Centennial-to-millennial fluctuations in July temperatures in North Finland as recorded by timberline tree rings of Scots pine

A tree-ring proxy of summer temperature anomalies for northern Finland for the past 7500 yr was analyzed using Fourier spectrum and wavelet approaches. Multicentennial (250-450 yr) variability is present in the proxy record during most of the time range. This variability is suggested to reflect low-frequency variability in the North Atlantic Oscillation. Century-scale (90-130 yr) variation is another important feature of the tree-ring proxy data during the Holocene and may be attributed to Glessberg solar activity variations. In addition, an approximately 2000-yr quasi-period is found in this temperature proxy data, similar to the millennial-scale variability, present in many climate records from the North Atlantic region. The results point to the importance of multiple forcings underlying significant Holocene climatic fluctuations.     

The Indonesian consumer market for clothing: Institutions, firms and organizational behaviours

The clothing industry is widely cited as an industrial sector that is embedded primarily in buyer-driven structures of global commodity chains in which retailers and brand-name companies, rather than manufacturers, are the key driving forces. Analysis of clothing production systems within the commodity chain literature, however, has been predominantly Western-centric, with little emphasis on similarities and/or differences between competitors in different institutional and societal contexts. Therefore, this paper explores the ways in which international and domestic clothing brand-owners compete for market shares within Indonesia. The analytical focus includes important issues such as the influence of the regulatory policy framework on firm-specific behaviour as well as applied marketing strategies within individual fashion segments.     

Spatial and temporal rockfall activity in a forest stand in the Swiss Prealps—A dendrogeomorphological case study

Rockfall is a major threat to settlements and transportation routes in large parts of the Alps. While protective forest stands in many locations undoubtedly reduce rockfall risk, little is known about the exact frequency and spatial distribution of rockfall activity in a given place or about how these parameters can be assessed. Therefore, the objective of the present study was to reconstruct rockfall events with dendrogeomorphological methods and to analyse the spatial and temporal rockfall activity in a subalpine forest stand. The study site is located in the transit zone of frequently passing, rather small rockfall fragments (mean diameter of 10 to 20 cm). In all, 33 stem discs from previously felled Picea abies trees found at the foot of Schwarzenberg in Diemtigtal (Swiss Prealps) were sampled, and a total number of 301 rockfall events were dated to between A.D. 1724 and 2002.Results showed that the spatial distribution of rockfall changed slightly with time, and that rockfall activity increased considerably over the last century. In contrast, rockfall magnitude presumably remained on a comparable level. The seasonal occurrence of rockfall showed a clear peak during the dormant season of trees, most probably in early spring. Furthermore, on a 10-year moving average basis, rockfall rates were positively correlated with mean annual as well as summer and winter temperatures. This means that higher temperatures resulted in increased rockfall activity. On the other hand, no correlation with annual or seasonal precipitation totals was revealed. Overall, this study provides an appropriate method for the detailed assessment of spatial and temporal variations in rockfall activity in a given place.     

Irradiance observations of the 1–8 Å solar soft X-ray flux from goes

The solar 0.5–8 soft X-ray flux was monitored by the NOAA Geostationary Operational Environmental Satellites (GOES) from 1974 to the present, providing a continuous record over two solar activity cycles. Attempts have been made to determine a soft X-ray (SXR) background flux by subtracting out solar flares (using the daily lowest flux level). The SXR background flux represents the quiescent SXR flux from heated plasma in active regions, and reflects similar (intermediate-term) variability and periodicities (e.g. 155-day period) as the SXR or hard X-ray (HXR) flare rate, although it is determined in non-flaring time intervals. The SXR background flux peaks late in Solar Cycle 21 (2–3 years after the sunspot maximum), similar to the flare rate measured in SXR, HXR, or gamma rays, possibly due the increasing complexity of coronal magnetic structures in the decay phase of the solar cycle. The SXR background flux appears to be dominated by postflare emission from the dominant active regions, while the contributions from the quiet Sun are appreciable in the Solar Minimum only (A1-level). Comparisons with full-disk integrated images from YOHKOH suggest that the presence of coronal holes can decrease the quietest SXR irradiance level by an additional order of magnitude, but only in the rare case of absence of active regions.Presented at IAU Colloquium No. 143, The Sun as a Variable Star: Solar and Stellar Irradiance Variations, Boulder, CO, June 20–25, 1993     

Analysis of the Major Fe Bearing Mineral Phases in Recent Lake Sediments by EXAFS Spectroscopy

Extended X-ray absorption fine structure (EXAFS) spectroscopy and chemical analyses were combined to determine the Fe bearing minerals in recent lake sediments from Baldeggersee (Switzerland). The upper section of a laminated sediment core, deposited under eutrophic conditions, was compared to the lower part from an oligotrophic period. Qualitative analysis of FeK EXAFS agreed well with chemical data: In the oligotrophic section Fe(II)–O and Fe(III)–O specieswere present, whereas a significant fraction of Fe(II)–S sulfides was strongly indicated in the eutrophic part. A statistical analysis was performed by least square fitting of normalized reference spectra. The set of reference minerals included Fe(III) oxides and Fe(II) sulfides, carbonates and phosphates. In the oligotrophic regime no satisfying fit was obtained using the set of reference spectra, indicating that siderite (FeCO₃) was not present in a significant amount in these carbonate-rich sediments. Simulated EXAFS spectra for a(Ca_x, Fe_1-x)CO₃solid solution allowed reconstructing the specificfeatures of the experimental spectra, suggesting that this phase was the dominant Fe carrier in the oligotrophic section of the core. In the eutrophic part, mackinawite was positively identified and represented the dominant Fe(II) sulfide phase. This finding agreed with chemical extraction, which indicated that18–40 mol% of Fe was contained in the acid volatile iron sulfide fraction. EXAFS spectra of the eutrophic section were best fitted by considering the admixture of mackinawite and the Fe–Ca carbonate phase inferred to be predominant in the oligotrophic regime.     

The Formation of Massive Sulfide Ores in Black Shales of the Eastern Caucasus: Evidence from the Kizil Dere Orefield

Issues pertaining to the genesis of massive sulfide deposits (Kizil Dere and others) embedded in Jurassic black shales of the eastern Caucasus are discussed on the basis of field materials. Major structural-dynamic constraints along with structural, lithological, and mineralogical indicators of the formation of such deposits have been established. These deposits are epigenetic objects formed during active deformations of clayey sequences and migration of metagenic waters over sources of deep ore-conducting fractures in structural and other traps. Therefore, they can be referred to the metagenic-hydrothermal type.     

Biochemical Characterization of Refractory Organic Substances

The characterization of refractory organic substances (ROS) is very complicated because of their heterogeneous structure. Size-exclusion chromatography with continuous detection of dissolved nitrogen (LC-DN), dissolved organic carbon (LC-DOC), and UV-absorbance (LC-UV) is a very useful analytical tool for the characterization of changes of ROS in natural aquatic systems and in technological treatment. The effect of natural, oxidative, and biochemical processes on formation and removal of ROS is described. Additionally the role of hydrolysable carbohydrates in the composition of ROS is presented.