Non‐mass‐dependent oxygen isotopic fractionation in smokes produced in an electrical discharge

Abstract— We report the first production of non‐mass‐dependently fractionated silicate smokes from the gas phase at room temperature from a stream of silane and/or pentacarbonyl iron in a molecular hydrogen (or helium) flow mixed with molecular oxygen (or nitrous oxide). The smokes were formed at the Goddard Space Flight Center (GSFC) at total pressures of just under 100 Torr in an electrical discharge powered by a Tesla coil, were collected from the surfaces of the copper electrodes after each experiment and sent to the University of California at San Diego (UCSD) for oxygen isotopic analysis. Transmission electron microscopy studies of the smokes show that they grew in the gas phase rather than on the surfaces of the electrodes. We hypothesize at least two types of fractionation processes occurred during formation of the solids: a mass‐dependent process that made isotopically lighter oxides compared to our initial oxygen gas composition followed by a mass‐independent process that produced oxides enriched in ¹⁷O and ¹⁸O. The maximum Δ¹⁷O observed is + 4.7‰ for an iron oxide produced in flowing hydrogen, using O2 as the oxidant. More typical displacements are 1–2‰ above the equilibrium fractionation line. The chemical reaction mechanisms that yield these smokes are still under investigation.     

White dwarf masses in magnetic cataclysmic variables: multi-temperature fits to Ginga data

One method of obtaining the mass of the white dwarf in magnetic cataclysmic variables (mCVs) is through their hard X-ray spectra. However, previous mass estimates using this method give lower limits because the temperature of the plasma in the post-shock region (where the hard X-rays are emitted) is lower than the temperature of the shock itself. In AM Her systems, the additional cooling of the post-shock plasma by cyclotron emission will further lower the derived mass. Here we present estimates of the masses of the white dwarf in 13 mCVs derived using Ginga data and a model in which X-rays are emitted from a multi-temperature emission region with the appropriate temperature and density profile. We include in the model reflection from the surface of the white dwarf and a partially ionized absorber. We are able to achieve good fits to the data. We compare the derived masses with previous estimates and the masses for larger samples of isolated white dwarfs and those in CVs.     

A revision of the Jurassic (Bathonian to Oxfordian) lithostratigraphy of the onshore Moray Firth Basin,north-east Scotland

Bathonian to Oxfordian strata occur onshore in two principal locations over 30 km apart on the coast of the Moray Firth, at Brora and Balintore. The existing lithostratigraphy has the same formation names applied to both successions despite profound differences, exemplified in their schemes of local members. Furthermore, three of the formation names include the same place name, and use obsolete lithological terms.     

Solute and geothermal flux monitoring using electrical conductivity in the Madison,Firehole, and Gibbon Rivers,Yellowstone National Park

The thermal output from the Yellowstone magma chamber can be estimated from the Cl flux in the major rivers in Yellowstone National Park; and by utilizing continuous discharge and electrical conductivity measurements the Cl flux can be calculated. The relationship between electrical conductivity and concentrations of Cl and other geothermal solutes (Na, SO₄, F, HCO₃, SiO₂, K, Li, B, and As) was quantified at monitoring sites along the Madison, Gibbon, and Firehole Rivers, which receive discharge from some of the largest and most active geothermal areas in Yellowstone. Except for some trace elements, most solutes behave conservatively and the ratios between geothermal solute concentrations are constant in the Madison, Gibbon, and Firehole Rivers. Hence, dissolved concentrations of Cl, Na, SO₄, F, HCO₃, SiO₂, K, Li, Ca, B and As correlate well with conductivity (R² > 0.9 for most solutes) and most exhibit linear trends. The 2011 flux for Cl, SO₄, F and HCO₃ determined using automated conductivity sensors and discharge data from nearby USGS gaging stations is in good agreement with those of previous years (1983–1994 and 1997–2008) at each of the monitoring sites. Continuous conductivity monitoring provides a cost- and labor-effective alternative to existing protocols whereby flux is estimated through manual collection of numerous water samples and subsequent chemical analysis. Electrical conductivity data also yield insights into a variety of topics of research interest at Yellowstone and elsewhere: (1) Geyser eruptions are easily identified and the solute flux quantified with conductivity data. (2) Short-term heavy rain events can produce conductivity anomalies due to dissolution of efflorescent salts that are temporarily trapped in and around geyser basins during low-flow periods. During a major rain event in October 2010, 180,000 kg of additional solute was measured in the Madison River. (3) The output of thermal water from the Gibbon River appears to have increased by about 0.2%/a in recent years, while the output of thermal water for the Firehole River shows a decrease of about 10% from 1983 to 2011. Confirmation of these trends will require continuing Cl flux monitoring over the coming decades.     

A simple method of magnetic declination fluctuation correction for long single-streamer positioning in a seismic survey

In single‐streamer acquisition, the use of acoustic transducers to constrain the receiver positions is not possible, thus implying the use of compass birds to gather information on the streamer location. The compasses are, however, sensitive to the declination of the local magnetic field of the earth, and local fluctuations not accounted for can degrade the accuracy of reconstructed positions. In order to correct these small‐scale fluctuations, we propose a simple deterministic method to calculate a spatial correction to apply to the compasses that enhances the positioning accuracy. The local compass declination is calculated after a first reconstruction on the whole survey area. This method was applied with success to navigation data from a 3D survey offshore Japan, and the positioning accuracy was improved to the level of the DGPS accuracy.     

