Automatic sampling of stream water during storm events in small remote catchments

In order to study the relationship between water composition and stream flow rate, it is desirable to sample at a frequency related to flow rate, especially during storm events. In a rural catchment of 18 ha near Oxford, the rate of rainfall was found to be linearly related to discharge on the rising limb of the stream hydrograph. A sampling system was therefore designed in which electrical pulses from a tipping-bucket raingauge were used to initiate and control the action of an automatic water sampler. A threshold rainfall intensity is set above which sampling commences. Sampling then continues at regular increments of rainfall until the intensity drops below the threshold, after which sampling occurs at regular intervals during the period that the stream flow reverts to normal. The CMOS electrical circuits which control the sampling also operate a cassette tape recorder which records the time of each tip of the raingauge and operation of the sampler. Since the sytem is designed to impose very little additional load on the battery which powers the water sampler, and can operate unattended for at least a fortnight, it is ideal for use in small, remote catchments. The system has been extended to include measurements of water temperature and could provide other measurements as well.     

Stream-sediment geochemical prospecting for uranium in the paleozoic of the Belgian ardennes

During the years 1979 and 1980, a preliminary program of uranium exploration in the Paleozoic of the Belgian Ardennes was carried out under the sponsorship of the Commission of European Communities. The Laboratory of Mineralogy of the Polytechnic Faculty of Mons was charged with the radiometric section of the program, the Geochemistry Laboratory of the Free University of Brussels with the hydrogeochemical exploration, and the Geochemistry Laboratory of the University of Louvain with the stream sediment exploration. The Geological Survey of Belgium had the responsibility for coordinating the three programs, the statistical and computer treatment of the data, and the compilation of the different maps.Orientation studies at the Geochemistry Laboratory of the University of Louvain showed that a positive geochemical response for uranium could be obtained with bank sampling, which consists of collecting colluvium and alluvium on both sides of the rivers. This necessitates a large sampling density of about one sample per km² (10 205 samples from an area of 11 000 km²).The frequency distribution of the values of uranium follows the lognormal law with a geometric mean of 1.06 ppm and a threshold of 2.36 ppm (P= 0.954). The anomalies (> 3 ppm) fall into three main areas each in a different geological setting: (1) at the periphery of the Cambro-Silurian Massif of Stavelot; (2) within the transition beds between the Visean and Namurian; and (3) in the lower Devonian of the central Ardennes.The first two areas coincide with zones of known radiometric anomalies and of the occurrence of uraniferous minerals.In the third zone, follow-up work has led to the discovery of a uraniferous mineral assemblage consisting of a weathered mass of iron oxide, leucoxene and phosphates.Statistical analyses of the results indicate no significant relationship between U and either organic carbon or Mn, a negative correlation between U and carbonate and pH, and a good positive correlation between U and Cu, V and Fe. The last correlation may indicate an association of U, V, and Cu with iron oxides formed during meteoric alteration.     

Carbon and hydrogen isotopic compositions of the NBS 22 and NBS 21 stable isotope reference materials: An inter-laboratory comparison

Measurement of 17 laboratories on the stable isotope reference materials, NBS 22 lubricating oil and NBS 21 graphite, resulted in a revised calibration on the PDB scale. NBS 22 ¹³C/¹²C ratios of all laboratories did not demonstrate a gausssian distribution. Therefore, values which resulted from direct comparison with NBS 20 carbonate standards were selected the mean value of which is $\text{?29.81 ± 0.06?}$; this value is recommended as new value for NBS 22. The reported variations in δ¹³C for NBS 21 were consistent within the accuracies for single meaurements; the mean value is ?28.16 ± 0.01. The variations of D/H ratios of NBS 22 also were consistent with the accuracy quoted, with a mean value of ?119?.     

Low-pressure differentiation of tholeiitic lavas as recorded in segregation veins from Reykjanes (Iceland), Lanzarote (Canary Islands) and Masaya (Nicaragua)

Segregation veins are common in lava sheets and result from internal differentiation during lava emplacement and degassing. They consist of evolved liquid, most likely replaced by gas-filter pressing from a ∼50% crystallised host lava. Pairs of samples, host lavas and associated segregation veins from the Reykjanes Peninsula (Iceland), Lanzarote (Canary Islands) and the Masaya volcano (Nicaragua) show extreme mineralogical and compositional variations (MgO in host lava, segregation veins and interstitial glass ranges from 8–10 wt%, 3–6 wt%, and to less than 0.01 wt%, respectively). These samples allow the assessment of the internal lava flow differentiation mechanism, since both the parental and derived liquid are known in addition to the last magma drops in the form of late interstitial glasses. The mineralogical variation, mass-balance calculated from major- and trace element composition, and transitional metal partition between crystals and melts are all consistent with fractional crystallisation as the dominant differentiation mechanism. The interstitial glasses are highly silicic (SiO₂ = 70–80 wt%) and represent a final product of high-degree (75–97%) fractional crystallisation of olivine tholeiite at a pressure close to one atmosphere. The tholeiitic liquid-line-of-decent and the composition of the residual melts are governed by the K₂O/Na₂O of the initial basaltic magma. The granitic minimum is reached if the initial liquid has a high K₂O/Na₂O whereas trondhjemitic composition is the final product of magma with low initial K₂O/Na₂O. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Initiation and growth of salt-based thrust belts on passive margins: results from physical models

