transition, but small glaciers persisted in the mountains at the eastern lake shore. During the Early Holocene, until 8400 cal. a BP, sedimentation changed from glaciolacustrine to lacustrine and rising temperatures caused the spread of thermophilous vegetation. The Middle Holocene, until 3700 cal. a BP, comprises the regional Holocene Thermal Maximum (8000–4600 cal. a BP) with relatively stable temperatures, denser vegetation cover and absence of mountain glaciers. Reoccurrence of mountain glaciers during the Late Holocene, until 30 cal. a BP, presumably results from a slight cooling and increased humidity. Since c. 30 cal. a BP Lake Imandra has been strongly influenced by human impact, originating in industrial and mining activities. Our results are in overall agreement with vegetation and climate reconstructions in the Kola region.     

Spatio‐temporal variability of zooplankton biomass and environmental control in the Northern Benguela Upwelling System: field investigations and model simulation

Spatial and temporal distribution patterns of zooplankton are highly variable in the Northern Benguela Upwelling System. We studied the distribution of zooplankton (size class ≥ 0.33 mm) and used field data from four cruises that took place between March 2008 and February 2011, as well as simulation results of a regional ecosystem model. Remotely sensed sea surface temperatures (SST) and surface chlorophyll concentrations were analysed to investigate environmental influences on zooplankton biomass. The Intense Benguela Upwelling Index showed a distinct seasonal signal throughout the years and the highest upwelling peaks in August/September. Even though surface chlorophyll concentrations were very variable throughout the year, the highest concentrations were always detected in September, following the upwelling of nutrient‐rich water. In field catches, zooplankton biomass concentration in the upper 200 m was highest above the outer shelf and shelf‐break in December 2010 and February 2011, i.e. 6 months after the upwelling peaks. In contrast, zooplankton biomass simulated by the model in the surface water was highest in September. In March/April, biomass maxima were typically measured in the field at intermediate water depths, but the vertical distribution was also affected by extensive oxygen minimum zones. The ecosystem model reproduced this vertical pattern. Although general trends were similar, simulation data of zooplankton standing stocks overestimated the field data by a factor of 3. In upwelling systems, food webs are generally considered to be short and dominated by large cells. However, our field data indicate more small‐sized zooplankton organisms above the shelf than offshore.     

Magnetic,in situ,mineral characterization of Chelyabinsk meteorite thin section

Magnetic images of Chelyabinsk meteorite's (fragment F1 removed from Chebarkul lake) thin section have been unraveled by a magnetic scanning system from Youngwood Science and Engineering (YSE) capable of resolving magnetic anomalies down to 10^?3 mT range from about 0.3 mm distance between the probe and meteorite surface (resolution about 0.15 mm). Anomalies were produced repeatedly, each time after application of magnetic field pulse of varying amplitude and constant, normal or reversed, direction. This process resulted in both magnetizing and demagnetizing of the meteorite thin section, while keeping the magnetization vector in the plane of the thin section. Analysis of the magnetic data allows determination of coercivity of remanence (B_cr) for the magnetic sources in situ. Value of B_cr is critical for calculating magnetic forces applicable during missions to asteroids where gravity is compromised. B_cr was estimated by two methods. First method measured varying dipole magnetic field strength produced by each anomaly in the direction of magnetic pulses. Second method measured deflections of the dipole direction from the direction of magnetic pulses. B_cr of magnetic sources in Chelyabinsk meteorite ranges between 4 and 7 mT. These magnetic sources enter their saturation states when applying 40 mT external magnetic field pulse.     

Tropical Pacific – mid-latitude teleconnections in medieval times

Terrestrial and marine late Holocene proxy records from the western and central US suggest that climate between approximately 500 and 1350 a.d. was marked by generally arid conditions with episodes of severe centennial-scale drought, elevated incidence of wild fire, cool sea surface temperatures (SSTs) along the California coast, and dune mobilization in the western plains. This Medieval Climate Anomaly (MCA) was followed by wetter conditions and warming coastal SSTs during the transition into the “Little Ice Age” (LIA). Proxy records from the tropical Pacific Ocean show contemporaneous changes indicating cool central and eastern tropical Pacific SSTs during the MCA, with warmer than modern temperatures in the western equatorial Pacific. This pattern of mid-latitude and tropical climate conditions is consistent with the hypothesis that the dry MCA in the western US resulted (at least in part) from tropically forced changes in winter NH circulation patterns like those associated with modern La Niña episodes. We examine this hypothesis, and present other analyses showing that the imprint of MCA climate change appears in proxy records from widely distributed regions around the planet, and in many cases is consistent with a cool medieval tropical Pacific. One example, explored with numerical model results, is the suggestion of increased westerlies and warmer winter temperatures over northern Europe during medieval times. An analog technique for the combined use of proxy records and model results, Proxy Surrogate Reconstruction (PSR), is introduced.