The pressure and temperature dependence of the elastic properties of single-crystal fayalite Fe2SiO4

The nine adiabatic elastic stiffness constants of synthetic single-crystal fayalite, Fe₂SiO₄, were measured as functions of pressure (range, 0 to 1.0 GPa) and temperature (range, 0 to 40° C) using the pulse superposition ultrasonic method. Summary calculated results for a dense fayalite polycrystalline aggregate, based on the HS average of our single-crystal data, are as follows: V_p = 6.67 km/s; V_s = 3.39km/s; K= 127.9 GPa; μ = 50.3 GPa; (?K/?P)_T = 5.2; (?μ/?P)_T=1.5;(?K/?T)_P= ?0.030 GPa/K;and,(?/?T)_P =-0.013 GPa/K (the pressure and temperature data are referred to 25° C and 1 atm, respectively). Accuracy of the single-crystal results was maintained by numerous cross and redundancy checks. Compared to the single-crystal elastic properties of forsterite, Mg₂SiO₄, the fayalite stiffness constants, as well as their pressure derivatives, are lower for each of the on-diagonal (C _ij for which i=j) values, and generally higher for the off-diagonal (C _ij for which i≠j) data. As a result, the bulk moduli (K) and dK/dP for forsterite and fayalite are very similar, but the rigidity modulus (μ) and dμ/dP for polycrystalline fayalite are much lower than their forsterite counterparts. The bulk compression properties derived from this study are very consistent with the static-compression x-ray results of Yagi et al. (1975). The temperature dependence of the bulk modulus of fayalite is somewhat greater (in a negative sense) than that of forsterite. The rigidity dependencies are almost equivalent. Over the temperature range relevant to this study, the elastic property results are generally consistent with the data of Sumino (1978), which were obtained using the RPR technique. However, some of the compressional modes are clearly discrepant. The elastic constants of fayalite appear to be less consistent with a theoretical HCP model (Leibfried 1955) than forsterite, reflecting the more covalent character of the Fe-O bonding in the former.     

Absolute measurements and computed values for Martian irradiance between 10.5 and 12.5 μm

The combination of seasonal and orbital changes in Martian insolation result in complex latitude dependent surface temperature variations that effect the total radiance of the planet as seen from the earth. These surface temperature variations have been calculated, based upon a computer simulation of the thermal environment of the planet. The temperature variations are then integrated to yield the total radiance of the planet as seen from the earth as a function of time. The absolute radiance of Mars was measured on April 4, 1971, with a balloon-borne radiometer system operating in the wavelength range between 10.5 and 12.5 μm. The average brightness temperature of the Mars disk determined from these measurements was 254°K with a 1 σ error of 4°K.     

River-aquifer interactions, geologic heterogeneity, and low-flow management

Low river flows are commonly controlled by river-aquifer exchange, the magnitude of which is governed by hydraulic properties of both aquifer and aquitard materials beneath the river. Low flows are often important ecologically. Numerical simulations were used to assess how textural heterogeneity of an alluvial system influences river seepage and low flows. The Cosumnes River in California was used as a test case. Declining fall flows in the Cosumnes River have threatened Chinook salmon runs. A ground water-surface water model for the lower river basin was developed, which incorporates detailed geostatistical simulations of aquifer heterogeneity. Six different realizations of heterogeneity and a homogenous model were run for a 3-year period. Net annual seepage from the river was found to be similar among the models. However, spatial distribution of seepage along the channel, water table configuration and the level of local connection, and disconnection between the river and aquifer showed strong variations among the different heterogeneous models. Most importantly, the heterogeneous models suggest that river seepage losses can be reduced by local reconnections, even when the regional water table remains well below the riverbed. The percentage of river channel responsible for 50% of total river seepage ranged from 10% to 26% in the heterogeneous models as opposed to 23% in the homogeneous model. Differences in seepage between the models resulted in up to 13 d difference in the number of days the river was open for salmon migration during the critical fall months in one given year.     

Yanama budyari gumada: reframing the urban to care as Darug Country in western Sydney

ABSTRACT

In non-urban places of Australia, caring-as-Country frames natural resource management (NRM) as a practice of reciprocal, more-than-human care-giving (S. Suchet-Pearson, S. Wright, K. Lloyd, and L. Burarrwanga. 2013. ‘Caring as Country: towards and ontology of co-becoming in natural resource management.’ Asia Pacific Viewpoint 54 (2): 185–197). Caring-as-Country is an idea that encapsulates the entangled, reciprocal relationships that people have with, and as part of, agentic more-than-human worlds. In more urbanised places, however, practices of caring-as-Country are often unrecognised, undervalued and undocumented. In this paper we make explicit practices of caring, healing and rejuvenation at Yellomundee Regional Park, Darug Country in western Sydney. Our discussion of care, entanglement and reciprocity at Yellomundee focuses on two specific activities that embody caring-as-Country: the return of cultural burns and sustained presence on Country in the form of Darug-led culture camps. The Darug principle of yanama budyari gumada, to ‘walk with good spirit’, embodies and invites new ways of thinking and practising intercultural caring-as-Country in heavily colonised, urban places like Yellomundee. As we document the practices arising from this invitation, we consider its far-reaching implications for NRM and planning, and we expand on the importance of geographies of care for unceded urban places.     

Evidence for temporally coherent increases in the abundance of small Discostella (Bacillariophyceae) species over the past 200 years among boreal lakes from the Experimental Lakes Area (Canada)

Journal of Paleolimnology - Increased relative abundances and accumulation rates of the small, centric diatom Discostella have been recorded in numerous paleolimnological investigations of north...     