The last interglacial sea-level high stand on the southern Cape coastline of South Africa

The continental margin of southern South Africa exhibits an array of emergent marginal marine sediments permitting the reconstruction of long-term eustatic sea-level changes. We report a suite of optical luminescence ages and supplementary amino acid racemization data, which provide paleosea-level index points for three sites on this coastline. Deposits in the Swartvlei and Groot Brak estuaries display tidal inlet facies overlain by shoreface or eolian facies. Contemporary facies relations suggest a probable high stand 6.0-8.5 m above modern sea level (amsl). At Cape Agulhas, evidence of a past sea-level high stand comprises a gravel beach (ca. 3.8 m amsl) and an overlying sandy shoreface facies (up to 7.5 m amsl). OSL ages between 138 ± 7 ka and 118 ± 7 ka confirm a last interglacial age for all marginal marine facies. The high stand was followed by a sea-level regression that was associated with the accumulation of eolian dunes dating to between 122 ± 7 ka and 113 ± 6 ka. These data provide the first rigorous numerical age constraints for last interglacial sea-level fluctuations in this region, revealing the timing and elevation of the last interglacial high stand to broadly mirror a number of other far-field locations.     

Petrogenesis of basalt–trachyte lavas from Olmoti Crater, Tanzania

Olmoti Crater is part of the Plio-Pleistocene Ngorongoro Volcanic Highland (NVH) in northern Tanzania to the south of Gregory Rift. The Gregory Rift is part of the eastern branch of the East African Rift System (EARS) that stretches some 4000 km from the Read Sea and Gulf of Aden in the north to the Zambezi River in Mozambique. Here, we (1) characterize the chemistry and mineral compositions of lavas from Olmoti Crater, (2) determine the age and duration of Olmoti volcanic activity through ⁴⁰Ar/³⁹Ar dating of Olmoti Crater wall lavas and (3) determine the genesis of Olmoti lavas and the relationship to other NVH and EARS volcanics and (4) their correlation with volcanics in the Olduvai and Laetoli stratigraphic sequences.Olmoti lavas collected from the lower part of the exposed crater wall section (OLS) range from basalt to trachyandesite whereas the upper part of the section (OUS) is trachytic. Petrography and major and trace element data reflect a very low degree partial melt origin for the Olmoti lavas, presumably of peridotite, followed by extensive fractionation. The ⁸⁷Sr/⁸⁶Sr data overlap whereas Nd and Pb isotope data are distinct between OLS and OUS samples. Interpretation of the isotope data suggests mixing of enriched mantle (EM I) with high-μ-like reservoirs, consistent with the model of Bell and Blenkinsop [Bell, K., Blenkinsop, J., 1987. Nd and Sr isotopic compositions of East African carbonatites: implications for mantle heterogeneity. Geology 5, 99–102] for East African carbonatite lavas. The isotope ratios are within the range of values defined by Oceanic Island Basalt (OIB) globally and moderate normalized Tb/Yb ratios (2.3–1.6) in these lavas suggest melting in the lithospheric mantle consistent with other studies in the region.⁴⁰Ar/³⁹Ar incremental-heating analyses of matrix and anorthoclase separates from Olmoti OLS and OUS lavas indicate that volcanic activity was short in duration, lasting 200 kyr from 2.01 ± 0.03 Ma to 1.80 ± 0.01 Ma. The age of Olmoti activity overlaps with ages reported for Ngorongoro Caldera, implying contemporaneous activity of multiple NVH volcanic centers during part of the eruption interval.Olmoti is considered the source for the bulk of interbedded volcanics and volcaniclastic deposits that comprise much of the upper Bed I section of nearby Olduvai Gorge, and part of the Laetoli sequence, both known for their well preserved fossils and archaeological remains. Age and chemical data reported here are compatible with those derived from tephra and lava interbedded in Bed I at Olduvai Gorge and from the Olpiro Beds at Laetoli.     

Short-term variability of suspended sediment and phytoplankton in Tampa Bay,Florida: Observations from a coastal oceanographic tower and ocean color satellites

We examined short-term phytoplankton and sediment dynamics in Tampa Bay with data collected between 8 December 2004 and 17 January 2005 from optical, oceanographic, and meteorological sensors mounted on a coastal oceanographic tower and from satellite remote sensing. Baseline phytoplankton (chlorophyll-a, Chl) and sediment concentrations (particle backscattering coefficient at 532 nm, bbp(532)) were of the order of 3.7 mg m⁻³ and 0.07 m⁻¹, respectively, during the study period. Both showed large fluctuations dominated by semidiurnal and diurnal frequencies associated with tidal forcing. Three strong wind events (hourly averaged wind speed >8.0 m s⁻¹) generated critical bottom shear stress of >0.2 Pa and suspended bottom sediments that were clearly observed in concurrent MODIS satellite imagery. In addition, strong tidal current or swells could also suspend sediments in the lower Bay. Sediments remained suspended in the water column for 2–3 days after the wind events. Moderate Chl increases were observed after sediment resuspension with a lag time of ˜1–2 days, probably due to release of bottom nutrients and optimal light conditions associated with sediment resuspension and settling. Two large increases in Chl with one Chl > 12.0 mg m⁻³ over ˜2 days, were observed at neap tides. For the study site and period, because of the high temporal variability in phytoplankton and sediment concentrations, a monthly snapshot can be different by −50% to 200% from the monthly “mean” chlorophyll and sediment conditions. The combination of high-frequency observations from automated sensors and synoptic satellite imagery, when available, is an excellent complement to limited field surveys to study and monitor water quality parameters in estuarine environments.