Scaled sandbox models simulated primary controls on the kinematics of the early structural evolution of salt‐detached, gravity‐driven thrust belts on passive margins. Models had a neutral‐density, brittle overburden overlying a viscous décollement layer. Deformation created linked extension–translation–shortening systems. The location of initial brittle failure of the overburden was sensitive to perturbations at the base of the salt. Salt pinch‐out determined the seaward limit of the thrust belt. The thrust belts were dominated by pop‐up structures or detachment folds cut by break thrusts. Pop‐ups were separated by flat‐bottomed synclines that were partially overthrust. Above a uniformly dipping basement, thrusts initiated at the salt pinch‐out then consistently broke landward. In contrast, thrust belts above a seaward‐flattening hinged basement nucleated above the hinge and then spread both seaward and landward. The seaward‐dipping taper of these thrust belts was much lower than typical, frictional, Coulomb‐wedge models. Towards the salt pinch‐out, frictional resistance increased, thrusts verged strongly seawards and the dip of the taper reversed as the leading thrust overrode this pinch‐out. We attribute the geometry of these thrust belts to several causes. (1) Low friction of the basal décollement favours near‐symmetric pop‐ups. (2) Mobile salt migrates away from local loads created by overthrusting, which reduces the seaward taper of the thrust belt. (3) In this gravity‐driven system, shortening quickly spreads to form wide thrust belts, in which most of the strain overlapped in time.     

Monitoring overburden layer changes and fault movements from time-lapse seismic data on the Valhall Field

A method developed by Røste et al. , which discriminates between layer thickness and velocity changes, is tested on pre-stack time-lapse seismic ocean bottom cable (OBC) data from the Valhall Field. A key parameter in this discrimination process is the dilation factor, α, which is the relative velocity change divided by the relative thickness change within a given layer. The high quality and good repeatability of the OBC data enables us to estimate α with a reasonable accuracy for α-values between 0 and −5. For α-values below −5, complementary information, like for instance geomechanics is required. For the top reservoir horizon we estimate a maximum subsidence of 0.50 m ± 0.29 m and a corresponding velocity decrease for the sequence from the seabed to the top reservoir of 2.0 m s⁻¹± 0.40 m s⁻¹.
Time-lapse distortion patterns with characteristic time-shift versus offset signatures are observed. The positions and vertical extents of the distortion zones are determined from ray path considerations and modelling. The distortion zones correlate with buried faults, indicating that a (time-lapse) distortion zone might be produced by a localized slip in a fault zone. We present an extended method which allows for vertical (in addition to lateral) variations in the relative thickness and velocity changes. This method can be viewed as a simplified version of time-lapse tomography, but involving fewer unknown parameters, giving more stability to the estimated changes in thickness and velocity. Using this technique, we are able to estimate α for positions with localized time-lapse distortions.     

Non-linear seismic behavior of structures with limited hysteretic energy dissipation capacity

This paper investigates the non-linear seismic behavior of structures such as slender unreinforced masonry shear walls or precast post-tensioned reinforced concrete elements, which have little hysteretic energy dissipation capacity. Even if this type of seismic response may be associated with significant deformation capacity, it is usually not considered as an efficient mechanism to withstand strong earthquakes. The objective of the investigations is to propose values of strength reduction factors for seismic analysis of such structures. The first part of the study is focused on non-linear single-degree-of-freedom (SDOF) systems. A parametric study is performed by computing the displacement ductility demand of non-linear SDOF systems for a set of 164 recorded ground motions selected from the European Strong Motion Database. The parameters investigated are the natural frequency, the strength reduction factor, the post-yield stiffness ratio, the hysteretic energy dissipation capacity and the hysteretic behavior model (four different hysteretic models: bilinear self-centring, with limited or without energy dissipation capacity, modified Takeda and Elastoplastic). Results confirm that the natural frequency has little influence on the displacement ductility demand if it is below a frequency limit and vice versa. The frequency limit is found to be around 2 Hz for all hysteretic models. Moreover, they show that the other parameters, especially the hysteretic behavior model, have little influence on the displacement ductility demand. New relationships between the displacement ductility demand and the strength reduction factor for structures having little hysteretic energy dissipation capacity are proposed. These relationships are an improvement of the equal displacement rule for the considered hysteretic models. In the second part of the investigation, the parametric study is extended to multi-degree-of-freedom (MDOF) systems. The investigation shows that the results obtained for SDOF systems are also valid for MDOF systems. However, the SDOF system overestimates the displacement ductility demand in comparison to the corresponding MDOF system by approximately 15%.