Analytical scanning and transmission electron microscopy of laboratory impacts on Stardust aluminum foils: Interpreting impact crater morphology and the composition of impact residues

Abstract— The known encounter velocity (6.1 kms^?1) and particle incidence angle (perpendicular) between the Stardust spacecraft and the dust emanating from the nucleus of comet Wild‐2 fall within a range that allows simulation in laboratory light‐gas gun (LGG) experiments designed to validate analytical methods for the interpretation of dust impacts on the aluminum foil components of the Stardust collector. Buckshot of a wide size, shape, and density range of mineral, glass, polymer, and metal grains, have been fired to impact perpendicularly on samples of Stardust Al 1100 foil, tightly wrapped onto aluminum alloy plate as an analogue of foil on the spacecraft collector. We have not yet been able to produce laboratory impacts by projectiles with weak and porous aggregate structure, as may occur in some cometary dust grains. In this report we present information on crater gross morphology and its dependence on particle size and density, the pre‐existing major‐ and trace‐element composition of the foil, geometrical issues for energy dispersive X‐ray analysis of the impact residues in scanning electron microscopes, and the modification of dust chemical composition during creation of impact craters as revealed by analytical transmission electron microscopy. Together, these observations help to underpin the interpretation of size, density, and composition for particles impacted on the Stardust aluminum foils.     

Thrust tectonics in the south central pyrenees

Surface structural data and published stratigraphies are combined to construct two balanced and restored sections through the Nogueras Zone of the south central Pyrenees. The allochthonous Nogueras Zone units are interpreted as the foreland-dipping margin of a major antiformal stack in the Palaeozoic rocks of the Pyrenean Axial Zone. Their structural evolution is summarized in a hangingwall sequence diagram. This reinterpretation of the Nogueras Zone is incorporated into a new NS balanced and restored section from the centre of the Pyrenean Axial Zone to the Ebro Basin. A classical ‘Rocky Mountains’ piggy-back thrust model is employed and the resulting section is a significant departure from those previously published. It is argued that ‘gravity gliding’ has never been an important mechanism in the Alpine Pyrenees. Section restoration casts doubt on the correlation of the surface expression of the North Pyrenean Fault and the seismically detected Moho step beneath it.     

Aerogel keystones: Extraction of complete hypervelocity impact events from aerogel collectors

Abstract— In January 2006, the Stardust mission will return the first samples from a solid solar system body beyond the Moon and the first samples of contemporary interstellar dust ever collected. Although sophisticated laboratory instruments exist for the analysis of Stardust samples, techniques for the recovery of particles and particle residues from aerogel collectors remain primitive. Here, we describe our recent progress in developing techniques for extracting small volumes of aerogel, which we have called “keystones,” which completely contain particle impacts but minimize the damage to the surrounding aerogel collector. These keystones can be fixed to custom‐designed micromachined silicon fixtures (so called “microforklifts”). In this configuration, the samples are self‐supporting, which can be advantageous in situations where interference from a supporting substrate is undesirable. The keystones may also be extracted and placed onto a substrate without a fixture. We have also demonstrated the capability of homologously crushing these unmounted keystones for analysis techniques that demand flat samples.     

Garnet inclusions in diamond and the state of the upper mantle

Temperature and pressure estimates for Earth's upper mantle generally are based on indirect information derived from phase equilibria studies and the measurement of temperature and pressure dependent physical and chemical properties for relevant mantle materials. This paper describes an alternative approach, based on solid-inclusion piezothermometry, which utilizes the thermoelastic properties of direct mantle derived mineral samples. In particular, this study provides the theoretical development, based on the Murnaghan equation of state for solids, for a simple method of calculating isomeke lines for host and inclusion minerals of cubic symmetry which may be extrapolated accurately to upper mantle pressure and temperature conditions. The method is demonstrated for the particular case of garnet inclusions in diamond, for which adequate laboratory thermoelastic data are available. A specific application is made in the evaluation of the depth of formation of the D1 garnet-diamond inclusion system described by Harris et al. (1970). The pressure and temperature conditions of inclusion formation lie along the calculated isomeke line within the range constrained by recent graphite-diamond phase equilibria data. However, because the isomeke line for the garnet-diamond system and the graphite-diamond phase transition are very similar in slope, a further constraint is required. Assuming, therefore, that temperature in the upper mantle is bounded by the “Oceanic” and “Shield” geotherms of Clark and Ringwood (1964), the present results indicate that the D1 garnet-diamond system formed within the depth range 138 to 155 km (about 45 to 53 kbar pressure). This result, which relates to the genesis of kimberlite xenoliths, is generally consistent with the results of other studies which utilize phase equilibria data.     

RARE EARTH ELEMENT ABUNDANCES IN SEPARATED PHASES OF MAYO BELWA,AN ENSTATITE ACHONDRITE

Separated fractions from the Mayo Belwa aubrite have been analysed for the rare earth elements (REE). The data show no ytterbium anomalies but the feldspar and magnetic fractions show complementary europium anomalies. The separated phases together account for the total REE abundances in the bulk meteorite which are about 0.5 times chondritic. The REE content of the feldspar is greater than that of the bulk meteorite. The partition coefficients for the REE between feldspar and orthopyroxene are about 10 times (in favour of the feldspar) those of the nearest equivalent terrestrial feldspar/orthopyroxene pairs, implying that the distribution of the REE which would result from equilibrium co-crystallisation from a single liquid has been disturbed by a later event. This occurred more recently than 4.33 b.y. ago and resulted in a redistribution of the REE between the feldspar and a REE enriched residue. However, the REE patterns of the minerals are very like those of terrestrial equivalents and appear to be the result of igneous cumulus processes on a parent body rather than condensation of dust from a nebular gas.