The stable aryl hydrocarbon receptor agonist potency of United Kingdom Continental Shelf (UKCS) offshore produced water effluents

The in vitro aryl hydrocarbon receptor (AhR) agonist potency of offshore produced water effluents, collected from the United Kingdom Continental Shelf, was determined using the dioxin responsive (DR)-chemically activated luciferase expression (CALUX) assay. Octadecylsilane (C18) solid phase extraction (SPE) extracts of produced water were exposed to DR-CALUX cells for 24 h in order to investigate the contribution in potency from compounds that are stable to metabolism by the CALUX cells during exposure. The stable AhR agonist potency determined over 24 h was highly variable and ranged from 1 to 430 ng TCDD TEQ_CALUX l⁻¹. These data reflect the highly variable composition of produced water discharges from different production fields. It is recommended that further work be performed to characterise the full range of stable dioxin like AhR agonists present in offshore produced water discharges using techniques such as bioassay-directed analysis.     

15,000-yr pollen record of vegetation change in the high altitude tropical Andes at Laguna Verde Alta, Venezuela

Pollen analysis of sediments from a high-altitude (4215 m), Neotropical (9°N) Andean lake was conducted in order to reconstruct local and regional vegetation dynamics since deglaciation. Although deglaciation commenced 15,500 cal yr B.P., the area around the Laguna Verde Alta (LVA) remained a periglacial desert, practically unvegetated, until about 11,000 cal yr B.P. At this time, a lycopod assemblage bearing no modern analog colonized the superpáramo. Although this community persisted until 6000 cal yr B.P., it began to decline somewhat earlier, in synchrony with cooling following the Holocene thermal maximum of the Northern Hemisphere. At this time, the pioneer assemblage was replaced by a low-diversity superpáramo community that became established 9000 cal yr B.P. This replacement coincides with regional declines in temperature and/or available moisture. Modern, more diverse superpáramo assemblages were not established until 4600 cal yr B.P., and were accompanied by a dramatic decline in Alnus, probably the result of factors associated with climate, humans, or both. Pollen influx from upper Andean forests is remarkably higher than expected during the Late Glacial and early to middle Holocene, especially between 14,000 and 12,600 cal yr B.P., when unparalleled high values are recorded. We propose that intensification of upslope orographic winds transported lower elevation forest pollen to the superpáramo, causing the apparent increase in tree pollen at high altitude. The association between increased forest pollen and summer insolation at this time suggests a causal link; however, further work is needed to clarify this relationship.     

The transmission to space of the light produced by lightning in the clouds of Venus

A Monte Carlo program by Thomason and Krider has been adapted to the Venus cloud geometry and optical properties. If lightning flashes occur within or just below the clouds, the fraction of photons of visible light escaping to space is 0.1–0.4, depending on the location of the flash. For flashes near the surface, only one blue photon in 10⁴ was found to escape; about 5% of the red ones are transmitted. Failure of the Pioneer Venus Orbiter to unambiguously detect optical lightning signals from space is not due to attenuation by the atmosphere and clouds. In any case, lightning is not acceptable as an explanation for ashen light.     

Impact cratering and spall failure of gabbro

Both hypervelocity impact and dynamic spall experiments were carried out on a series of well-indurated samples of gabbro to examine the relation between spall strength and maximum spall ejecta thickness. The impact experiments carried out with 0.04- to 0.2-g, 5- to 6-km/sec projectiles produced decimeter- to centimeter-sized craters and demonstrated crater efficiencies of 6 × 10^?9 g/erg, an order of magnitude greater than in metal and some two to three times that of previous experiments on less strong igneous rocks. Most of the crater volume (some 60 to 80%) is due to spall failure. Distribution of cumulative fragment number, as a function of mass of fragments with masses greater than 0.1 g yield values of b = d(log N_f)/d log(m) ?0.5 ?0.6, where N is the cumulative number of fragments and m is the mass of fragments. These values are in agreement or slightly higher than those obtained for less strong rocks and indicate that a large fraction of the ejecta resides in a few large fragments. The large fragments are plate-like with mean values of B/A and C/A 0.8 0.2, respectively (A = long, B = _termediate, and C = short fragment axes). The small equant-dimensioned fragments (with mass < 0.1 g and B ～ 0.1 mm) represent material which has been subjected to shear failure. The dynamic tensile strenght of San Marcos gabbro was determined at strain rates of 10⁴ to 10⁵ sec^?1 to be 147 ± 9 MPa. This is 3 to 10 times greater than inferred from quasi-static (strain rate 10⁰ sec^?1) loading experiments. Utilizing these parameters in a continuum fracture model predicts a tensile strenght of $\text{σ}{}_{\mathrm{<mtext>m</mtext>}}\text{∝}\text{ε}\text{?}{}^{\mathrm{[0.25–0.3]}}$, where ε is strain rate. It is suggested that the high spall strenght of basic igneous rocks gives rise to enhanced cratering efficiencies due to spall in the <10²-m crater diamter strength-dominated regime. Although the impact spall mechanism can enhance cratering efficiencies it is unclear that resulting spall fragments achieve sufficient velocities such that fragments of basic rocks can escape from the surfaces of planets such as the Moon or Mars.     

Pb diffusion in monazite: a combined RBS/SIMS study

We report measurements of Pb diffusion in both synthetic (CePO₄) and natural monazites run under dry, 1-atm conditions. Powdered mixtures of prereacted CePO₄ and PbZrO₃ were used as the source of Pb diffusant for “in-diffusion” experiments conducted in sealed Pt capsules for durations ranging from a few hours to several weeks. Following the diffusion anneals, Pb concentration profiles were measured with Rutherford Backscattering Spectroscopy (RBS) and supplemented by measurements with secondary ion mass spectrometry (SIMS). In order to evaluate potential compositional effects upon Pb diffusivity and simulate diffusional Pb loss that might occur in natural systems, we also conducted “out-diffusion” experiments on Pb-bearing natural monazites. In these experiments, monazite grains were surrounded by a synthetic zircon powder to act as a “sink.” Monazites from these experiments were analyzed with SIMS. Over the temperature range 1100 to 1350°C, the Arrhenius relation determined for in-diffusion experiments on synthetic monazite is given by:

     

Where do periodic variations in the discharge of a well become negligible?

A rule of thumb is presented to determine where variations in the discharge of a pumping well have a significant influence on the flow in an aquifer. The rule of thumb relates the period of the variation of the discharge to the distance from the well beyond which the transient effect on the flow in the aquifer is insignificant. For example, when an irrigation well pumps intermittently during the growing season, the rule may be applied to determine the distance from the well beyond which flow in the aquifer can be simulated with an average discharge during the growing season; the distance from the well beyond which flow can be simulated with a steady, yearly averaged discharge can also be computed.